The Ethical Purpose of Education Walt Whitman.

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Presentation transcript:

The Ethical Purpose of Education

Walt Whitman

Triassic Fossils

My 4 out of 5 Rule

CH 3  C  P At Sussex we created many new molecules and studied them by microwave spectroscopy and photoelectron spectroscopy Phosphorus compounds with John Nixon - Polyynes with David Walton H 2 C=PH CH 3 CH=S HCCCCCNHCCCCCN CH 3  B=SF  B=S FCPFCP F 2 C=SH 2 C=C=S H  C  C  C  C  C  C  C  N (CH 3 ) 2 CH=SC=S F 2 C=PHH 2 C=PClH 2 C=PF HCPHCPC6H5CPC6H5CP The first carbon phosphorus double C=P bonded species – phosphaalkenes General method for creating carbon phosphorus triple bonded species – phosphaalkynes – only HCP previously known (for more than a decade) General thermolytic routes to new unstable species - thiocarbonyls Cl  B=SBr  B=S General method for creating Boron –Sulphides General method for creating cyanopolyynes N  C–C  P Cl  C  PHC  C–C  P H 2 C=CH-C=PH HC  C–C  C–C  P

H−C≡C−C≡C−C≡NH−C≡C−C≡C−C≡N Walton Polyyne Synthesis

Radioastronomy

Rotating dipolar molecule → a photon that can be detected by a radio telescope HCCCCCNHCCCCCN

Hintenberger Franzen and Schuy Z Nat 1963 Mass spectrum of arc discharged graphite

C 60 VS

Half Price Books

Resonant 2-photon ionisation (R2PI) spectroscopy Si C

Ap2

Graphite Target Should produce long carbon chains oooooo ooooooo oooooo ooooooo

The Idea ?

C 60

C 60 VS

My 4 out of 5 Rule

© The Pentagon Isolation Rule (PIR)

Ferrocene image at: Fe

image at: commons.wikimedia.org/wiki/File:Endohedral_fu... commons.wikimedia.org/wiki/File:Endohedral_fu...

C 28 s Sussex NNC

© If C 60 is a closed cage…

I had a hole drilled though the base plate and filled it with Argon Sussex NNC

We deposited soot from the carbon arc on an electron microscope slide and varied the Argon pressure

Sussex NNC Electron microscopy indicated that the structure of the deposited soot changed dramatically as the pressure was raised to over 80 microns

A manuscript of a paper presented at a conference in Capri sent to me by Mike Jura a professor of astrophysics at UCLA

Infra red spectrum of arc discharged soot!

The Red Solution

© 3 Then there were

Fullerene Chemistry ©

The Buckyball bounces!

C 60 Bouncing

© Just How Small is a Buckyball.

Fullerene Growth

…in Outer Space The Third Man

C 60 C 70 Detection of C 60 and C 70 in a Young Planetary Nebula J Cami, J Bernard-Salas,E Peeters and S E Malek July 2010

Diamond Graphite and… C 60

Movie- “The Third Man”

BBC Horizon TV Programme 1992

©

Problem 25 th March Draw the C 60 molecule and comment on why you drew it the way you did