Drill: Draw & name 5 isomers of C 5 H 8
Review Drill & Test
Functional Groups
Draw & Name Isomers of: C 4 H 6
Functional Groups Chemically active part of an organic compound
Functional Groups Anything other than singularly bonded carbon & hydrogen in an organic compound
Functional Groups The name of any organic compound ends with the suffix for the most important functional group
Terminology R- represents the part of the organic compound you are not referring to
Terminology R-OH -OH is the functional group R- anything else
Alkene C=C
Alkyne C=C
Halides R-X X = F, Cl, Br, or I haloalkane alkylhalide
Halides Cl 2-chlorobutane 2-butylchloride
Ethers R 1 -O-R 2 alkylalkylether alkoxyalkane
Ethers CH 3 CH 2 -O-CH 3 Methylethylether methoxyethane
Hydroxyl Group C OH
Alcohols R-OH hydroxyalkane alkanol
Alcohols CH 3 -CH 2 -OH hydroxyethane ethanol
Carbonyl Group C=O
Ketones O R-C-R Oxy or ketoalkane alkanone
Ketones O 3-pentanone 3-oxypentane
Aldehyde O R-C-H alkanal alkanaldehyde
Aldehydes O hexanal hexanaldehyde H
Name the following: OHCl CHCH H 3 C CH 2 CH 3
Name the following: OHCl CHCH H 3 C CH 2 CH 3
4-chloro-2-pentanol OHCl CHCH H 3 C CH 2 CH 3
Drill: Name the following: OHO
Carboxyl Group C=O HO
Carboxylic Acid O R-C-OH Alkanoic Acid
Carboxylic Acid O CH 3 -CH 2 -C-OH Propanoic Acid
Drill: Draw & name 5 isomers of: OH
Functional Isomers: Isomers with different functional groups: The suffix changes
Propanone Propanaldehyde O O H
Positional Isomers: Isomer’s functional group in a new location The # before the main chain name changes
2-propanol 1-propanol OH
Name the following: CH 3 -CH 2 -CH 2 -OH CH 3 -CH 2 -O- CH 2 -CH 3 O CH 3 -CH 2 -C-CH 2 -CH 3
Name the following: O O C C H 3 C CH OH OH
Name the following: O O C C H 3 C CH OH OH
2-hydroxy-3-ketobutanoic acid O O C C H 3 C CH OH OH
Name the following: O CH 3 -CH 2 -CH 2 -C-OH O CH 3 -CH 2 -C-H
Carboxyl Derivatives C=O O
Esters O R 1 -C-O-R 2 Alkylalkanoate
Esters O CH 3 -CH 2 -CH 2 -C-O-CH 3 methylbutanoate
Anhydrides O O R 1 -C-O-C-R 2 Alkanoicalkanoic anhydride
O O O Butanoicpropanoic anhydride
Draw the following: 2-hydroxypentanal Methylpropylether Trichloroethanoic acid Ethylbutanoate Aceticformic anhydride
Drill: Draw & Name 5 isomers of: C3H6O2C3H6O2
Name, then & Draw & name a Functional Isomer of: O OH C C C C C C C
O C C C C C C C
3-hydroxy-5- methylhexanoic acid O OH C C C C C C C
2,3-dihydroxy-5- methylhexanal(dehyde) O H C C C C C C OH C
1,3-dihydroxy-5- methyl-2-hexanone O OH C C C C C C C
Name & Draw 1 Positional Isomer of: O OH C C C C C C C
O C C C C C C C 2-hydroxy-5- methylhexanoic acid
Name & Draw 1 Structural Isomer of: O OH C C C C C C C
3-hydroxyheptanoic acid O OH C C C C C C C
Name & Draw 1 Optical Isomer of: O OH C C C C C C C
To draw an optical isomer, draw the mirror image of an assymetric compound
O OH C C C C C C C 3-hydroxy-5- methylhexanoic acid
