Prentice Hall Copyright 2007 Chapter Sixteen Aldehydes and Ketones James E. Mayhugh Oklahoma City University  2007 Prentice Hall, Inc. Fundamentals of.

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Chapter Sixteen Aldehydes and Ketones James E. Mayhugh Oklahoma City University  2007 Prentice Hall, Inc. Fundamentals of General, Organic, and Biological.
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Prentice Hall Copyright 2007 Chapter Sixteen Aldehydes and Ketones James E. Mayhugh Oklahoma City University  2007 Prentice Hall, Inc. Fundamentals of General, Organic, and Biological Chemistry 5th Edition

Prentice Hall Copyright 2007 Outline 16.1 The Carbonyl Group 16.2 Naming Aldehydes and Ketones 16.3 Properties of Aldehydes and Ketones 16.4 Some Common Aldehydes and Ketones 16.5 Oxidation of Aldehydes 16.6 Reduction of Aldehydes and Ketones 16.7 Addition of Alcohols: Hemiacetals and Acetals

Prentice Hall Copyright The Carbonyl Group Carbonyl compound: Any compound that contains a carbonyl group, C=O. Carbonyl group: A functional group that has a C atom joined to an O atom by a double bond. The bond angles between the three substituents on the carbonyl carbon atom are 120°, or close to it.

Prentice Hall Copyright 2007

16.2 Naming Aldehydes and Ketones The simplest aldehydes are known by their common names, which end in -aldehyde, for example, formaldehyde, acetaldehyde, and benzaldehyde. In the IUPAC system, the -e ending of the alkane with the same number of C’s is replaced by -al. When substituents are present, the chain is numbered beginning with 1 for the carbonyl carbon. For example, 3-methylbutanal.

Prentice Hall Copyright 2007 Common names for ketones give the names of the two alkyl groups bonded to the carbonyl carbon followed by the word ketone. Ketones are named systematically by replacing the final -e of the alkane name with -one. The numbering of the chain begins at the end nearest the carbonyl group. The location of the carbonyl group is indicated by placing the number of the carbonyl carbon in front of the name. Using this nomenclature scheme, acetone would be named 2-propanone.

Prentice Hall Copyright 2007 Common names for ketones give the names of the two alkyl groups bonded to the carbonyl carbon followed by the word ketone. Ketones are named systematically by replacing the final -e of the alkane name with -one. The numbering of the chain begins at the end nearest the carbonyl group. The location of the carbonyl group is indicated by placing the number of the carbonyl carbon in front of the name. Using this nomenclature scheme, acetone would be named 2-propanone.

Prentice Hall Copyright Properties of Aldehydes and Ketones Aldehydes and ketones cannot hydrogen-bond with one another, so they are lower boiling than alcohols. Aldehydes and ketones are higher boiling than alkanes because of the polarity of the carbonyl group. Common aldehydes and ketones are liquids.

Prentice Hall Copyright 2007 Simple aldehydes and ketones are water-soluble due to hydrogen bonding with water molecules, and ketones are good solvents. Simple ketones are less toxic than simple aldehydes. Many aldehydes and ketones have distinctive odors. ►A perfumer sits at a mixing table testing new combinations of fragrances, many of which are aldehydes and ketones.