Measure VOCs/OVOCs needed to understand chemistry leading to tropospheric ozone and aerosols. Long and short-lived halogenated species that can impact.

Slides:



Advertisements
Similar presentations
Global Ozone Project Curriculum Rev 13 Lesson 2: Ozone Formation in the Troposphere.
Advertisements

How much of the total ozone column change occurs in the stratosphere?
Geophysical Fluid Dynamics Laboratory Review June 30 - July 2, 2009 Geophysical Fluid Dynamics Laboratory Review June 30 - July 2, 2009.
WOAP 4 meeting, Hamburg, 29 – 31 March 2010 Perspectives from WCRP projects SPARC: Objectives of the next two years Christian von Savigny (IUP Bremen)
Organic Halogen and Related Trace Gases in the Tropical Atmosphere: Results from Recent Airborne Campaigns over the Pacific Elliot Atlas 1, Maria Navarro.
Forensic Analysis and Sorbent Collection Methods MSRAS Soil Gas Sampling Workshop Indianapolis, IN August 21-22, 2006 Gina Plantz NewFields Environmental.
HIAPER Modular Inlets (HIMIL) & Instrument Exhaust System - Dave Rogers - Outline HIMIL description contamination testing re-install HIMIL to different.
CARIBIC – Sampling from Passenger Aircraft Consortium –Start: 1994 –First measurements: 1997 –Lund Joined 1995 First measurements: PhD (Papaspiropoulos,
Improving the Representation of Atmospheric Chemistry in WRF William R. Stockwell Department of Chemistry Howard University.
ASCOS Pre-Expedition Workshop Contributing Efforts to ASCOS using the Proton Transfer Reaction Technique for VOC Analysis M. Müller, M. Graus, A. Wisthaler,
Polar Ozone: Stratosphere- Troposphere Coupling and recent Changes Proseminar Presentation Techniques Axel Behrendt.
METO 637 Lesson 15. Polar meteorology In the winter months the poles are in perpetual darkness. This causes extremely cold temperatures in the stratosphere.
The Atmosphere: Oxidizing Medium In Global Biogeochemical Cycles EARTH SURFACE Emission Reduced gas Oxidized gas/ aerosol Oxidation Uptake Reduction.
METO 621 Lesson 24. The Troposphere In the Stratosphere we had high energy photons so that oxygen atoms and ozone dominated the chemistry. In the troposphere.
EARTH’S ATMOSPHERE Chapter 14.1 Pages
Larger Chemical Ozone Loss in 2004/2005 Arctic Winter/Spring Wuhu Feng and Martyn Chipperfield School of Earth and Environment, University of Leeds Acknowledgments.
METO 637 Lesson 16.
This Week—Tropospheric Chemistry READING: Chapter 11 of text Tropospheric Chemistry Data Set Analysis.
HILL RESEARCH LAB Isoprene Analysis by Ion Mobility Spectrometry-Mass Spectrometry INTRODUCTION RESULTS Isoprene is one of the most important naturally.
1 Motivation 2 Instrumentation and Retrieval 3 CONTRAST Profile Comparison Stratospheric case study 4 TORERO NH/SH gradients 5 Summary and conclusions.
1 Br radicals in the tropical troposphere: a GEOS-Chem perspective Johan Schmidt Harvard University CONTRAST/ATTREX/CAST STM (October 22 nd ) Thanks to:
MAOS (Mobile Aerosol Observing System) and the G1 Aircraft at Cape Cod Allie Marquardt Collow.
Convective Transport of Active Species in the Tropics.
CAST: VOC observations from WAS using GC-FID and GC-MS Stephen Andrews, Jimmy Hopkins, Richard Lidster, Shalini Punjabi, Jamie Minaeian, Dene Bowdalo,
CAM-chem model evaluation of the emissions and distributions of VSLS using TOGA VOC observations from CONTRAST and TORERO (in the lower and free troposphere.
Overview of integrated science goals, flight planning, and formation flying Brian Toon.
Ozone & Greenhouse Effect. What is Ozone? Ozone is a molecule that occurs in the Stratosphere Ozone absorbs harmful UV rays from the sun O 3 + uv O 2.
ATMOSPHERIC CHEMISTRY OF ORGANIC COMPOUNDS Lecture for NC A&T (part 1) March 9, 2011 Geoff Tyndall
Deriving vertical profiles of free tropospheric trace gases from ground based measurements: Implications for oxidation of atmospheric mercury Sean Coburn.
Trace gases measurements from the Global Hawk Whole Air Sampler during the Airborne Tropical Tropopause Experiment 2013 (ATTREX-2) Maria Navarro 1, E.
References Andersson, K. et al., 1997: TVOC and Health in Non-industrial Indoor Environments. Indoor Air, 7, Apel, E. C. et al., 2003: A fast-GC/MS.
OZONE ONE KIND OF AIR POLLUTION. A photochemical reaction  Sunlight + a chemical = different chemicals  Not all kinds of light  Only shorter wavelengths.
The Ozone Layer Author: Patrick Mathias Purpose: To understand how the ozone layer protects people from UV radiation, and how the ozone layer is depleted.