C C C C C C HO O OH C 3-hydroxy-5- methylhexanoic acid
Draw: 2-phenylpropanoic acid 3-hydroxy-2-iodopentanal 2-cyclohexyl-3-octanone phenylbutanoate
Drill: Name: C C C C OH O C OCl
Drill: Draw the following: Butanoicpentanoic anhydride
Thiol R-SH Sulfhydrylalkane Mercaptoalkane Alkanethiol
SH 3-sulfhydrylpentane 3-mercaptopentane 3-pentanethiol
Sulfide R 1 -S-R 2 Alkylalkylsulfide Alkylalkylthioether
Sulfide S diethylsulfide diethylthioether
Disulfide R 1 -S-S-R 2 Alkylalkyldisulfide
Disulfide S-S methylphenyldisulfide C
Thioesters O R 1 -C-S-R 2 Alkylthioalkanoate
Thioesters O CH 3 -C-S-CH 3 Methylthioethanoate
Draw the Following: Methylthiobutanoate Methylphenyl ether Diphenyl thioether 2-propanethiol
Name: C C C C C OH O SH Cl
C C C C C OH O SH Cl
3-chloro-2-mercaptopentanoic acid C C C C C OH O SH Cl
Drill: Name: C C C C O C O
Amine Group N:
Ammonia :NH 3
Ammonium NH 4 +
Primary Amines R-NH 2 Aminoalkane alkylamine
Primary Amines CH 3 -NH 2 Aminomethane methylamine
Secondary Amines R 2 R 1 -NH Alkylalkylamine
CH 3 CH 3 -CH 2 -NH methylethylamine
Tertiary Amines R 2 R 1 -N-R 3 Alkylalkylalkylami ne
CH 2 -CH 3 CH 3 -N: CH 2 -CH 2 -CH 3 methylethylpropylamine
Quaternary Amines R 2 R 1 -N-R 3 R 4 Tetraalkylammonium +
CH 3 CH 3 -N-CH 3 CH 2 -CH 2 -CH 3 trimethylpropylammonium +
CH 3 CH 3 -N-H CH 2 -CH 2 -CH 3 dimethylpropylammonium +
Amides O R 1 -C-NH 2 Alkanoamide
O C-C-C-C-C NH 2 Pentanoamide
Nitrile R-C=N Cyanoalkane Alkanonitrile
Nitrile CH 3 -C=N Cyanomethane Ethanonitrile
Name: C C C C C OH O F
Name: C C C C C OH O F
3-fluoro-4- hydroxypentanoic acid C C C C C OH O F
Draw & name 10 isomers of: C 4 H 9 NO
Draw the following: 2-phenyl-1-propanol Butylethenyl ether
Draw the following: phenylthioacetate methylisopropylsulfide 2-mercaptobutanal
Name: C C C S C C O
C C C S C C O
propylthioacetate C C C S C C O
Name: SH O OH
Name: SH O OH
3-hydroxy-5-mercapto-6- methyl-7-phenyloctanoic acid SH O OH
Draw & name 10 isomers of: C 4 H 8 SO 2
Drill: Name SH O H O
Name C N OH N H O H
Name C N OH N H O H
4-cyano-2-hydroxy-3- methylhexanoamide C N OH N H O H
Drill: Name Cl OH O
Primary Amines R-NH 2 Aminoalkane alkylamine
Secondary Amines R 2 R 1 -NH Alkylalkylamine
Tertiary Amines R 2 R 1 -N-R 3 Alkylalkylalkylami ne
Quaternary Amines R 2 R 1 -N-R 3 R 4 Tetraalkylammonium +
Amides O R 1 -C-NH 2 Alkanoamide
Nitrile R-C=N Cyanoalkane Alkanonitrile
Name C N OH NH 2 O
Cyanate R-O-C=N Alkylcyanate
Cyanate O-C=N cyclohexylcyanate
Isocyanate R-N=C=O Alkylisocyanate
Isocyanate N=C=O 1-pentylisocyanate
Thiocyanate R-S-C=N Alkylthiocyanate
Thiocyanate S-C=N 2-propylthiocyanate
Isothiocyanate R-N=C=S Alkylisothiocyanate
Isothiocyanate CH 3 -N=C=S Methylisothiocyanate
Phosphates O R-O-P-O -1 O -1 Alkylphosphate
Phosphates O -O-P-O -1 O -1 Phenylphosphate
Diphosphates O O R-O-P-O-P-O -1 O -1 O -1 Alkyldiphosphate
