Anthropogenic emissions of highly reactive VOCs (HRVOCs) inferred from oversampling of OMI formaldehyde (HCHO) columns And its application to Houston-Galveston-Brazoria.

Slides:

Advertisements

Similar presentations

Dylan Millet Harvard University with

Advertisements

Observing U.S. urban NO x emissions from Ozone Monitoring Instrument (OMI) satellite retrievals Zifeng Lu, David G. Streets Decision and Information Sciences.

Template Evaluating NOx Emission Inventories for Regulatory Air Quality Modeling using Satellite and Model Data Greg Yarwood, Sue Kemball-Cook and Jeremiah.

AIR POLLUTION IN THE US : Ozone and fine particulate matter (PM 2.5 ) are the two main pollutants 75 ppb (8-h average) 15  g m -3 (1-y av.)

Page 1 OMI Science Team Meeting, Helsinki, Finland, 24 – 27 June 2008M. Van Roozendael et al. On the usability of space nadir UV-visible observations for.

Dylan Millet, Daniel Jacob, and May Fu Harvard University Thomas Kurosu and Kelly Chance Harvard-Smithsonian Astrophysical Observatory Alex Guenther NCAR.

Observational Approaches for Climate Treaty Verification: Atmospheric observations provide the only source of independent information through which treaty.

1 Surface nitrogen dioxide concentrations inferred from Ozone Monitoring Instrument (OMI) rd GEOS-Chem USERS ` MEETING, Harvard University.

Constraining global isoprene emissions with GOME formaldehyde column measurements Changsub Shim, Yuhang Wang, Yunsoo Choi Georgia Institute of Technology.

Caroline Nowlan, Xiong Liu, Cheng Liu, Gonzalo Gonzalez Abad, Kelly Chance Harvard-Smithsonian Center for Astrophysics, Cambridge, MA James Leitch, Joshua.

Model Evaluation with Satellite Data: NO 2, HCHO, and Beyond Monica Harkey Tracey Holloway Alex Cohan Rob Kaleel.

Detection of anthropogenic formaldehyde over North America by oversampling of OMI data: Implications for TEMPO Lei Zhu and Daniel J. Jacob.

Using OMI HCHO observations as a constraint on isoprene emissions over Africa Eloïse Marais 1, Daniel Jacob 1, Jennifer Murphy.

Deriving isoprene emissions for the African continent using space-based formaldehyde measurements Eloïse Marais 1, Daniel Jacob.

Assessing the Lightning NO x Parameterization in GEOS-Chem with HNO 3 Columns from IASI Matthew Cooper 1 Randall Martin 1,2, Catherine Wespes 3, Pierre-Francois.

Isoprene emissions in Africa inferred from OMI HCHO ACKNOWLEDGEMENTS: This work was funded by the NASA ACMAP program and the South African National Research.

Validation of a Satellite Retrieval of Tropospheric Nitrogen Dioxide Randall Martin Dalhousie University Smithsonian Astrophysical Observatory Daniel Jacob.

Intercomparison methods for satellite sensors: application to tropospheric ozone and CO measurements from Aura Daniel J. Jacob, Lin Zhang, Monika Kopacz.

Mapping isoprene emissions from space Dylan Millet with

North American Isoprene Emissions Measured from Space Paul Palmer Harvard University ACD seminar series, NCAR, January 14, 2002.

Biogenic, pryogenic, anthropogenic pryogenic anthropogenic biogenic anthropogenic pryogenic pyrogenic anthropogenic biogenic anthropogenic Thomas Kurosu,

SPACE-BASED HCHO MEASUREMENTS AS CONSTRAINTS ON VOC EMISSIONS IN ASIA Tzung-May Fu, Daniel J. Jacob Harvard University Kelly V. Chance Harvard SAO/CFA.

AIR QUALITY STUDIES USING OBSERVATIONS FROM SPACE Daniel J. Jacob and funding from NASA ACMAP, NASA GTCP, EPRI with Easan Drury (now at NERL), Folkert.

Interannual variability in biogenic emissions driven by dynamic vegetation conditions Daniel Cohan (PI), Adetutu Aghedo, Erin Chavez-Figueroa, and Ben.

NMVOC emissions NMVOC emissions estimated from HCHO GOME-2 satellite data J-F. Muller, J. Stavrakou I. De Smedt, M. Van Roozendael Belgian Institute for.

Nitrogen Oxide Emissions Constrained by Space-based Observations of NO 2 Columns University of Houston Amir Souri, Yunsoo Choi, Lijun Diao & Xiangshang.

The Sensitivity of U.S. Surface Ozone Formation to NO x and VOCs as Viewed from Space: the Ozone Monitoring Instrument (OMI) Bryan Duncan 1, Yasuko Yoshida.

