Co-digestion of Hog Manure with Glycerol to Boost Biogas Production Oswald Wohlgemut (MSc) July 14, 2008
Farm-scale Anaerobic Digestion
Background Anaerobic digestion
Lab Research Co-digesting hog manure with Glycerol Goals – To find optimal glycerol dosage – To boost biogas and methane production – To determine nutrient (N,P) fate through digestion – To gather information to be used for operating a pilot-scale model Biodiesel Glycerol
Why co-digest with glycerol? To find a valuable use for biodiesel waste To help boost biogas and methane production Make the process more economical To reduce GHG emissions To increase “green energy” in Manitoba
Experimental Setup 4 bench-scale anaerobic digesters (4L) Complete-mix, mesophilic (35ºC), semi-continuous fed, with gas collection
Experimental Setup 1. Shock Loading Effect – addition of 1%, 2%, 4% pure glycerol (by weight) 2. Comparison Study – comparing 1% pure glycerol to 1% crude glycerol (by weight) 3. Digester Recovery – testing microbial resistance to high COD glycerol loading over time
Feed Characteristics Hog manure screened and diluted (~1% TS) pH 7.6 Digester FeedCOD (g/l)Additional COD load Manure (Control)16.7 Manure + 1% Pure Glycerol x Manure + 2% Pure Glycerol x Manure + 4% Pure Glycerol x Manure + 1% Crude Glycerol x
Results Shock Loading Experiment Control (Manure) ~ 72% CH 4 Manure + 1% pure glycerol ~ 64% CH 4
Results Shock Loading Experiment Reactors with 2% and 4% pure glycerol addition were overloaded with SCOD and did not stabilize
Results Comparison Experiment Control (Manure) ~ 70% CH 4 Manure +1% pure glycerol ~ 63% CH 4 Manure + 1% crude glycerol ~ 67% CH X
Results Digester Recovery Can bacteria recover from overloading? Comparing 2% glycerol loading in experiment 1 & 3 Experiment 1 Glycerol start Glycerol stop 2.8 X Experiment 3
Results Methane Yield and Composition Substratem³CH 4 /kg COD added % CH 4 composition Control (Manure) % pure glycerol + manure % crude glycerol + manure % pure glycerol + manure
Conclusion Biogas and methane production increased with glycerol addition A high glycerol shock loading can cause digester failure with a buildup of VFAs Bacteria were able to recover and utilize high glycerol COD loading over time Methane composition decreases with increasing glycerol addition Crude glycerol did not have inhibitory effects
Future Research Batch experiments with raw manure to determine BMP (Biochemical Methane Potential) of manure with different concentrations of glycerol Analysis to determine nutrient (P, N) fate through digestion with glycerol
Future Research Pilot-scale digester in a solar greenhouse
Acknowledgements Manitoba Agriculture, Food and Rural Initiatives Dr. Nazim Cicek Dr. Jan Oleszkiewicz My colleagues in the lab
Questions?