Diphosphates O O CH 3 -O-P-O-P-O -1 O -1 O -1 Methyldiphosphate
Triphosphates O O O R-O-P-O-P-O-P-O -1 O -1 O -1 O -1 Alkyltriphosphate
Triphosphates O O O -O-P-O-P-O-P-O -1 O -1 O -1 O -1 2-butyltriphosphate
Phosphodiester O CH 3 -CH 2 -O-P-O-CH 3 O -1 Methylethylphosphate
Carboxylic acid Carboxylic acid derivative Aldehyde Ketone Alcohol Amine Thiol
Drill: Draw & Name 5 isomers of: C 3 H 7 NO 2
Drill: Name: C O OH NH 2 OH Br
Organic HW Draw & Name 5 isomers of: C 3 H 6 SO
Drill: Draw & Name 5 Isomers of: C 4 H 7 NO
Lab: Today Review: Tomorrow Test : Wednesday
Name the following: C O NH 2 OH NCNC
Name the following: C O NH 2 OH NCNC
3-cyano-2-hydroxy-7-methyl- 6-phenyloctanoamide C O NH 2 OH NCNC
Drill: Name the following: C O OH NHSH Cl
Name the following: C O OH NHSH Cl
2-amino-3-chloro-4- mercapto-N,7-dimethyl-6- phenylnonanoic acid C O OH NHSH Cl
Test Tomorrow on Functional Groups
Name the following: O OHF
Name the following: O OHF
3-fluoro-1-methoxy-4-methyl-2- cyclopropylhepta-5-yn-1-ol O OHF
Name the following: OO O PO 4 -2 OH
Name the following: OO O PO 4 -2 OH 2 1
4-methyl-3-phenyl-2- phosphopentanoic-2- hydroxypropanoic anhydride OO O PO 4 -2 OH 2 1
Draw: 3-mercaptohexanoamide Methyl-2-hydroxythioacetate Para-iodophenylformic acid Phenylpropylamine 2-amino-3-ethyl-4-keto-N- methylhexanaldehyde
Draw & Name 10 isomers of: C 4 H 9 SNO
Draw & Name 10 isomers of: C 4 H 9 NO 2
Name the following: NH P 3 O 10 -4
Name the following: NH P 3 O 10 -4
4-amino-6,7-dimethyl-N- phenyl-3-octyltriphosphate NH P 3 O 10 -4
Name the following: O SH O H
Name the following: O SH O H
3-mercapto-6,7-dimethyl- 4-phenoxynonanal O SH O H
Drill: Name: OH NH 2 O OH NCNC
Name: OH NH 2 O OH NCNC
3-amino-5-cyano-4- hydroxyhexanoic acid OH NH 2 O OH NCNC
Name the following: Br O O NCSNCS
Name the following: Br O O NCSNCS 1
propyl-4-bromo-3-cyclobutyl- 5-thiocyanatohexanoate Br O O NCSNCS 1
Name the following: O OHCl
Name the following: O OHCl
3-chloro-2-cyclopropyl-4- methylpentanoic acid O OHCl
Drill: Name the following: O OF O
O OF O 1 2
Methyl-3-fluoro-2-keto-4- methylpentanoate O OF O 1 2
Name the following: S OOH NCNC
Name the following: S OOH NCNC 1 2
Ethyl-2-cyano-3- hydroxythiohexanoate S OOH NCNC 1 2
Draw the Following: 3-methyl-5-propyl- octanoamide Octylbutanoate
Draw the Following: Aceticpentanoic anhydride 2-cyano-3- mercaptohexanoic acid
Drill Draw & name 5 isomers of: C 4 H 7 NO
Draw: Benzoic acid
Draw: 4-hydroxy-N- methyl- benzoamide
Drill: Draw: 4-hydroxy-2- mercapto pentanoic acid
Review
C=C
O R C O R
R N C O
R-SH
R-NH 2
O R C OH
O C R R
R-OH
O O C C R O R
R C N
H :N R R
O R C NH 2
O R C H
R O C N
R 1 -O-R 2
R-I
R + R N R R
C=C
R + R NH R
R 1 -S-R 2
O R C S R
R S C N
O -2 O P O R O
R :N R R
R-S-S-R
R N C S
Drill: Name: OH O NH 2 SH
Name the compounds on the board
Draw the compounds on the board
Draw & Name 10 isomers of C 4 H 7 SNO
C 4 H 7 NO