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Published byAmbrose Stevens Modified over 9 years ago
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In a chemical reaction, one or more substances change into new/different substances According to the Law of Conservation of Mass a skeleton chemical equation must be balanced by placing COEFFICIENTS in front of chemical formula(s) NOTE – correct chemical formula can not be changed!!!!
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Lets look at a sample reaction: solid magnesium and hydrochloric acid react to form hydrogen gas and magnesium chloride solution Equations are used to describe chemical reactions Word Equation Magnesium + hydrochloric acid hydrogen gas + magnesium chloride Chemical Equation Mg + 2 HCl H 2 + MgCl 2
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Chemical Equation Mg + 2HCl H 2 + MgCl 2 Reactants Products
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When looking at a chemical equation, we often do not know what state the reactants or products are in State symbols are used to indicate the physical state of the chemicals in your equation at SATP. (s) = Solid (l) = Liquid (g) = Gas (aq) = aqueous, (dissolved in water)
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Chemical equation Mg + 2HCl H 2 + MgCl 2 Balanced chemical equation with state symbols Mg (s) + 2 HCl (aq) H 2(g) + MgCl 2 (aq)
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Although there are MILLIONS of possible chemical reactions, we are able to use patterns to identify/predict some general TYPES of reactions.
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SynthesisDecomposition Single Displacement Double Displacement Combustion (complete & incomplete)
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The direct combination of 2 substances (elements or compounds) to form a compound. General equation: A + B → AB A and B can be elements or compounds, AB is a compound.
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EXAMPLES OF SYNTHESIS Reactions: P 4 (s) + 5 O 2 (g) 2 P 2 O 5 (s) 2 Na (s) + Cl 2 (g) 2 NaCl (s) 2 Al (s) + 3 I 2 (g) 2 AlI 3 (s)
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Metal oxide + water base Na 2 O (s) + H 2 O (l) 2NaOH (aq) Non metal oxide + water acid CO 2(g) + H 2 O (l) H 2 CO 3(aq)
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Decomposition Reactions - The splitting up of a larger molecule into simpler substances (elements or compounds). - often require heat, light or electricity General Equation: AB→ A + B AB is a compound, A and B can be elements or compounds
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Electrolysis of water: 2 H 2 O (g) 2 H 2 (g) + O 2 (g) Nitrogen triiodide decomposing: 2 NI 3 (s) N 2 (g)+ 3 I 2 (s) Breaking down of sugar C 12 H 22 O 11 (s) 12 C (s) + 11 H 2 O (l) Electrolysis: the decomposition of a compound by an electric current
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Carbonate metal oxide + carbon dioxide Na 2 CO 3(s) Na 2 O (s) + CO 2(g) Bicarbonate metal oxide + carbon dioxide + water NaHCO 3(s) Na 2 O (s) + CO 2(g) +H 2 O (g) Hydrate compound + water Al(NO 3 ) 3 *5H 2 O (s) Al(NO 3 ) 3(s) + 5H 2 O (g)
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-one element takes the place of (displaces) another element in a compound -usually metals displace metals, and non metals displace non metals We use the metal activity series and halogen displacement series to help us predict single displacement reactions.
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General equation: A + BC → B + AC (A is a metal) or N + BC → B + CN (N is a non-metal) A, B, and N are elements/diatomic molecules. BC, AC and CN are compounds.
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EXAMPLES of Single Displacement Reactions: 2 Mg (s) + CO 2 (s) C (s) + 2 MgO (s) Cu (s) + 2 AgNO 3 (aq) Cu(NO 3 ) 2 (aq) + 2 Ag (s) thermite (steel making) Fe 2 O 3 (s) + 2 Al (s) 2 Fe (s) + Al 2 O 3 (s)
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Metals higher on the activity series table are stronger and end up with a partner!
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-Involves the displacement of “partners” -the metal cations in each reactant exchange places, elements in different compounds displace each other or exchange places. - a precipitate, a gas or a molecular compound is usually formed
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General equation: AB + CD → AD+ CB A,C = metal cations (simple or polyatomic cations) B,D = non metallic anions (simple or polyatomic anions ) *Remember, metals can only switch with metals, and non-metals can only switch with non-metals!
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2 NaOH (aq) + Cu(NO 3 ) 2 (aq) Cu(OH) 2 (s) + 2 NaNO 3 (aq) Colour of the precipitate formed: light blue 2 NaI (aq) + Pb(NO 3 ) 2 (aq) PbI 2 (s) + 2 NaNO 3 (aq) Colour of the precipitate formed: yellow Note – We use the solubility rules to predict the subscript of new products formed
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Combustion
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A chemical reaction in which a substance (often hydrocarbons like propane (C 3 H 8 ), methane (CH 4 ) and kerosene (C 10 H 22 ) ) reacts rapidly with OXYGEN and releases heat and light energy.
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The word equation for the COMPLETE COMBUSTION of a hydrocarbon: Δ Hydrocarbon +Oxygen → Carbon Dioxide + Water Vapour + Energy (light & heat) The general equation: C x H y +O 2 →CO 2 +H 2 O Eg. Propane in a BBQ Δ C 3 H 8 (g) +5 O 2 (g)→3 CO 2 (g) +4 H 2 O (g)
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Incomplete Combustion occurs when there is not enough O 2 available for complete combustion produces a mixture of CO, C, CO 2, and H 2 O vapour depending on the oxygen supply available
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Eg. Propane in a BBQ C 3 H 8 (g) + 3O 2 (g) → CO 2 (g) + 4H 2 O (g) + C (s) +CO (g) or C 3 H 8 (g) + 3O 2 (g) → 4H 2 O (g) + C (s) + 2CO (g) or C 3 H 8 (g) + 4O 2 (g) → CO 2 (g) + 4H 2 O (g) + 2CO (g) or 2C 3 H 8 (g) + 7O 2 (g) → 8H 2 O (g) + 6CO (g) or C 3 H 8 (g) + 2O 2 (g) → 4H 2 O (g) + 3C (s)
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