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AN INTRODUCTION TO ATOM ECONOMY KNOCKHARDY PUBLISHING 2015 SPECIFICATIONS
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INTRODUCTION This Powerpoint show is one of several produced to help students understand selected topics at AS and A2 level Chemistry. It is based on the requirements of the AQA and OCR specifications but is suitable for other examination boards. Individual students may use the material at home for revision purposes or it may be used for classroom teaching with an interactive white board. Accompanying notes on this, and the full range of AS and A2 topics, are available from the KNOCKHARDY SCIENCE WEBSITE at... www.knockhardy.org.uk/sci.htm KNOCKHARDY PUBLISHING ATOM ECONOMY ©HOPTON
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ATOM ECONOMY ©HOPTON
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ATOM ECONOMY In most reactions you only want to make one of the resulting products Atom economy is a measure of how much of the products are useful A high atom economy means that there is less waste ©HOPTON
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ATOM ECONOMY In most reactions you only want to make one of the resulting products Atom economy is a measure of how much of the products are useful A high atom economy means that there is less waste ATOM ECONOMY ©HOPTON MOLECULAR MASS OF DESIRED PRODUCT x 100 SUM OF MOLECULAR MASSES OF ALL PRODUCTS MOLECULAR MASS OF DESIRED PRODUCT x 100 SUM OF MOLECULAR MASSES OF ALL PRODUCTS
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WORKED CALCULATIONS ©HOPTON
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WORKED CALCULATIONS Calculate the atom economy for the formation of 1,2-dichloroethane, C 2 H 4 C l 2 ©HOPTON Example1
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WORKED CALCULATIONS Calculate the atom economy for the formation of 1,2-dichloroethane, C 2 H 4 C l 2 EquationC 2 H 4 + C l 2 ——> C 2 H 4 C l 2 M r 28 71 99 ©HOPTON Example1
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WORKED CALCULATIONS Calculate the atom economy for the formation of 1,2-dichloroethane, C 2 H 4 C l 2 EquationC 2 H 4 + C l 2 ——> C 2 H 4 C l 2 M r 28 71 99 atom economy =molecular mass of C 2 H 4 C l 2 x 100 molecular mass of all products ©HOPTON Example1
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WORKED CALCULATIONS Calculate the atom economy for the formation of 1,2-dichloroethane, C 2 H 4 C l 2 EquationC 2 H 4 + C l 2 ——> C 2 H 4 C l 2 M r 28 71 99 atom economy =molecular mass of C 2 H 4 C l 2 x 100 molecular mass of all products =99 x 100 = 100% 99 ©HOPTON An ATOM ECONOMY of 100% is typical of an ADDITION REACTION Example1
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WORKED CALCULATIONS Calculate the atom economy for the formation of 1,2-dichloroethane, C 2 H 4 C l 2 EquationC 2 H 4 + C l 2 ——> C 2 H 4 C l 2 M r 28 71 99 atom economy =molecular mass of C 2 H 4 C l 2 x 100 molecular mass of all products =99 x 100 = 100% 99 ©HOPTON An ATOM ECONOMY of 100% is typical of an ADDITION REACTION Example1
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WORKED CALCULATIONS Calculate the atom economy for the formation of nitrobenzene, C 6 H 5 NO 2 ©HOPTON Example2
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WORKED CALCULATIONS Calculate the atom economy for the formation of nitrobenzene, C 6 H 5 NO 2 EquationC 6 H 6 + HNO 3 ——> C 6 H 5 NO 2 + H 2 O M r 78 63 12318 ©HOPTON An ATOM ECONOMY of 100% is not possible with a SUBSTITUTION REACTION Example2
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WORKED CALCULATIONS Calculate the atom economy for the formation of nitrobenzene, C 6 H 5 NO 2 EquationC 6 H 6 + HNO 3 ——> C 6 H 5 NO 2 + H 2 O M r 78 63 12318 atom economy = molecular mass of C 6 H 5 NO 2 x 100 molecular mass of all products ©HOPTON Example2
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WORKED CALCULATIONS Calculate the atom economy for the formation of nitrobenzene, C 6 H 5 NO 2 EquationC 6 H 6 + HNO 3 ——> C 6 H 5 NO 2 + H 2 O M r 78 63 12318 atom economy = molecular mass of C 6 H 5 NO 2 x 100 molecular mass of all products =123 x 100 = 87.2% 123 + 18 ©HOPTON Example2
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WORKED CALCULATIONS Calculate the atom economy for the formation of nitrobenzene, C 6 H 5 NO 2 EquationC 6 H 6 + HNO 3 ——> C 6 H 5 NO 2 + H 2 O M r 78 63 12318 atom economy = molecular mass of C 6 H 5 NO 2 x 100 molecular mass of all products =123 x 100 = 87.2% 123 + 18 ©HOPTON An ATOM ECONOMY of 100% is not possible with a SUBSTITUTION REACTION Example2
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WORKED CALCULATIONS Calculate the atom economy for the preparation of ammonia from the thermal decomposition of ammonium sulphate. ©HOPTON Example3
