1. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.1 Schematic diagram of a double-focusing mass spectrometer.

2. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.2 Schematic diagram of a time-of-flight reflectron mass analyzer.

3. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.3 A cut-away view of the orbitrap mass analyzer. Ions are injected into the orbitrap at the point indicated by the arrow. Adapted with permission from [7]. Copyright 2005 John Wiley & Sons.

4. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.4 (a) Polyhedral representation of the shell of the Mo 72 Fe 30 sphere [light polyhedra FeO 6 octahedra, dark polyhedra Mo(Mo) 5 ]. (b) MALDI TOF mass spectra of the Mo 72 (Mo 6 )Fe 30 and their oligomers. Reproduced from [9] with permission of The Royal Society of Chemistry.

5. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.5 Isotope abundance patterns of some atoms and groups of atoms.

6. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.6 Simulation of part of a mass spectrum of [ReBr(CO) 5 ]. The weak peaks arise from ions containing 13 C, 17 O or 18 O.

7. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.7 An EI-MS spectrum of C 10 H 8 CrO 4.

8. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.8 Fragment ions observed after isolation and excitation of [PhAg 2 ] + (MS 3 mass spectrum) (a) by CID and (b) UV/vis photodissociation ( = 290 nm). Adapted with permission from [11]. Copyright 2011 American Chemical Society.

9. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.9 Comparison of an experimental photofragmentation spectrum and the calculated absorption spectrum for the lowest energy isomer of [PhAg 2 ] + (shown in inset). The analysis of the excitations is given in the right panel of the figure. Adapted with permission from [11]. Copyright 2011 American Chemical Society.

10. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.10 Reaction scheme of a ruthenium benzylidene complex showing the formation of a reactive intermediate (compound 2) and final product (compound 3), along with the mass spectrum obtained after isolation of compound 2 and subsequent reaction with 1-butene. Adapted with permission from [12]. Copyright 1998 John Wiley & Sons.

11. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.11 GC-MS spectrum showing the presence of 1,5-diaza-2,4,6,8-tetrasila-[3,3,0]- bicyclooctane.

12. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.I

13. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.II

14. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.III

15. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.IV

16. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.V

17. Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. Morrison @ 2013 John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.VI