I. Kikaš, a I. Škorić, a M. Kovács, b L. Fodor, b O. Horváth, b M. Šindler a a Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, Zagreb, Croatia b Department of General and Inorganic Chemistry, Institute of Chemistry, Faculty of Engineering, University of Pannonia, P.O.B. 158, Veszprém H-8201, Hungary [1] Škorić, I.; Šmehil, M.; Martinić, Ž.; Molčanov, K.; Kojić-Prodić, B.; Šindler-Kulyk, M. J. Photochem. Photobiolog. A - Chemistry 207 (2009) 190–196. [2] Filippini, M.-H.; Rodriguez, J. Chem. Rew. 99 (1999) 27–76. Sinteza, fotokemija i fotofizika novih butadienskih derivata Synthesis, photochemistry and photophysics of novel butadienes derivatives In order to prepare new polycyclic structures by photochemical methodology, new systems with prolonged conjugation, ,  ’-diaryl-1,3-butadiene derivatives 1-4, were synthesized by Wittig reaction. The influence of the introduced methyl group on the double bond was examined in order to see the possibility of the intramolecular [2+2] photocycloaddition and formation of the benzobicyclo[3.2.1]octadiene photoproducts. The methyl group has great influence on the planarity and steric hindrance of the starting geometrical isomers and as the consequence on the yield and reaction course also. Detailed photophysical characterization of the starting derivatives 1-4 was examined for better understanding different photochemical routes. The photochemical reactions were performed as well as the spectroscopic characterization of the photoproducts. Fig 1. Transient absorption spectum of trans,trans-3 recorded at 150 ns after the excitation, the estimated spectrum of the triplet state along with the spectrum of the starting material and that of the final product. The decay curves at 305 and 400 nm are also displayed. Fig 2. Transient absorption spectra of trans,trans-4 recorded at 80, 150, and 300 ns after the excitation, the estimated spectrum of the triplet state along with the spectrum of the starting material and that of the final product. The decay curves at 255 and 310 nm are also displayed. Fig 3. Two-stage absorption transient signal (decay curve) of trans,trans-4 at 300 nm in a longer time- scale. Fig 4. Fluorescence spectra of the geometrical isomers of compounds 3 and 4. Emission These butadiene derivatives 1–4 display diverse emission features strongy depending on their structures. The cis,cis-3 isomer efficiently fluoresces (  = 0.246), its emission spectrum is characterized by well resolved vibronic fine structure (Fig 4). The fluorescence of the cis,trans-3 isomer is very similar, but its quantum yield is 45% lower (  = 0.135). The trans,trans- 3 isomer, however, displays an order of magnitude weaker (  = 0.017) and rather structurless emission, probably due to the steric infuence promoting other (probably photochemical) decay routes. Methyl substituents on the double bonds in compounds 4 dramatically modify the emission properties too, breaking the extended conjugation. The fluorescence spectra are strongly red-shifted, becoming a very weak (  < 0.001), broad, structureless band (Fig 4). Also the lifetime of the singlet excited state is significantly lower for these methylated derivatives compared to the corresponding unsubstituted compounds. Transient absorption Time-resolved absorption measurements gave some hints regarding the photochemical decay routes of the excited states. In the case of the unsubstituted trans,trans-3 isomer a transient absorption of 450-ns lifetime was observed, which may be assigned to the triplet excited state of this compound (Fig 1). The corresponding methyl substituted derivative displayed several transient absorptions. The shortest-lived one of 150-ns lifetime, similarly to the previous case, may be attributed to the formation and decay of triplet excited state (Fig 2). Synthesis of butadiene derivatives Photophysics Photochemistry and reaction mechanisms At longer time-scale, however, two other transients were observed with 50-  s and 15-ms lifetime, respectively (Fig 3). On the basis of the lifetime and the change of the absorption, the decay of the latter intermediate probably leads to the formation of the final product in the photochemical reaction of the starting compound. Scheme 3. Intramolecular [2+2] photocycloaddition of butadiene derivative 3. Scheme 1. Intramolecular [2+2] photocycloaddition of butadiene derivative 1 Scheme 2. Two possible electrocyclic photoproducts from different configurations of 2. Scheme 4. Photoisomerisation of butadiene derivative 4 XXII. hrvatski skup kemičara i kemijskih inženjera Zagreb, Hrvatska, veljače This work was supported by the Ministry of Science, Education and Sports of the Republic of Croatia and the National Office of Research and Technology (OMFB-01247/2009). The photochemistry of butadiene structures 1-4 under the intramolecular conditions of cycloaddition reactions was studied and different reaction pathways (Schemes 1-4) were followed as the influence of the presence of the methyl group in the starting molecules 1,2 and 4 in comparison with the unsubstituted derivative 3. Literature: