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Published byCarmel Adams Modified over 8 years ago
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Hess’s Law
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Enthalpy is a State Variable ‘State variable’ just means something that doesn’t change depending on the path you take to get from A to B. If you start at the bottom of K2, your overall change in altitude is the same no matter which route you take up.
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For Chemistry Purposes This means that if you don't know the H for a reaction, you can figure it out by using the ones for any other reactions that start and end at the same point: A A B C If you put 100 kJ in to go from A to C and get 40 kJ out from C to B then it must be 60 kJ in from A to B
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Example Reaction Let's burn some random compound: 2C 7 H 10 O 2 + 17O 2 → 14CO 2 + 10H 2 O H = ???? Since we picked this compound arbitrarily, we probably have no idea how much energy we'll get from burning it. BUT! If we can find a set of reactions that, when combined, start with 2C 7 H 10 O 2 and 17 oxygens, and end with 14 carbon dioxides and 10 waters, their individual H values will add up to our desired value
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This Is Not Easy Finding the right reactions can be...problematic. There are some shortcuts, though: If you're interested, or planning on taking AP chem, look up “heat of formation” or “enthalpy of formation”
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Summary Enthalpy is a state function (path doesn't matter) You can use a series of reactions to get H The details can be messy, but there are shortcuts
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