Table 15-1, p. 612. Common Names of Carboxylic Acids Table 15.1.

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Presentation transcript:

Table 15-1, p. 612

Common Names of Carboxylic Acids Table 15.1

Common Names of Dicarboxylic Acids Table 15.1

p. 614

p. 615

Fig. 15-1, p. 616

p. 616

Table 15-2, p. 615

p. 618

Fig. 9-16, p. 338 Electrophilic Aromatic Substitution

Fig. 9-16, p. 338 pKa’s of Substituted Benzoic Acids Lower pKa Higher pKa

p. 620 Preparation of Carboxylic Acids : Review 1.Oxidation of 1  alcohols: a. b.

p. 620 Preparation of Carboxylic Acids : Review 1.Oxidation of 1  alcohols: a. CrO 3, H 2 SO 4 b. K 2 Cr 2 O 7, H 3 O + 1.Oxidation of 1  alcohols:

p. 620 Preparation of Carboxylic Acids : Review 2. Oxidation of aldehydes: a. b. 1.Oxidation of 1  alcohols:

p. 620 Preparation of Carboxylic Acids : Review 2. Oxidation of aldehydes: a. CrO 3, H 2 SO 4 b. K 2 Cr 2 O 7, H 3 O + 1.Oxidation of 1  alcohols:

p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): b. carbon-carbon double bonds : i. ii. Methyl, 1°, 2°

p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): KMnO 4 b. carbon-carbon double bonds : i. ii. Methyl, 1°, 2°

p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): KMnO 4 b. carbon-carbon double bonds : i. (sect 8.8) KMnO 4 ii. Methyl, 1°, 2°

p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): KMnO 4 b. carbon-carbon double bonds : i. (sect 8.8) KMnO 4 ii. O 3, H 2 O 2 Methyl, 1°, 2°

p. 620 Preparation of Carboxylic Acids : Review 3. Oxidative cleavage a. of aryl benzenes (sect 9.10): KMnO 4 b. carbon-carbon double bonds : i. (sect 8.8) KMnO 4 ii. O 3, H 2 O 2 Methyl, 1°, 2°

p. 620 Preparation of Carboxylic Acids : 1.Oxidative Cleavage: a. O 3, H 2 O 2 2. Reduction of Carbon Dioxide: a. Examples b. Mechanism c. Limitations

p. 620 Preparation of Carboxylic Acids : 3. Hydrolysis of Nitriles a. Examples b. Limitations c. Mechanisms i.Acid catalyzed ii.Base catalyzed

p. 620 Preparation of Nitriles 1.From Alkyl Halides 2. From Amides

p. 620 Reactions of Nitriles with Reducing Agents 1.Lithium Aluminum Hydride 2. Grignard Reagents

Fig. 15-4, p. 627

p. 628

Fig. 15-5, p. 628

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