4-1 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein THE ANALYSIS OF GLASS

4-2 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Glass Fragments Glass is a hard, brittle, amorphous substance that is composed of silicon oxides mixed with various metal oxides. Amorphous solids have their atoms arranged randomly, unlike crystals. Tempered glass is stronger than normal glass due to rapid heating and cooling. Laminated glass found in car windshields has a layer of plastic between two pieces of ordinary window glass.

4-3 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Glass Fragments For the forensic scientist, the problem of glass comparison is one that depends on the need to find and measure those properties that will associate one glass fragment with another while minimizing or eliminating other sources. To compare glass fragments, a forensic scientist evaluates two important physical properties: density and refractive index.

4-4 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Important Physical Properties Density is defined as the mass per unit volume. (D = M/V) –Density is an intensive property of matter, meaning it remains the same regardless of sample size. –It is considered a characteristic property of a substance and can be used as an aid in identification.

4-5 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Forensic Science: Fundamentals & Investigations, Chapter 14 5 Density The formula for calculating density is: D = m / V The mass (m) of a fragment of glass can be found using a balance beam device. Place the fragment of glass into a beaker filled with water and measure the volume (V) of overflow. Divide the mass (in grams) by the volume (in milliliters) to find the density (D) of the glass fragment in g/ml

4-6 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Density Practice Find the density for the following pieces of glass: 1. Mass: 4g, Volume Displaced: 2mL 2. Mass: 15g, Volume Displaced: 3mL 3. Mass: 1g, Volume Displaced: 2mL

4-7 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Important Physical Properties Light waves travel in air at a constant speed until they penetrate another medium, such as glass or water, at which point they are suddenly slowed, causing the rays to bend. The bending of light waves because of a change in velocity is called refraction. Refractive index is the ratio of the speed of light in a vacuum to that in the medium under examination.

4-8 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Important Physical Properties For example, at 25 o C the refractive index of water is This means that light travels times faster in a vacuum than it does in water. Like density, refractive index is an intensive property and will serve to characterize a substance.

4-9 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Figure 4–10 Light is refracted when it travels obliquely from one medium to another.

4-10 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Figure 4-4 The electromagnetic spectrum.

4-11 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Figure 4–3 Representation of the dispersion of light by a glass prism.

4-12 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Analyzing Cracks The penetration of window glass by a projectile, whether it is a bullet or a stone, produces cracks which radiate outward (radial fractures) and encircle the hole (concentric fractures). By analyzing the radial and concentric fracture patterns in glass, the forensic scientist can determine the direction of impact.

4-13 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Fractures Concentric Radial bsapp.com

4-14 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein bsapp.com

4-15 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein bsapp.com

4-16 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Direction of Penetration A projectile hole is always wider at the exit side bsapp.com

4-17 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Direction of Penetration Concentric Radial bsapp.com

4-18 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Stress Marks The perpendicular edge of stress marks always face the surface on which the crack originated bsapp.com

4-19 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein

4-20 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein Analyzing Cracks The direction of impact can also be accomplished by applying the 3R Rule: Radial cracks form a Right angle on the Reverse side of the force. It is frequently possible to determine the sequence of impacts when there have been successive penetrations of glass because a fracture always terminates at an existing line of fracture.

4-21 PRENTICE HALL ©2008 Pearson Education, Inc. Upper Saddle River, NJ FORENSIC SCIENCE An Introduction By Richard Saferstein AB Which hole was made first?