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Published byElwin Anderson Modified over 9 years ago
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colligative property- depends on the # of particles dissolved in a given amount of solvent *ionic produces greater result than molecular because they dissociate Ex: vapor pressure and freezing point lowering boiling point and osmotic pressure increase
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ex: How many particles? CaCℓ 2 3 NaCℓ 2 C 6 H 12 O 6 1
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-vapor pressure lowers when solute is added WHY? -IMF of particles makes it harder to escape to gaseous phase, lowering vapor pressure
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ideal solution- obeys Raoult’s Law -implies total uniformity of interaction -all molecules influence each other the same way (sol-sol, solv-solv, solv-sol are indistinguishable) *real solutions are more like ideal solutions when solute conc. is low and solute and solvent have similar sizes and take part in similar types of intermolecular attractions
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Boiling point Elevation -bp of solution is higher than that of the pure solvent *adding solute lowers vapor pressure and a higher temp is needed to get to 1 atm for normal bp -page 533
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Freezing Point Depression -fp of solution is lower than that of the pure solvent *adding solute lowers vapor pressure so a lower temp is needed to freeze at 1atm -page 534
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page 540 A Closer Look
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