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213 PHC Dr. Mona AlShehri 5th Lecture
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(1) Gary D. Christian, Analytical Chemistry, 6 th edition.
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Explain the different stages of strong and weak acid-base titration curves. Calculate the pH at these stages.
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Titration curves
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An acid-base titration involves a neutralization reaction ( an acid is reacted with equivalent amount of base) A titration curve is constructed by plotting the pH of the solution as a function of the volume of the titrant added The titrant is always a strong acid or base The analyte may be either a strong acid or base or a weak acid or base
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Both titrant (NaOH) and analyte (HCl) are completely ionized e.g. titration of HCl with NaOH HCl + NaOH NaCl + H 2 O
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Both titrant (HCl)and analyte (NaOH)are completely ionized e.g. titration of NaOH with HCl NaOH + HCl NaCl + H 2 O
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The analyte (CH 3 COOH) is partially ionized e.g. titration of CH 3 COOH with NaOH CH 3 COOH + NaOH CH 3 COONa + H 2 O
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The analyte (NH 3 ) is partially ionized e.g. titration of NH 3 with HCl NH 3 + HCl NH 4 Cl
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Strong and weak acid-base titration curves. pH calculations.
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