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Published byMervyn James Modified over 8 years ago
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Each atom in a molecule can be thought of as having a Formal Charge Formal Charge = difference between the number of valence electrons on the free atom minus number of valence electrons assigned to the atom in the molecule
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Atoms in molecules try to achieve formal charges as close to zero as possible Example: Based on the two Lewis structures for sulfate, which is the best representation for the molecule?
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Energy, in kJ, required to break a bond in 1 mole of a compound Bond energies given in Table 8.4 (pg. 374)
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Bond energies can be used to calculate an approximate energy of reaction H can be thought of as the energies required to break old bonds plus the energies released when new bonds are formed H = D(bonds broken) - D(bonds formed)
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Use bond energies to calculate the H for the reaction of methane with chlorine and fluorine to give freon (CF 2 Cl 2 ) CH 4 + 2Cl 2 + 2F 2 CF 2 Cl 2 + 2HF + 2HCl
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