Water Quality in San Francisco Bay J.A. Davis San Francisco Estuary Institute
u u Non-profit scientific organization u Programs: –Contaminant Monitoring and Research Program »Regional Monitoring Program »Aquatic Pesticide Monitoring Program –Regional Watershed Science Program –Regional Wetlands Monitoring Program –Biological Invasions
Regional Monitoring Program Innovative partnership between government, dischargers, and scientists Work closely with the Regional Board $ 3 million/year of stable funding Began in 1993 World class monitoring Major change in direction beginning in 2002
RMP Objectives Compare monitoring information to relevant water quality objectives and other guidelines Describe patterns and trends in contaminant concentration and distribution Describe general sources and loading of contamination to the Estuary Measure contaminant effects on selected parts of the Estuary ecosystem Synthesize and distribute information from a range of sources to present a more complete picture of the sources, distribution, fates, and effects of contaminants in the Estuary ecosystem
RMP Components Water Chemistry Aquatic Toxicity Sediment Chemistry Sediment Toxicity Bivalve Bioaccumulation Fish Pilot Studies Special Studies
303(d) Listed Chemicals u Draft list from 11/01 u High Priority –Mercury, PCBs u Medium –Chlordane, DDT, Dieldrin, Diazinon u Low –Selenium, Dioxins, Furans, Dioxin-like PCBs
303(d) “B” Listed Chemicals u Draft list from 11/01 –Copper –Nickel –PAHs –PBDEs –Sediment Toxicity
PCB Concentrations in San Francisco Bay Fish Fillets, 2000
Mercury Concentrations in San Francisco Bay Fish Fillets, 2000
ContaminantNPercent Above PCBs8090% Mercury13438% Dieldrin8019% Selenium1217% DDTs804% Chlordanes800% DioxinsNot yet available Comparisons to Screening Values
Conceptual Model of PCB Fate in the Bay
Predicted Long Term Trends in PCB Mass with Varying Loads
New Contaminants of Concern: Flame Retardants TetraBDEPentaBDE HexaBDE Sources: textiles, household and industrial products Use: reduces flame capacity of materials Max level: ppt (ng/L) Sacramento River water Concern: endocrine system disruption, bioaccumulation Triphenylphosphate
My Water Quality Report Card for the Bay Getting Better DDT, chlordane Sloooow improvement PCBs Staying the Same Hg Getting Worse PBDEs (?), Pyrethroids (?)