NACAA MSC, North Carolina

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Presentation transcript:

NACAA MSC, North Carolina Update NACAA MSC, North Carolina October 29, 2015 Laki Tisopulos, Ph.D., P.E. Assistant Deputy Executive Officer South Coast Air Quality Management District

AQ-SPEC - Background Governing Board direction to establish center - July 2014 Over $600,000 investment Main Goals & Objectives Evaluate sensor performance Provide guidance & clarity for ever-evolving sensor technology & data interpretation Catalyze successful evolution and use of sensor technology Minimize confusion AQMesh CairClip Shinyei Dylos (prototype) DC1100 Pro SmartCitizens

AQ-SPEC - Overview FIELD TESTING LAB TESTING RESULTS vs (Side-by-side comparison w/ FRMs) LAB TESTING (Controlled conditions) RH = 30% T = 25C Conc = 10 ppb vs RESULTS (Categorize sensors based on performance)

Website / Clearinghouse AQ-SPEC – Overview (continued) SCAQMD Website / Clearinghouse AQ Officials Community Vendors RESULTS

AQ-SPEC Field Testing Started on 09/12/2014 Locations: Sensor tested in triplicates Two month deployment Locations: Rubidoux station Inland site Fully instrumented I-710 station Near-roadway site

AQ-SPEC Field Testing (continued)

T and RH controlled: T (0-50 0C); RH (5-95%) AQ-SPEC Lab Testing Particle testing Particle generation system Particle monitors: mass concentration and size distribution Gas testing Gas generation / dilution system Gas monitors: CO, NOX, O3, SO2, H2S, CH4/NMHC T and RH controlled: T (0-50 0C); RH (5-95%)

AQ-SPEC Lab Testing (continued) Test for: Linearity of response (range) Accuracy & precision Lower detectable limit Concentration resolution Response time Interference equivalents RH and T influences Other T and RH controlled: T (0-50 0C); RH (5-95%)

www.aqmd.gov/aq-spec

www.aqmd.gov/aq-spec

www.aqmd.gov/aq-spec

Sensor vs FEM/FRM Method* Field Testing - Summary Manufacturer (Model) Type Pollutant(s) Cost Time Resolution Sensor vs FEM/FRM Method* HabitatMap (AirBeam) Optical PM2.5 ~$200 1 min R2~0.70 Dylos (DC1100) PM(0.5-2.5) ~$300 R2~0.85 Alphasense (OPC-N2) PM1 PM10 ~$400 15 sec R2~0.90 R2~0.80 Shinyei (PM Evaluation Kit) ~$1,000 MetOne (Neighborhood Sensor) ~$1,900 RTI (MicroPEM) ~$2,000 10 sec *Comparisons refer to 1-hr average data; results are still preliminary; laboratory evaluations needed to confirm field results

Sensor vs FEM/FRM Method* Field Testing – Summary (continued) Manufacturer (Model) Type Pollutant(s) Cost Time Resolution Sensor vs FEM/FRM Method* Smart Citizen Kit Metal oxide CO, NO2 ~$200 1 min R2(CO)~0.85 R2(NO2): unreliable Aeroqual (S-500) O3 ~$500 R2~0.85 Landtec (AQMesh AQM-5) Electrochem. CO, NO, NO2, SO2, and O3 ~$10,000 1-15 min R2(NO)~0.85 R2(NO2)<0.50 R2(O3)<0.50 R2(SO2): unreliable *Comparisons refer to 1-hr average data; results are still preliminary; laboratory evaluations needed to confirm field results

AirBeam PM Sensor AirBeam Sensor (3 units tested): Optical particle counter (non-FEM) PM2.5 count (hundred particles/ft3) and PM2.5 mass (ug/m3) Time resolution: 1-min Unit cost: ~$200 MetOne BAM (reference method): Beta-attenuation monitor (FEM) Measures PM2.5 Cost: ~$20,000 Time resolution: 1-hr GRIMM (reference method): Optical particle counter (FEM) Uses proprietary algorithms to calculate total PM, PM2.5, and PM1 from particle number measurements Cost: ~$25,000 and up Time resolution: 1-min