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WORKED CALCULATIONS Calculate the atom economy for the preparation of ammonia from the thermal decomposition of ammonium sulphate. Equation(NH 4 ) 2 SO 4 ——> H 2 SO 4 + 2NH 3 M r 132 98 17 ©HOPTON Example3
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WORKED CALCULATIONS Calculate the atom economy for the preparation of ammonia from the thermal decomposition of ammonium sulphate. Equation(NH 4 ) 2 SO 4 ——> H 2 SO 4 + 2NH 3 M r 132 98 17 atom economy = 2 x molecular mass of NH 3 x 100 molecular mass of all products ©HOPTON Example3
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WORKED CALCULATIONS Calculate the atom economy for the preparation of ammonia from the thermal decomposition of ammonium sulphate. Equation(NH 4 ) 2 SO 4 ——> H 2 SO 4 + 2NH 3 M r 132 98 17 atom economy = 2 x molecular mass of NH 3 x 100 molecular mass of all products =2 x 17= 25.8% 98 + (2 x 17) ©HOPTON Example3
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WORKED CALCULATIONS Calculate the atom economy for the preparation of ammonia from the thermal decomposition of ammonium sulphate. Equation(NH 4 ) 2 SO 4 ——> H 2 SO 4 + 2NH 3 M r 132 98 17 atom economy = 2 x molecular mass of NH 3 x 100 molecular mass of all products =2 x 17= 25.8% 98 + (2 x 17) ©HOPTON In industry a low ATOM ECONOMY isn’t necessarily that bad if you can use some of the other products. If this reaction was used industrially, which it isn’t, the sulphuric acid would be a very useful by-product. Example3
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CALCULATIONS Calculate the atom economy of the following reactions (the required product is shown in red) CH 3 COC l + C 2 H 5 NH 2 ——> CH 3 CONHC 2 H 5 + HC l C 2 H 5 C l + NaOH ——> C 2 H 5 OH + NaCl C 2 H 5 C l + NaOH ——> C 2 H 4 + H 2 O + NaC l ©HOPTON
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CALCULATIONS Calculate the atom economy of the following reactions (the required product is shown in red) CH 3 COC l + C 2 H 5 NH 2 ——> CH 3 CONHC 2 H 5 + HC l C 2 H 5 C l + NaOH ——> C 2 H 5 OH + NaCl C 2 H 5 C l + NaOH ——> C 2 H 4 + H 2 O + NaC l ©HOPTON 70.2%
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CALCULATIONS Calculate the atom economy of the following reactions (the required product is shown in red) CH 3 COC l + C 2 H 5 NH 2 ——> CH 3 CONHC 2 H 5 + HC l C 2 H 5 C l + NaOH ——> C 2 H 5 OH + NaCl C 2 H 5 C l + NaOH ——> C 2 H 4 + H 2 O + NaC l ©HOPTON 70.2% 55.8%
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CALCULATIONS Calculate the atom economy of the following reactions (the required product is shown in red) CH 3 COC l + C 2 H 5 NH 2 ——> CH 3 CONHC 2 H 5 + HC l C 2 H 5 C l + NaOH ——> C 2 H 5 OH + NaCl C 2 H 5 C l + NaOH ——> C 2 H 4 + H 2 O + NaC l ©HOPTON 70.2% 55.8% 33.9%
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OVERVIEW ©HOPTON
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OVERVIEW addition reactions will have 100% atom economy substitution reactions will have less than 100% atom economy elimination reactions will have less than 100% atom economy ©HOPTON
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OVERVIEW addition reactions will have 100% atom economy substitution reactions will have less than 100% atom economy elimination reactions will have less than 100% atom economy high atom economy= fewer waste materials = GREENER and MORE ECONOMICAL ©HOPTON
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OVERVIEW addition reactions will have 100% atom economy substitution reactions will have less than 100% atom economy elimination reactions will have less than 100% atom economy high atom economy= fewer waste materials = GREENER and MORE ECONOMICAL The percentage yield of a reaction must also be taken into consideration. some reactions may have a high yield but a low atom economy some reactions may have a high atom economy but a low yield ©HOPTON
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OVERVIEW addition reactions will have 100% atom economy substitution reactions will have less than 100% atom economy elimination reactions will have less than 100% atom economy high atom economy= fewer waste materials = GREENER and MORE ECONOMICAL The percentage yield of a reaction must also be taken into consideration. some reactions may have a high yield but a low atom economy some reactions may have a high atom economy but a low yield Reactions involving equilibria must also be considered ©HOPTON
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©2015 JONATHAN HOPTON & KNOCKHARDY PUBLISHING THE END AN INTRODUCTION TO ATOM ECONOMY ©HOPTON
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