ADIABATIC WORK. Apparatus Insulated cylinder with movable piston and two side chambers, both initially evacuated, also with stirrer operated by electric.

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Presentation transcript:

ADIABATIC WORK

Apparatus Insulated cylinder with movable piston and two side chambers, both initially evacuated, also with stirrer operated by electric motor

Problem Compare the work done in three different processes, involving both quasi-equilibrium and non-equilibrium processes

Process a. Air is initially at State O. Move piston to compress air until State A is reached. Lock piston in place. Open the valve leading to chamber A. Unlock piston. Move piston until State C’ is reached

Process b. Air is initially at State O Air Move piston to compress air until State B is reached. Lock piston in place. Open the valve leading to chamber B. Unlock piston. Move piston until State C’ is reached

Process c. Air is initially at State O Piston remains fixed throughout process. Run stirrer until system reaches State C’

ENERGY CHANGE DEPENDS ON END STATES ONLY WORK DEPENDS ON END STATES AND HOW PROCESS IS CARRIED OUT (PROCESS PATH) SINCE U C’ - U O = O Q C’ - O W C’ IN GENERAL,