Strain-induced Crystallization Shigeyuki Toki 、Igors Sics

Slides:



Advertisements
Similar presentations
Polymer network consists of long polymer chains which are crosslinked with each other and form a continuous molecular framework. All polymer networks (which.
Advertisements

(0,0) RECIPROCAL LATTICE (0,1) (1,1) (2,1) (3,1) REAL LATTICE a b a* b*
Cross-linked Polymers and Rubber Elasticity
Industrial chemistry Kazem.R.Abdollah Rubber 1.
Highly Permeable Polymer Membranes Containing Directed Channels for Water Purification Benjamin S. Hsiao, SUNY at Stony Brook, DMR The concept.
The main purposes of EnviroSync are to: (1) serve as an advocate for the MES-SR community (2) assess the state of existing SR facilities for MES research.
Wetting of Liquid Crystal Surfaces and Induced Smectic Layering at the Nematic-Liquid Interface* Masafumi Fukuto, 1 Oleg Gang, 2 Kyle J. Alvine, 3 Benjamin.
Solids Ch. 12.
Computing and Chemistry 3-41 Athabasca Hall Sept. 16, 2013.
REPORT ON X-RAY MEASUREMENT ON LHC COLLIMATOR MATERIALS AT BNL …with many thanks to: E. Quaranta CollUSM - October 17 th 2014 N. Simos, K. Aldogan, Z.
X-Ray Diffraction Spectroscopy RAMAN Microwave. What is X-Ray Diffraction?
CAREER: Rational Synthesis and Studies of Functionalized Carbon Nanotubes Stanislaus S. Wong, SUNY at Stony Brook, DMR Developing near-edge X-ray.
Results on IR and SBR samples To confirm our interpretation of the stress- optical diagrams, additional experiments were conducted on the samples prepared.
Crystallinity in Polymers
What Is a Synchrotron? From the BNL Website Introduction The human eye can see only visible light. It comes in the form of different wavelengths. These.
Role of Polymer architecture and tacticity on mechanical and flow behavior (R.M. Kannan, Wayne State University, DMR )  Experiments: Rheo-FTIR.
Ning Zhang and Michael Dudley Department of Materials Science and Engineering, Stony Brook University Ning Zhang and Michael Dudley Department of Materials.
Energy stored in a Stretched String When stretching a rubber band or a spring, the more we stretch it the bigger the force we must apply.
Hooke's Law The Physics of Springs.
Materials PHYA2. MATERIALS DENSITY, SPRINGS, STRESS AND STRAIN Topics 11, pp.162–173.
The Development of Laue Monochromator at X17B3 National Synchrotron Light Source in (111) diffraction intensities by severer of non-bending Si.
T. Oka, PRL 45,531 (1980) What is H 3 + ?  2y 2x  Equilateral triangle structure  Simplest stable polyatomic molecule  No stable excited electronic.
Influence of Branch Content on the Mechanical Properties of metallocene LLDPEs Ashraful Islam, Ibnelwaleed A. Hussein Department of Chemical Engineering.
Macromolecular Crystallography Summary of the July 18, 2007 Breakout Session.
John Miao Stanford Synchrotron Radiation Laboratory Stanford Linear Accelerator Center Crystallography without Crystals and the Potential of Imaging Single.
© Oxford Instruments Analytical Limited 2001 Introduction to Basic Crystallography - Zones in the EBSP In an Electron Backscatter Diffraction Pattern (EBSP),
Laser Assisted High Pressure Phase Transformation in SiC
Polymer Chemistry Polymer Characteristics and Classifications Ms. Mandel Honors Physical Science.
Pressure Quench of flow-induced crystallization Zhe Ma, Luigi Balzano, Gerrit W M Peters Materials Technology Department of Mechanical Engineering Eindhoven.
Multi-anvil at the NSLS Michael Vaughan Liping Wang Jiuhua Chen Baosheng Li Li Hélène Couvy Wei Liu Carey Koleda Bill Huebsch Ken Baldwin.
《Modern Research Methods in Polymer Science》
Directed Crystallization Precursor Structures in Polymers Benjamin S. Hsiao (Stony Brook University), DMR Using in-situ synchrotron SAXS techniques,
