Enthalpies of Formation. An enthalpy of formation,  H f, is defined as the enthalpy change for the reaction in which a compound is made from its constituent.

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Presentation transcript:

Enthalpies of Formation

An enthalpy of formation,  H f, is defined as the enthalpy change for the reaction in which a compound is made from its constituent elements in their elemental forms.

Standard Enthalpies of Formation Standard enthalpies of formation,  H f °, are measured under standard conditions (25 °C and 1.00 atm pressure).

Standard Enthalpies of Formation The law of summation of heats of formation states that the enthalpy of a reaction is equal to the total formation energy of the products minus that of the reactants.. –  is the mathematical symbol meaning “the sum of”, and m and n are the coefficients of the substances in the chemical equation.

A Problem to Consider You record the values of  H f o under the formulas in the equation, multiplying them by the coefficients in the equation. -You can calculate  H o by subtracting the values for the reactants from the values for the products.

Practice Problem 6.45

Practice Problem 6.46

Calculation of  H Imagine this as occurring in three steps: C 3 H 8 (g) + 5 O 2 (g)  3 CO 2 (g) + 4 H 2 O (l) C 3 H 8 (g)  3 C (graphite) + 4 H 2 (g) 3 C (graphite) + 3 O 2 (g)  3 CO 2 (g) 4 H 2 (g) + 2 O 2 (g)  4 H 2 O (l)

Calculation of  H Imagine this as occurring in three steps: C 3 H 8 (g) + 5 O 2 (g)  3 CO 2 (g) + 4 H 2 O (l) C 3 H 8 (g)  3 C (graphite) + 4 H 2 (g) 3 C (graphite) + 3 O 2 (g)  3 CO 2 (g) 4 H 2 (g) + 2 O 2 (g)  4 H 2 O (l)

Calculation of  H Imagine this as occurring in three steps: C 3 H 8 (g) + 5 O 2 (g)  3 CO 2 (g) + 4 H 2 O (l) C 3 H 8 (g)  3 C (graphite) + 4 H 2 (g) 3 C (graphite) + 3 O 2 (g)  3 CO 2 (g) 4 H 2 (g) + 2 O 2 (g)  4 H 2 O (l)

C 3 H 8 (g) + 5 O 2 (g)  3 CO 2 (g) + 4 H 2 O (l) C 3 H 8 (g)  3 C (graphite) + 4 H 2 (g) 3 C (graphite) + 3 O 2 (g)  3 CO 2 (g) 4 H 2 (g) + 2 O 2 (g)  4 H 2 O (l) C 3 H 8 (g) + 5 O 2 (g)  3 CO 2 (g) + 4 H 2 O (l) Calculation of  H The sum of these equations is: