5.0 View Data 1. The View Data program

5.0 View Data 2.View Data of a Compound Database Pressure and Energy units Compound Database Possibility to add other databases in the data search - see slide 18 Cu Click on «OK» to scan the Main FACT pure substance database for all species of Cu and O Cu For example, the elements Cu and O

5.0 View Data 3.The Menu Bar Units Menu: Energy Pressure Summary Menu: Cu All species containing Cu and O Cu All species containing Cu All species containing O Edit Edit Menu: File File Menu: Cu Double-click or «Enter» to view the compound data of Cu Help is provided through a slide show presentation

5.0 View Data 4.Phases Retrieval of data on Cu from the Main FACT pure substances database. There are 2 temperature ranges for Cu (liq) – each has its own C P expression. Cu has 3 phases – S, L and G. 3 phases Species name, formula weight and density References

5.0 View Data 5.References The full name of the database appears in the Status Bar: [C:\FactWin\FACTDATA\FACTBASE.CDB]. Bibliographic data

5.0 View Data 6.Heat capacity expressions – C p (T) Note that the 2 nd C p expression for the liquid is constant at temperatures over 900 K. The heat capacity expression of solid copper between 298 K and 1100K is: C p (T) = [ × T T × T T -1 ] (J/mol·K)

5.0 View Data 7.Enthalpy expressions – H(T) H(T) =[ T × T T × T ln T ] (J/mol)

5.0 View Data 8.Gibbs Energy expressions – G(T) G(T) =[ T × T T × T ln T T ln T ] (J/mol) at 1 bar

5.0 View Data 9.Entropy expressions – S(T) S(T) =[ ln T × T T × T T -1 ] (J/mol·K) at 1 bar

5.0 View Data 10.The Menu Bar Table Table Menu: Databases Databases Menu: Selection of the phase(s). Selection of the temperature range and step. Graph Graph Menu:  Selection of thermodynamic data: C p HGST C p, H, G or S …vs T 

5.0 View Data Cu 11.Thermodynamic Data for Cu: Tabular Output Close Print Save Output Output Menu: + + thermodynamic data at T = K standard state Fromto From 500 K to 2500 K in steps of in steps of 500 K all phases ( S, L, G )

5.0 View Data MagneticC p 12.Magnetic data and C p expressions for Fe and… … p is the P Factor and  is the Structure Factor Fe

5.0 View Data Fe 13.Plotted C p data for Fe Curie temperature = 1043 K

5.0 View Data Fe 14.Tabular output for Fe The allotropic transformation S1  S2 (alpha  gamma) at K At this temperature G(S1) = G(S2) (two phases in equilibrium). The enthalpy of fusion is J at K. The allotropic transition reverses at K where S2  S1 (gamma  delta). Phase transitions S1  S2  S1  L  G as T increases. The enthalpy of vaporization to form monatomic Fe(g) at 1 atm is ( ) = J at K. …with an associated enthalpy of transformation of ( ) = J

5.0 View Data CO 2 15.Real gas coefficients for carbon dioxide CO 2 B is estimated by the Tsonopoulos method from P c, T c, V c, omega (the acentric factor) and the dipole moment. Gases are treated as non-polar. For ideal gases, the value of B is zero. The truncated virial equation of state is employed to treat real gases: CO 2 For example, CO 2

5.0 View Data SiO 2 16.Data for SiO 2 SiO 2 For example, SiO 2

5.0 View Data Volumeexpansivitiescompressivities bulk modulus. 17. Volume data - expansivities, compressivities and derivative of bulk modulus. expansivities Thermal expansion expression ( expansivities ): Compressibility expression: Derivative of the bulk modulus expression:

5.0 View Data 18.Adding a compound database to the list. 1. Press the « Add… » button in the Compound Databases (1) frame. 3. This opens the dialog box “Compound - list of databases”. Type in the full name or browse to locate. 2. Select «compound»

5.0 View Data 19.Adding a compound database to the list. (continued) 4. Enter a nickname (4 characters). Enter a description (one line). Click on «OK». 5. The SGTE database is now included in the list of compound databases.

5.0 View Data 20.Data in 2 or more compound databases « All Databases » 15FACT2 SGTE17 15 compounds from the FACT BASE database and 2 from the SGTE BASE database for a total of 17 compounds.

5.0 View Data 21.View Data of a Solution Database Pressure and Energy units Solution Database Possibility to add other databases in the data search – see slide 23. Cu FeS Click on «OK» to scan the Main FACT real solutions database for all solutions containing Cu, Fe and S. Cu FeS For example, the elements Cu, Fe and S

5.0 View Data 22.The solution datasets window Help is provided through a slide show presentation Summary Menu: CuFe All solutions containing Cu, Fe or O Cu All solutions containing Cu Fe All solutions containing Fe All solutions containing O Units Menu: Energy Pressure Edit Edit Menu: File File Menu: The full name of the Main FACT real solutions database appears in the Status Bar: [ C:\FactWin\FACTDATA\FACTSOLN.SDB ].

5.0 View Data 23.Adding a solution database to the list. 1. Press « Add… » button in the Solution Databases (1) frame. 3. This opens the dialog box “Solution - list of databases”. Type in the full name or browse to locate. 2. Select «solution»

5.0 View Data 24.Adding a solution database to the list. (continued) 4. Enter a nickname (4 characters). Enter a description (one line). Click on «OK». 5. The SGTE database is now included in the database list.

5.0 View Data 25.Data in 2 or more solution databases. « All Databases » 10 A total of 10 Solutions: 4FACT 6SGTE 4 solutions from the FACT database and 6 from the SGTE database.