C. Johannesson Aufbau Principle Electron Configuration.

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Presentation transcript:

C. Johannesson Aufbau Principle Electron Configuration

C. Johannesson Electron Configurations  Pauli Exclusion Principle  Each orbital can hold TWO electrons with opposite spins.

C. Johannesson A. General Rules  Aufbau Principle  Electrons fill the lowest energy orbitals first.  “Lazy Tenant Rule”

C. Johannesson RIGHT WRONG A. General Rules  Hund’s Rule  Within a sublevel, place one e - per orbital before pairing them.  “Empty Bus Seat Rule”

C. Johannesson O 8e -  Orbital Diagram  Electron Configuration 1s 2 2s 2 2p 4 B. Notation 1s 2s 2p

C. Johannesson  Shorthand Configuration S 16e - Valence Electrons Core Electrons S16e - [Ne] 3s 2 3p 4 1s 2 2s 2 2p 6 3s 2 3p 4 B. Notation  Longhand Configuration

C. Johannesson © 1998 by Harcourt Brace & Company s p d (n-1) f (n-2) C. Periodic Patterns

C. Johannesson C. Periodic Patterns  Period #  energy level (subtract for d & f)  A/B Group #  total # of valence e -  Column within sublevel block  # of e - in sublevel

C. Johannesson s-block1st Period 1s 1 1st column of s-block C. Periodic Patterns  Example - Hydrogen

C. Johannesson C. Periodic Patterns  Shorthand Configuration  Core e - : Go up one row and over to the Noble Gas.  Valence e - : On the next row, fill in the # of e - in each sublevel.

C. Johannesson [Ar]4s 2 3d 10 4p 2 C. Periodic Patterns  Example - Germanium

C. Johannesson  Full energy level  Full sublevel (s, p, d, f)  Half-full sublevel D. Stability

C. Johannesson  Electron Configuration Exceptions  Copper EXPECT :[Ar] 4s 2 3d 9 ACTUALLY :[Ar] 4s 1 3d 10  Copper gains stability with a full d-sublevel. D. Stability

C. Johannesson D. Stability  Ion Formation  Atoms gain or lose electrons to become more stable.  Isoelectronic with the Noble Gases.

C. Johannesson  Electron Configuration Exceptions  Chromium EXPECT :[Ar] 4s 2 3d 4 ACTUALLY :[Ar] 4s 1 3d 5  Chromium gains stability with a half-full d-sublevel. D. Stability

C. Johannesson O 2- 10e - [He] 2s 2 2p 6 D. Stability  Ion Electron Configuration  Write the e - config for the closest Noble Gas  EX: Oxygen ion  O 2-  Ne