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PROBLEMS CH 15
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 2 Learning Check Identify each as aldo- or keto- and as tetrose, pentose, or hexose. A. B.
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Solution Identify each as aldo- or keto- and as tetrose, pentose or hexose. A. B. aldohexose ketopentose
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 4 Learning Check Identify each as the D or L isomer. A.B. C. __-Ribose __-Threose __-Fructose
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 5 Solution Identify each as the D or L isomer. A.B. C. __-Ribose __-Threose __-Fructose LLD
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Learning Check Draw the Fischer projection of D -fructose.
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 7 Solution Draw the Fischer projection of D -fructose.
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 8 Learning Check Draw the Haworth structure of - D -galactose.
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 9 Solution Step 1 Turn the open-chain Fischer projection clockwise by 90 .
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 10 Step 2 Fold the horizontal carbon chain into a hexagon and bond the O on carbon 5 to the carbonyl group to form the hemiacetal. Solution
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Step 3 Complete the Haworth structure by drawing the – OH group on carbon 1 below the ring to give the α anomer, or above the ring to give the β anomer.
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 12 Learning Check Write the products of the oxidation and reduction of D -Mannose. D -Mannose
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 13 Solution Write the products of the oxidation and reduction of D -Mannose. D -Mannitol D -Mannose D -Mannonic acid
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Learning Check Identify the monosaccharides in each of the following. 1. lactose A. - D -glucose B. - D -fructose C. - D -galactose 2. maltose A. - D -glucose B. -D-fructose C. - D -galactose 3. sucrose A. - D -glucose B. - D -fructoseC. - D -galactose
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Solution Identify the monosaccharides in each of the following. 1. lactose A. - D -glucose C. - D -galactose 2. maltose A. - D -glucose 3. sucrose A. - D -glucose B. - D -fructose
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© 2013 Pearson Education, Inc. Chapter 15, Section 1 16 Identify the polysaccharides and types of glycosidic bonds in each of the following. A. B. Learning Check
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Solution Identify the polysaccharides and types of glycosidic bonds in each of the following. A.Cellulose -1,4-glycosidic bonds B. Amylose -1,4-glycosidic bonds Amylopectin -1,4- and -1,6-glycosidic bonds
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