Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Chapter 15. Work, Heat, and the First Law of Thermodynamics

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Heat and Work in Ideal-Gas Processes Consider a gas cylinder sealed at one end by a moveable piston. Assume KE =0 (cylinder not moving) and PE = 0 (cylinder position at y = 0). But since T > 0 kelvin, U int ≠ 0. For a monatomic gas: U = 3/2 nRT For non-monatomic gases, U is still proportional to T: U α T

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Heat and Work in Ideal-Gas Processes How can we change the amount of internal energy in our system of an ideal gas? We have studied 2 energy transfer mechanisms, heat (Q) and work (W). Let’s look at both of these mechanisms.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Review: What is the best definition of heat? A. the amount of thermal energy in an object. B. the energy that moves from a hotter object to a colder object. C. how high the temperature of an object is. D. all of the above

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. What is the best definition of heat? A. the amount of thermal energy in an object. B. the energy that moves from a hotter object to a colder object. C. how high the temperature of an object is. D. all of the above

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Heat, Temperature, and Thermal Energy Thermal energy U is an energy of the system due to the motion of its atoms and molecules. Any system has a thermal energy even if it is isolated and not interacting with its environment. The units of U are Joules. Heat Q is energy transferred between the system and the environment as they interact due to a difference in temperature. The units of Q are Joules. Temperature T is a state variable that quantifies the “hotness” or “coldness” of a system. A temperature difference is required in order for heat to be transferred between the system and the environment. The units of T are degrees Celsius or Kelvin.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. If heat is the only energy transfer mechanism ΔU = U f -U i = Q Q is positive when the system gains energy. This means that the environment has a higher temperature than the system. Q is negative when the system loses energy. This means that the environment has a lower temperature than the system.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Work done by the system and on the system W = |F| |Δx| cos θ If the piston moves to the right: Work done by the gas molecules on the piston is positive (force is to the right, piston moves to the right). energy is added to the piston, energy is taken away from the gas and the gas expands. If the piston moves to the left: Work done by the gas molecules on the piston is negative (force is to the right, gas molecules move left). Energy is added to the gas and the gas compresses.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley The First Law of Thermodynamics THE FIRST LAW OF THERMODYNAMICS The internal energy of a system changes due to heat and work: Work is positive when it is done by the system and negative when it is done on the system. Heat is positive when the system gains heat and negative when the system loses heat.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. A gas cylinder and piston are covered with heavy insulation so there can be no heat exchange with the environment. The piston is pushed into the cylinder, compressing the gas. According to the 1 st Law of Thermodynamics, the gas temperature: A.decreases. B. increases. C.doesn’t change. D.There’s not sufficient information to tell.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. ΔU = Q – W by insulation implies no heat exchange with environment Work done by gas is negative. Gas pushes left, piston compresses gas to the right: ΔU = Q – W by ΔU = – – W by ΔU is proportional to temperature increase. Therefore, temperature increases.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. EOC # 1 The internal energy of a system changes because the system gains 165 J due to heat transfer and does 312 J of work. In returning to its initial state *, the system loses 114 J of heat. a.How much work is involved during the return process? b.Is the work done by the system, or on the system ? * Initial state (for a gas) means same voloume, pressure, temperature, and internal energy.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. EOC # 1-Answer The internal energy of a system changes because the system gains 165 J due to heat transfer and does 312 J of work. In returning to its initial state *, the system loses 114 J of heat. a.How much work is involved during the return process? 261 J involved b.Is the work done by the system, or on the system? Work is done on the system.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley The First Law of Thermodynamics Example 2 An Ideal Gas The temperature of three moles of a monatomic ideal gas is reduced from 540K to 350K as 5500J of heat flows into the gas. Find (a) the change in internal energy and (b) the work done by the gas.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley The First Law of Thermodynamics (a) (b)

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley Thermal Processes isobaric: constant pressure isochoric: constant volume isothermal: constant temperature adiabatic: no transfer of heat Ideal Gas Processes

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley Thermal Processes An isobaric process is one that occurs at constant pressure. According to the 1 st Law of Thermodynamics: ΔU = Q – W by During an isobaric process: ΔU = Q – P ΔV: energy is transferred by both work and heat.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. The PV diagram for an work done during an isobaric process is a horizontal line

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. An isobaric process During an isobaric process, a system gains 1500 J of heat. The internal energy of the system increases b y 4500 J and the volume decreases by 0.01 m 3. Find the pressure of the system.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. An isobaric process During an isobaric process, a system gains 1500 J of heat. The internal energy of the system increases b y 4500 J and the volume decreases by 0.01 m 3. Find the pressure of the system. Answer: 3.0 x 10 5 Pa

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. The work done by the gas equals the area under the PV curve

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley Thermal Processes Example 4 Work and the Area Under a Pressure-Volume Graph Determine the work for the process in which the pressure, volume, and temp- erature of a gas are changed along the straight line in the figure. The area under a pressure-volume graph is the work for any kind of process.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley Thermal Processes Since the volume increases, the work is positive. Estimate that there are 9colored squares in the drawing.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Two process are shown that take an ideal gas from state 1 to state 3. Compare the work done by process A to the work done by process B. A. W A > W B B. W A < W B C. W A = W B = 0 D. W A = W B but neither is zero