AirBeam PM Sensor (continued) Preliminary results: High intra-model variability Particle count conc. Good correlation with FEM Particle mass conc. Calibration issues AirBeam v2 recalibrated using field testing data 1-hr ave. R2~0.70

Dylos DC1100/DC1700 Dylos (3 units tested): Optical particle counter (non-FEM) Three different size fractions including PM(0.5-2.5) (used as an estimate of PM2.5) Time resolution: 1-min Cost: ~$300 MetOne BAM (reference method): Beta-attenuation monitor (FEM) Measures PM2.5 Cost: ~$20,000 Time resolution: 1-hr GRIMM (reference method): Optical particle counter (FEM) Uses proprietary algorithms to calculate total PM, PM2.5, and PM1 from particle number measurements Cost: ~$25,000 and up Time resolution: 1-min

Dylos DC1100/DC1700 (continued) Preliminary results: Modest intra-model variability Particle count conc. Good correlation with FEM Particle mass conc. Can be derived via FEM calibration 5-min ave. 5-min ave. 5-min ave. R2~0.80

SmartCitizen Kit Smart Citizen Kit (3 units tested): Metal-oxide sensor (non-FEM) CO (kOhm), NO2 (kOhm), Temperature (C) and Relative Humidity (%) Time resolution: 1-min Unit cost: ~$200 SCAQMD FRM instruments: CO instrument; cost: ~$10,000 Time resolution: 1-min NOx instrument; cost: ~$11,000 Meteorological station (wind speed, wind direction temperature, relative humidity, and pressure); cost: ~$5,000 http://www.smartcitizen.me/

SmartCitizen Kit (continued) 5-min ave. R2<0.80 1-hr ave. R2>0.95 1-hr ave. R2>0.95 Preliminary results: Low intra-model variability CO: good correlation with FRM NO2: no correlation with FRM Reliable T and RH data

AeroQUAL S-500 aeroQUAL S-500 (3 units tested): Metal-oxide sensor (non-FRM) Ozone (pphm) Temperature (C) and Relative Humidity (%) Time resolution: 1-min Unit cost: ~$500 SCAQMD FRM instruments: Ozone instrument; cost: ~$7,000 Time resolution: 1-min Meteorological station (wind speed, wind direction temperature, relative humidity, and pressure); cost: ~$5,000

AeroQUAL S-500 (continued) Preliminary results: Low intra-model variability Ozone conc. Good correlation with FEM Slight signal degradation over time (sensor replacement available) 1-hr ave. R2~0.85

Field Testing - Discussion PM (optical) sensors: Minimal down time Low intra-model variability Strong correlation (R2) with two different FEM instruments Sensor “calibration” may be needed Potential sources of error: Sensors cannot detect very small particles (e.g. <0.5 μm for Dylos) Bias in algorithms used to convert particle counts to particle mass Gaseous sensors: CO; NO; O3 (when measured alone): good correlation with FRMs O3 and/or NO2: low correlation with FRM (potential O3 NO2 interference) SO2: difficult to measure with current electrochemical sensors Chamber testing is necessary to fully evaluate the performance of these sensors All results are still preliminary

Upcoming SCAQMD Activities Low-Cost Sensors Continue w/ testing Identify good performing sensors Pilot sensor network deployment options Geographic/Area wide network applications Fence-line applications Characterization of industrial emissions and their impact on nearby communities US EPA Community Scale Air Toxics Grant Monitor HAP emissions from refineries / other industrial sources (e.g. port) Use ORS techniques (e.g. SOF, max-DOAS, other) and “low-cost” sensors to assess spatial / temporal dispersion of emissions on surrounding communities 3 year study in the Carson-Wilmington area EJ communities participation

Thank you!