Electronic structure of ZnO from x-ray spectroscopy

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Presentation transcript:

Electronic structure of ZnO from x-ray spectroscopy Andrew Preston andrew@preston.co.nz

Co-authors Ben Ruck Louis Piper, Alex DeMasi and Kevin Smith Victoria University of Wellington Louis Piper, Alex DeMasi and Kevin Smith Boston University Andre Schleife, Frank Fuchs and Friedhelm Bechstedt Friedrich-Schiller-Universitat Jessica Chai and Steve Durbin University of Canterbury

Zinc oxide

Zinc oxide Zn2+ = [Ar]3d10 O2- = [Ne]

Zinc oxide (0001)

ZnO electronic structure

X-ray absorption (XAS) Ef Empty Filled

X-ray emission (XES) Empty Filled

ZnO electronic structure

ZnO XAS and XES

ZnO anisotropy O p orbitals ZnO crystal

ZnO anisotropy

ZnO anisotropy

ZnO XAS and XES

ZnO XAS and XES

ZnO XAS and XES

ZnO RXES

ZnO RXES

ZnO RXES

ZnO RXES

ZnO RXES

ZnO pxy band structure

ZnO pz band structure

Phys. Rev. B 78, 155114 (2008) (arXiv:0805.4641) andrew@preston.co.nz