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Two process are shown that take an ideal gas from state 1 to state 3. Compare the work done by process A to the work done by process B. A. W A > W B B. W A < W B C. W A = W B = 0 D. W A = W B but neither is zero

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley Thermal Processes isochoric: constant volume For the isochoric process the area under the curve is equal to zero. But W = PΔV = 0: during an isochoric process, energy is transferred by heat only

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley Thermal Processes Using and Ideal Gas ISOTHERMAL EXPANSION OR COMPRESSION Isothermal expansion or compression of an ideal gas ΔU = Q – W by But ΔU α ΔT If T does not change, ΔU = ΔT = 0! And Q = W

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. EXAMPLE The work of an isothermal compression QUESTION: A cylinder contains 7.0 g of N 2 gas. The gas compresses to half its volume at a constant temperature of 80˚C. a.How much work must be done by the gas? b.By how much does the internal energy of the gas change? c.How much heat was added or taken away from the gas?

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. EXAMPLE The work of an isothermal compression Answer: A cylinder contains 7.0 g of N 2 gas. The gas compresses to half its volume at a constant temperature of 80˚C. a.How much work must be done by the gas? -508 J (work was done on the gas to compress it) b.By how much does the internal energy of the gas change? 0J c.How much heat was added or taken away from the gas? 508 J of heat was taken away from the gas. Q – W by = 0

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley Thermal Processes Using and Ideal Gas ADIABATIC EXPANSION/COMPRESSION The red curve shows an adiabatic expansion of an ideal gas. The blue curves are isotherms at T i and T f. Adiabatic curves can be approximated as linear. According to the 1 st Law of Thermodynamics: ΔU = Q – W by but Q = 0, since walls are insulated ΔU = – W by For a monatomic ideal gas:

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Adiabatic Processes without adiabatic (insulating) walls Rapid expansion or compression does not allow the gas and surroundings to come to equilibrium –bicycle pump –air being forced to rise or sink due to atmospheric conditions –loading/ unloading a pneumatic lift.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Mass Lifter Lab – thermodynamic process with 4 steps 1.mass is loaded onto movable piston of a cylinder of gas kept at a low temperature. This is a “very rapid” event. Energy transfer due to temperature difference between gas and surroundings assumed to be negligible. 2.gas of cylinder is put in contact with room temperature water and energy transfer allowed. The mass rises. 3.mass is unloaded at a “rapid” pace. 4.gas of cylinder put in contact with ice water. The movable piston falls.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Molar specific heat capacity For a solid or liquid: Q = cm ∆T, where c is the specific heat capacity in Joules/kg kelvin. For a gas, we use number of moles (n) instead of mass: Q = Cn ∆T where C is the molar specific heat capacity in Joules/mol kelvin.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Molar specific heat capacity for a monatomic ideal gas At constant pressure C p = 5/2R At constant volume C v = 3/2R. Q = Cn ∆T ; so for the same amount of heat (Q) added to a gas, the gas at constant volume will show a greater temperature change because it is not losing energy by expanding.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Molar specific heat capacity Two containers hold equal masses of helium gas (monatomic) at equal temperature. You supply 10 J of heat to container A while not allowing the volume to change. You supply 10 J of heat to container B while not allowing the pressure to change. Is T fA greater than, less than or equal to T fB ? Explain, using the 1 st Law of Thermodynamics.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Molar specific heat capacity For an isochoric process: Q A = C v n ΔT = (3/2R)n ΔT A = 10J For an isobaric process: Q = C p n ΔT = (5/2R)n ΔT B = 10J ΔT A is greater than ΔT B

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. EOC # 33 Heat, Q, is added to a monatomic ideal gas at constant pressure. As a result, work, W is done by the gas. What is Q/W, the ratio of heat added to work done by the gas? This is a numerical value, with no variables.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. EOC # 33 Heat, Q, is added to a monatomic ideal work at constant pressure. As a result, work, W is done by the gas. What is Q/W, the ratio of heat added to work done by the gas? Q = C p nR ∆T = 5/2 nR ∆T W = P ∆V = PV f – PV i but PV = nR ∆T so W = nR ∆T Q/W = 5/2/1 = 2.5.

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Which of the following processes involve heat (energy transfer due to ∆T)? A.The brakes in your car get hot when you stop. B.You push a rigid cylinder of gas across a frictionless surface. C.A steel block is placed on top of a candle. D.You push a piston into a cylinder of gas, increasing the temperature of the gas. E.All of the above

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. Which of the following processes involve heat? A.The brakes in your car get hot when you stop. B.You push a rigid cylinder of gas across a frictionless surface. C.A steel block is placed on top of a candle. D.You push a piston into a cylinder of gas, increasing the temperature of the gas. E.All of the above

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. EOC #26 The drawing refers to 1 mole of a monatomic gas and a 4-step process. Complete the following table: ∆U W by Q A to B B to C C to D D to A

Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addison-Wesley. EOC #26 The drawing refers to 1 mole of a monatomic gas and a 4-step process. Complete the following table: ∆U W by Q A to B4990J3320J8310J B to C-4990J0J-4990J C to D-2490J-1660J-4150J D to A2490J0J2490J