Estimating anthropogenic NOx emissions over the US using OMI satellite observations and WRF-Chem Anne Boynard Gabriele Pfister David Edwards AQAST June.

Global isoprene sources and chemistry: constraints from atmospheric observations Daniel J. Jacob with Emily Fischer, Fabien Paulot, Lei Zhu, Eloïse Marais,

Validation, Day of Week and Seasonal Perspectives on Satellite NO 2 Ronald C. Cohen UC Berkeley.

Southeast US air chemistry: directions for future SEAC 4 RS analyses Tropospheric Chemistry Breakout Group DRIVING QUESTION: How do biogenic and anthropogenic.

SATELLITE OBSERVATIONS OF ATMOSPHERIC CHEMISTRY Daniel J. Jacob.

And funding from NASA ACMAP OMI HCHO columns Jan 2006Jul 2006 Using OMI formaldehyde (HCHO) observations to estimate isoprene emissions over Africa Eloïse.

Chemical Condition and Surface Ozone in Urban Cities of Texas During the Last Decade: Observational Evidence from OMI, CAMS, and Model Analysis Yunsoo.

Diagnosing the sensitivity of O 3 air quality to climate change over the United States Moeko Yoshitomi Daniel J. Jacob, Loretta.

Using OMI HCHO to test biogenic and anthropogenic emission inventories in Africa OMI HCHO EOS Aura STM 1-3 October, 2012 E. A. Marais

1 Prakash Karamchandani 1, David Parrish 2, Lynsey Parker 1, Thomas Ryerson 3, Paul O. Wennberg 4, Alex Teng 4, John D. Crounse 4, Greg Yarwood 1 1 Ramboll.

How accurately we can infer isoprene emissions from HCHO column measurements made from space depends mainly on the retrieval errors and uncertainties in.

Study on NO x lifetime in chemistry transport model Ran Yin.

Simulation Experiments for TEMPO Air Quality Objectives Peter Zoogman, Daniel Jacob, Kelly Chance, Xiong Liu, Arlene Fiore, Meiyun Lin, Katie Travis, Annmarie.

Air Resources Laboratory 1 Comprehensive comparisons of NAQFC surface and column NO 2 with satellites, surface, and field campaign measurements during.

MAPPING ISOPRENE EMISSIONS FROM SPACE USING OMI FORMALDEHYDE MEASUREMENTS Dylan B. Millet, Daniel J. Jacob, K. Folkert Boersma, Justin P. Parrella Atmospheric.

Quantifying methane emissions from North America Daniel Jacob with Alex Turner, Bram Maasakkers, Jianxiong Sheng, Melissa Sulprizio.

Top-Down Emissions Studies using Atmospheric Observations and Modeling Greg Frost NOAA Earth System Research Laboratory Boulder, Colorado, USA  Why top-down.

Contributions from TES and OMI to tropospheric chemistry and air quality: a retrospective Daniel J. Jacob.

The 2003 Wake-up Call: Predictable? “Normal” airmass flow Stagnant airmass flow Jul29-Jul31-Jul 2-Aug 4-Aug 6-Aug8-Aug.

February 11, 2016 Nitrogen Oxides (NO x ) Emissions from U.S. Shale Plays using an Integrated Top-down and Bottom-up Approach Speaker: Andy Chang, PhD.

Isoprene emissions in Africa inferred from OMI HCHO Eloïse Marais D. Jacob, T. Kurosu, K. Chance, J. Murphy,

Satellite Data for Health & Air Quality Applications

Xiaomeng Jin and Arlene Fiore

LaRC Air Quality Applications Group Sushil Chandra Jerry Ziemke

Distribution of formaldehyde over North America:

Xiaomeng Jin1, Arlene Fiore1, Lee Murray2, Luke Valin3

Mapping surface air concentrations from OMI and inferring cancer risks: implications for TEMPO Lei Zhu TEMPO STM 06/01/2017 Lei Zhu, Daniel J. Jacob, Frank.

Top-down constraints on emissions of biogenic trace gases from North America Dylan Millet with D.J. Jacob, R.C. Hudman, S. Turquety, C. Holmes (Harvard)

Randall Martin Aaron Van Donkelaar Daniel Jacob Dorian Abbot

North American Hydrocarbon Emissions Measured from Space

Satellite Remote Sensing of Ozone-NOx-VOC Sensitivity

Space-based Diagnosis of Surface Ozone Sensitivity to Anthropogenic Emissions Randall Martin Aaron Van Donkelaar Arlene Fiore.

Dylan Millet D.J. Jacob, D.R. Blake, K. Chance, A. Fried,

MAPPING OF VOLATILE ORGANIC COMPOUND (VOC) EMISSIONS USING SATELLITE OBSERVATIONS OF FORMALDEHYDE COLUMNS Daniel J. Jacob with Paui I. Palmer, Tzung-May.