Observations of BrO and (HOBr+Br 2 ) by GT-CIMS during CONTRAST 2014 Dexian Chen, Greg Huey, David Tanner GaTech Andrew Weinheimer, Denise Montzka, Teresa.
Global Measurements and Research on Stratospheric Ozone Depletion For The Vienna Convention and Its Protocols: Users, Needs & Requirements Leonard A. Barrie.
1 HIRDLS Science Team Meeting 26,27 June 2008 To be held in the Dobson Room, Atmospheric, Oceanic and Planetary Physics, Department of Physics, Oxford.
A NASA / NSF / NRL airborne field campaign focusing on atmospheric composition, chemistry, and climate over Southeast Asia. Programmatic Context, Issues.
Training begins in… 15:00 minutes Training begins in… 14:00 minutes.
The GEOS-CHEM Simulation of Trace Gases over China Li ZHANG and Hong LIAO Institute of Atmospheric Physics Chinese Academy of Sciences April 24, 2008.
The effect of pyro-convective fires on the global troposphere: comparison of TOMCAT modelled fields with observations from ICARTT Sarah Monks Outline:
Deep Convective Clouds and Chemistry (DC3) Field Experiment Principal Investigators: Mary Barth (NCAR), Bill Brune (PSU), Chris Cantrell(NCAR), Steve Rutledge.
1 Traffic Restrictions Associated with the Sino-African Summit: Reductions of NO x Detected from Space Yuxuan Wang, Michael B. McElroy, K. Folkert Boersma.
1 Global Hawk Pacific (GloPac). Science Objectives and Missions First demonstration of the Global Hawk unmanned aircraft system (UAS) for NASA and NOAA.
A NASA / NSF / NRL airborne field campaign focusing on atmospheric composition, chemistry, and climate over Southeast Asia. Programmatic Context, Issues.
A Strategic Initiative for UT/LS Research at NCAR L. Pan, S. Schauffler, M. Barth, T. Campos, A. Heymsfield, A. Lambert, D. Lenschow, W. Randel, P. Rasch.
Ozone Depletion O3O3. Ozone Factoids Good in the stratosphere, bad in the troposphere Produced at a height of ~50 km, settles to a height of 23 km Filters.
 Gasses make up the air around us  Primary gasses are Nitrogen and Oxygen  Small amounts of many other gasses are present.
Model evolution of a START08 observed tropospheric intrusion Dalon Stone, Kenneth Bowman, Cameron Homeyer - Texas A&M Laura Pan, Simone Tilmes, Doug Kinnison.
SEAC4RS Payload Payload Synergies Synergies. Complementarity between aircraft can be considered to fall into three categories. Each has considerations.
The impact of short-lived source gases on the ozone layer under the influence of a changing climate A proposed contribution to G-SPARC Björn-Martin Sinnhuber.
Use of GMI to Study Tropospheric and Stratospheric Bromine Budgets Debra Weisenstein AER, Inc. GMI Science Team Meeting March 2008.
2006 Graduate Student Symposium Measurement of HCl (g) in troposphere and lower stratosphere with CIMS technique Analytical characteristics and its implications.
The Deep Convective Clouds and Chemistry (DC3) Field Experiment Mary C. Barth (NCAR), W. H. Brune (PSU), C. A. Cantrell (U. Colorado), S. A. Rutledge (CSU),
2007 INTEX Data Meeting The Vertical Distribution of HCl over the Pacific during INTEX-B Saewung Kim, Bob Stickel, Greg Huey, Melody Avery, Jack Dibb,
Tracers of stratospheric influence and Asian dust over the Pacific during INTEX B phase II UNH SAGA special thanks to FASTOZ.
1 START08 Workshop, 8-9 Jan 2008 Understanding our atmosphere from non-CO 2 climate gases during HIPPO: Global network and aircraft profiles James W. Elkins.
Development and Applications of the TOMCAT/SLIMCAT 3-D CTM Wuhu Feng and Martyn Chipperfield NCAS, School of Earth and Environment, University of Leeds,
Layers of the Atmosphere Layer NameAltitude (km) Temperature change with altitude.
Ch. 7.3 Layers of the Atmosphere Chapter 7 section 3 page 267.
O BSERVATIONAL AND E XPERIMENTAL R ESEARCH BREAKOUT SESSION UCAR Members Meeting 2012 REPORT / SUMMARY Yvette Richardson Steve Cohn 1.
The NCAR Microwave Temperature Profiler: Data Applications from Recent Deployments Julie Haggerty, Kelly Schick, Chris Davis National Center for Atmospheric.
Ozone Depletion O3.
TOGA (Trace Organic Gas Analyzer)
Jacob T. Stewart Department of Chemistry, Connecticut College
Upper Troposphere and Lower Stratosphere Break out
WEST AFRICAN MONSOON EXPERIMENT (WAM)
13.2 NOTES The Atmosphere.
Diurnal Variation of Nitrogen Dioxide
OMI Tropospheric NO2 in China
The Atmosphere.
Presentation transcript:

