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Published byRosalind Gallagher Modified over 8 years ago
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CH1120
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Vary with respect to chemical properties but share some physical properties ◦ Low molar masses ◦ Non-metallic ◦ Expand spontaneously to fill container ◦ Volume of gas = volume of container ◦ Compressible ◦ Form homogeneous mixtures readily All physical properties arise due to molecules being relatively far apart
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At room temperature: ◦ He ◦ Ne ◦ Ar ◦ Kr ◦ Xe ◦ H 2 ◦ N 2 ◦ O 2 ◦ F 2 ◦ Cl 2
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An increase in volume at a constant temperature causes pressure to decrease ◦ Syringe filled with air A temperature increase at constant volume causes pressure to increase ◦ Balloon in winter
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SI unit = Pascal (Pa) 1Pa = 1N/m 2 1bar = 10 5 Pa 1atm = 760 torr = 760mmHg 1atm = 101.3Pa
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Remember how to calculate K K = ℃ + 273.15 Used in gas law equations
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An inflated balloon has a volume of 6.0L at sea level (1.0atm) and is allowed to ascend until the pressure is 0.45atm. During ascent, the temperature of the gas falls from 22℃ to -21℃. Calculate the volume of the balloon at its final altitude.
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Each gas behaves independently of other gases in a mixture At constant temperature and constant volume the total pressure of a gas sample is determined by the total number of moles of gas present
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Hypothetical gas whose pressure, volume, and temperature relationship are described completely by the ideal gas equation ◦ The molecules do not interact with one another ◦ The volume of the molecules is much smaller than the volume the gas occupies so we assume the molecules take up no space in the container Very small error is introduced with these assumptions so it is acceptable ◦ When accurate calculations are needed we can correct for the assumptions
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Unit depend on units of P, V, n, and T T in Kelvin n is in mols P usually atm V usually L
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UnitsNumerical Value 0.0820582 8.314472 1.987 8.314 62.4
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Calcium carbonate, CaCO 3(s) decomposes upon heating to CaO (s) and CO 2(g). A sample of CaCO 3 is decomposed, and the carbon dioxide is collected in a 250mL flask. After decomposition is complete, the gas has a pressure of 1.3atm at a temperature of 31℃. How many moles of CO 2 gas were generated? Use R to determine the units for all of the other components of your equation.
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When silver oxide is heated, it decomposes according to the reaction below. If 5.76g of Ag2O is heated and the O2 gas produced by the reaction is collected in a 0.65L flask at 25℃ what is the pressure of the O2 in the flask? 2Ag 2 O (s) 4Ag (s) + O 2(g)
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0℃ and 1atm are referred to as STP ◦ Standard temperature and pressure
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A sample of pure helium gas occupies a volume of 6.8 L at STP, how many grams of helium are present?
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