Estimation of Emission Sources Using Satellite Data

Detection of anthropogenic formaldehyde over North America by oversampling of OMI data: Implications for TEMPO Lei Zhu and Daniel J. Jacob.

SATELLITE OBSERVATIONS OF OZONE PRECURSORS FROM GOME

Biogenic Emissions over Europe and VOC Oxidation

Constraining the magnitude and diurnal variation of NOx sources from space Folkert Boersma.

MEASUREMENT OF TROPOSPHERIC COMPOSITION FROM SPACE IS DIFFICULT!

Using satellite observations of tropospheric NO2 columns to infer trends in US NOx emissions: the importance of accounting for the NO2 background Rachel.

TOP-DOWN ISOPRENE EMISSION INVENTORY FOR NORTH AMERICA CONSTRUCTED FROM SATELLITE MEASUREMENTS OF FORMALDEHYDE COLUMNS Daniel J. Jacob, Paul I. Palmer,

How Aura transformed air quality research with a look forward to TROPOMI and geostationary satellites Daniel Jacob.

Presentation transcript:

Anthropogenic emissions of highly reactive VOCs (HRVOCs) inferred from oversampling of OMI formaldehyde (HCHO) columns And its application to Houston-Galveston-Brazoria (HGB) area Lei Zhu 1, Daniel Jacob 1, Loretta Mickley 1, Yasuko Yoshida 2, Bryan Duncan 2, Eloïse Marais 3, Kelly Chance 4 01/15/2014 AQAST6 1 Harvard School of Engineering and Applied Sciences; 2 Atmospheric Chemistry and Dynamics Laboratory, NASA Goddard Space Flight Center; 3 Harvard Department of Earth and Planetary Sciences; 4 Harvard-Smithsonian Center for Astrophysics OMI HCHO 2006 JJA average [Millet et al., 2008]

Relating HCHO columns to HRVOCs VOC i HCHO h (340 nm), OH oxidation k ~ 0.5 h -1 Emission E i In absence of horizontal wind, mass balance for HCHO column  HCHO : yield y i but wind smears this relationship VOCs source Distance downwind  HCHO Propylene methanol Isoprene Ethylene 00 Beyond this distance, HCHO is mainly contributed by long-lived VOCs  HCHO –  0

Oversampling approach to detect point sources Oversampling: temporal averaging of the satellite data on a spatial grid much finer than the pixel resolution of the instrument Takes advantage of the spatial offset and changing geometry of the satellite pixels from day to day Trades temporal for spatial resolution Achieves higher signal-to-noise ratio data Smoothing Radius A satellite pixel 24×13km 2 2km Optimize smoothing radius: Too fine (12 km): Increase noise Too coarse (36 km): Lose spatial features MJJAS pixels in a 1°×1° box

Biogenic OMI HCHO column, , MJJA Barnett Shale Results: Oversampling of OMI HCHO pixels Oversampling approach enables detection of anthropogenic HRVOCs from point/urban sources and gas operations. OMI HCHO column (molec./cm 2 ) Temperature (K)

Reactivity-weighted HRVOCs emissions in HGB area based on top-down approach HCHO loss rate HCHO VCD HCHO VCD from long-lived VOCs Integration of HCHO columns over HGB 180km Reactivity-weighted HRVOCs in HGB Top-down constraint: 13.7±5.2 Gg C/year NEI08 estimation: 4.5 Gg C/year Parrish et al. [2012]: 25.2±1.1 Gg C/year OMI HCHO column , MJJA

HRVOCs emissions and secondary HCHO in HGB area 10 HRVOCs emissions from NEI08 Total=9.1 Gg C/year Understanding relative contribution of secondary play an important role in developing ozone control strategies Secondary HCHO contribution near Houston: 24±17%, Rappenglück, et al., [2010] 36%, Guven and Olaguer [2011] 63%, Friedfeld et al., [2002] 92%, Parrish et al., [2012]

Distinguish primary and secondary HCHO based on plume structure VOC i HCHO EiEi kiki k u YiYi Distance downwind NEI08 underestimates secondary HCHO by 3~6 times Column model Houston Primary Secondary

AQ managers: Are there any specific areas or periods that you would want me to look at? HCHO columns can go as fine as 0.02 degree (~2 km)! , available 2008-now, processing Other urban areas? VOCs point sources regions? Gas/oil fields? Trends? Oversampling of OMI HCHO columns provides a new solution to the long- standing problem of detecting and quantifying anthropogenic HRVOCs emissions from space Take home messages Top-down constraint shows reactivity- weighted HRVOCs emission in HGB is 13.7±5.2 Gg C/year, 3.0±1.2 times higher than that estimated using NEI08

Thank you!