Recent Developments in the Characterization of Extreme-Anisotropic Void Populations in Advanced Thermal Coatings TA Dobbins 1, AJ Allen 1, J Ilavsky 1,2,D.
Introduction to Statistical Modeling Wei Zhu Department of Applied Mathematics & Statistics State University of New York at Stony Brook
Unit 1 Key Facts- Materials Hooke’s Law Force extension graph Elastic energy Young’s Modulus Properties of materials.
UNIVERSITY OF GUYANA FACULTY OF NATURAL SCIENCES DEPART. OF MATH, PHYS & STATS PHY 110 – PHYSICS FOR ENGINEERS LECTURE 12 (THURSDAY, NOVEMBER 17, 2011)
Polymers (see Roe: Methods of X-ray and Neutron Scattering in Polymer Science (2000)) Polymers (see Roe: Methods of X-ray and Neutron Scattering in Polymer.
Plans for the DAC Program at X-17 Short term (existing $90K) Purchase symmetric DACs and diamonds Install Laue-Laue mono in 17B3 (NSLS provides) Improve.
Feb 18 & 19, 2009 © Thayumanasamy Somasundaram 1 X-Ray Facility Overview IMB X-Ray Facility (IMB XRF) Kasha Laboratory
Neutron Alison Edwards Bragg Institute – ANSTO.
Department of Bioengineering Suture Performance Under Uniaxial Tensile Testing Group: 101A5 Ilan Epstein – Background & Hypothesis Neha Jha – Methods &
CHEMISTRY 1000 Topics of Interest #5: Quasicrystals.
BROOKHAVEN SCIENCE ASSOCIATES NSLS-II - New opportunities for high pressure research - Lars Ehm National Synchrotron Light Source Brookhaven National Laboratory.
Multi-anvil at the NSLS Michael Vaughan Liping Wang Jiuhua Chen Baosheng Li Carey Koleda Bill Huebsch Ken Baldwin Chris Young.
Hooke’s Law. Robert Hooke investigated springs and found that the distance a spring stretched(extension) of a spring was proportional to the force(load)
© Pearson Education Ltd 2008 This document may have been altered from the original Week 13 Objectives Define and use the terms stress, strain and Young.
…about graphing data -plot data on a graph with correct axes -include appropriate labels and units on a graph.
The reading is 7.38 mm. The reading is 7.72 mm.
Date of download: 10/18/2017 Copyright © ASME. All rights reserved.
Organic Chemistry Lesson 21 X-ray crystallography.
Electric Grid Technology Energy Storage Technology
10.8 Forces and elasticity Q1a. The limit of proportionality of a spring is where the extension is no longer proportional to the applied force.
Bio-Templated Photonic Crystals with a Complete Band Gap
POLYMERS Polymer Technology Thermoplastic Polymers
CIE IGCSE PHYSICS Forces – Hookes Law
Stretching springs and Hooke’s Law
Pull thin polymer rod in tension
Work Done by a Varying Force
Microstructures of GaSb grown on SiC and AlN Composite Substrates
Modified Fullerene Vesicles and Membranes,
C.2.10 Sample Questions.
C.2.8 Sample Questions.
Hooke’s law Hooke’s law states that the extension of a spring force is proportional to the force used to stretch the spring. F ∝ x ‘Proportional’
Modified at -
C.2.8 Sample Questions.
Multi-simultaneous.
The Constant-Q IIR Filterbank Approach to Spectral Flux
Forces From Continuous Charges
ELASTIC DEFORMATION.
Bell Ringer Aug. 26th Draw a picture of a physical change and a chemical change.
Presentation transcript:

Strain-induced Crystallization Shigeyuki Toki 、Igors Sics in Natural Rubber Shigeyuki Toki 、Igors Sics and Benjamin S. Hsiao Chemistry Department State University of New York at Stony Brook

Rubber Research by Synchrotron X-Rays Strain-induced crystallization and molecular orientation in natural and synthetic rubbers (NR, IR, BR, IIR) Effect of network density and filler Stress-strain relation and strain-induced crystallization and molecular orientation

Instrumentation and sample Synchrotron X-rays (NSLS at BNL) Modified Instron stretching machine Mar-CCD Original length 25 mm, constant stretching rate (10 mm/min).

Stress-strain relation and 2D and 3D WAXD patterns during extension and retraction in vulcanized NR at 25oC