EDTA EthyleneDiamineTetraacetic Acid, a compound that forms strong 1:1 complexes with most metal ions. EDTA is a hexaprotic system, designated H 6 Y 2+.

Slides:



Advertisements
Similar presentations
Acids, Bases, and Solutions
Advertisements

Complexes Complex – Association of a cation and an anion or neutral molecule All associated species are dissolved None remain electrostatically effective.
EDTA Titrations. Chelation in Biochemistry Chelating ligands can form complex ions with metals through multiple ligands. This is important in many areas,
Section 8 Complex-Formation Titrations. Complex-Formation Titrations General Principles Most metal ions form coordination compounds with electron-pair.
Fractions of Dissociating Species in Polyligand Complexes When polyligand complexes are dissociated in solution, metal ions, ligand, and intermediates.
213 PHC 8 th lecture (1) Gary D. Christian, Analytical Chemistry, 6 th edition 1.
1 Acid-Base Properties of a Salt Solution  One of the successes of the Brønsted- Lowry concept of acids and bases was in pointing out that some ions can.
Acid / Base Equilibria A Practical Application of the Principles of Equilibrium.
Chapter 13 EDTA Titrations EthyleneDiamineTetraAcetic acid.
CHEMISTRY ANALYTICAL CHEMISTRY Fall
Complexes Complex – Association of a cation and an anion or neutral molecule Complex – Association of a cation and an anion or neutral molecule All associated.
The d-block Coordination Chemistry. Objectives Must Explain and use the terms ligand/complex/complex ion and ligand substitutions. Should Describe the.
ANALYTICAL CHEMISTRY CHEM 3811 CHAPTER 13
Complexation Titrations: Taking Advantage of Complexing Agents
Types of chemistry Although any type of chemical reaction may be used for titrimetric analysis, the most often used fall under the categories of: Bronsted.
Complexometric titrations
EDTA Titration EDTA = Ethylenediaminetetraacetic acid
Complexometric Reactions and Titrations
Chemistry Revision.
ACID AND BASES. ACIDS Acids are sour in taste Acids are sour in taste Present in fruit, vegetables and human body as well as obtained from the earth.
October 3, What is an acid? Acids are compounds that accept electrons from other chemicals known as bases. Many acids contain hydrogen. Acids taste.
And Neutralization. Acidic or basic is a chemical property Mixing them can cancel out their effects or neutralize them But 1st-water ionizes Water molecules.
What happens to the absorbed energy?. Energy soso s1s1 t1t1.
Objectives To describe the formation of ions from their parent atoms
Review for Tomorrow’s Test MolesStoichiometry Percent composition Empirical Formula.
Objectives To learn about reactions between strong acids and strong bases To learn about the reaction between a metal and a nonmetal To understand how.
Determining the Strengths of Acids and Bases
Acid/Base Chemistry Part II CHEM 2124 – General Chemistry II Alfred State College Professor Bensley.
Hydrolysis and Neutralization
DAILY QUESTION November 25, A neutralization reaction occurs between an ______ and a _______.
ACIDS and BASES Target: I will be able to define what makes something an acid or a base. I will be able to tell on a pH scale if something is an acid or.
Hydrolysis and Neutralization
Chapter 13 EDTA Titrations Lewis acid-base concept Lewis acid :electron pair acceptor metal Lewis base : electron pair donor ligand coordinate covalent.
Complexometric Determination of Calcium in Milk
Chapter 9 Complexation and Precipitation Titrations.
Chapter 13 “EDTA” Titrations It’s a Complex World Out There.
Acid-Base Notes. Acid- Compound that forms hydrogen ions (H + ) when dissolved in water Base – compounds that forms hydroxide ion (OH - ) when dissolved.
Acids and Bases in Solution. Acids  An acid is any substance that produces hydrogen ions (H+) in water.  Hydrogen ions cause the properties of acids.
ERT207 Analytical Chemistry Complexometric Titration
ERT207 Analytical Chemistry Complexometric Titration Pn Syazni Zainul Kamal PPK Bioproses.
Acids, Bases and pH Water molecules dissociate Dissociates into OH- and H+ Water is neutral because there are equal numbers of OH- and H+
Acid/Base Chemistry Science 10. Water – another view Normally we consider water as a covlent compound with the following formula: Normally we consider.
Acids, Bases, and Salts. pH pH – measure of the concentration of H + ions in a solution or how acidic or basic it is. Scale ranges from 0-14 Strong acids.
Properties of Acids and Bases Acids Bases *Taste sour*Taste Bitter *Turns blue litmus paper red*Turns red litmus paper blue *Reacts with metals*Produces.
 Usually consider solids (salts)  Dissolving in water – “like dissolves like” ◦ Forming aqueous solutions.  Remember pure liquids and solids are not.
Experiments in Analytical Chemistry -EDTA determination of Ca and Mg in water.
PH scale.
Acids and Bases Bundle 4: Water.
ACIDS, BASES and SALTS NaOH CaCl2.
ERT207 Analytical Chemistry Complexometric Titration
Chemistry of Life Unit 2 – Biology I.
Acids and Bases Bundle 4: Water.
Acids and Bases Bundle 4: Water.
Science ideas I need to know
Chapter 12 EDTA Titrations
Neutralisation Starter: What ions are found in acids?
Chapter 17: Complexation Reactions & Titrations
Knowledge Organiser – Formulae and equations
2.4 The pH Scale: Acids and Bases
Knowledge Organiser – Chemical Changes
Acids and Bases Bundle 4: Water.
Section 4 Acidic or Basic
How atoms form compounds
Revision on Chemical Changes
Acids & Bases Vocabulary.
Formulas Molecular formula represents the numbers and types of atoms in a molecule H2O, C6H12O6 Structural formula gives the arrangement of atoms 3-D models.
Revision on Chemical Changes
Solving weak acid equilibrium problems:
1)What is the pH of a M acid solution? pH = 3
Presentation transcript:

EDTA EthyleneDiamineTetraacetic Acid, a compound that forms strong 1:1 complexes with most metal ions. EDTA is a hexaprotic system, designated H 6 Y 2+. The highlighted, acidic hydrogen atoms are the ones that are lost upon metal-complex formation.

The neutral acid of EDTA is tetraprotic, with the formula H 4 Y. Or the disodium salt, Na 2 H 2 Y·2H 2 O But it is the most basic form that is associated with metal binding We can define α for each species as the fraction of EDTA in that form.

Fractional composition diagram for EDTA

The equilibrium constant for the reaction of a metal with a ligand is called the formation constant, K f, or the stability constant The number is called the conditional formation constant, or the effective formation constant. It describes the formation of MY n−4 at any particular pH.

Must be run ~ pH=10