Measure VOCs/OVOCs needed to understand chemistry leading to tropospheric ozone and aerosols. Long and short-lived halogenated species that can impact the trop and lower stratosphere High sensitivity/selectivity GC/MS – pptv- ppqv minute continuous analyses of 50 VOCs Semi-autonomous operation up to 50,000 ft Recently deployed on two field experiments TORERO, DC3 Trace Organic Gas Analyzer (TOGA) Gulfstream G-V Support: Steve Gabbard Roger Hendershot Rudy Montoya Scientists: Eric Apel Alan Hills Becky Hornbrook Dan Riemer (U Miami) DC3/TORERO – Recent Experiments TOGA on GV aircraft Instrument designed to have very low limits of detection (low – sub pptv) because organic species in ultratrace amounts can have a large impact on the atmosphere

TOGA Targeted Compounds Compound formaldehydeMethacrolein HCNMethyl Vinyl Ketone AcroleinButanal isobutaneMEK ChloromethaneChloroform AcetaldehydeMBO Propenedibromomethane n-Butanechloroiodomethane 1,3-ButadieneTetrachloromethane i-ButeneBenzene Bromomethanen-Heptane IsopentanePentanal Methanol2-Pentanone PentaneToluene Isoprenedibromochloromethane 2-MethylpentaneEthylbenzene, m,p xylene Hexaneo-Xylene Ethanolbromoform Propanalbenzaldehyde DMSdiiodomethane methyl iodidea-pinene Acetonecamphene Dichloromethaneb-pinene Acetonitrilelimonene MTBE

Let us know what other species you are interested in and we can see if we can accommodate We plan to measure some set of organic nitrates for this experiment