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Published byLionel Ramsey Modified over 8 years ago
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When non-metals combine together they share electrons to form molecules A covalent bond is a shared pair of electrons Non-metal + non-metal → Covalent bonding There are two types of covalently bonded structures: Simple molecular (small molecules) Macromolecular (giant structures)
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In some cases a large number (millions) of atoms join together by covalent bonding All the bonds are covalent This produces giant covalent structures not simple molecules Also called a macromolecular structure Diamond, graphite and silicon dioxide have giant covalent structures
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Diamond has a giant covalent structure Diamond is made from carbon atoms Each carbon atom is covalently bonded to four other carbon atoms All the carbon atoms are held together by strong covalent bonds C C C C C Carbon atom Strong covalent bond
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Diamond Mine is located in Russia
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Diamond only contains strong covalent bonds Therefore it is very hard and chemically unreactive It has high melting and boiling points as a lot of energy is needed to break the strong covalent bonds Diamond does not conduct electricity as it has no free electrons or ions
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Uses of diamond: Cutting tools and Jewellery
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Silicon dioxide (SiO 2 ) has a giant covalent structure Silicon dioxide has a similar structure to diamond It contains silicon and oxygen atoms instead of carbon atoms All the atoms are held together by strong covalent bonds
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Graphite has a giant covalent structure Graphite contains only carbon atoms Each carbon atom is covalently bonded to three other carbon atoms The carbon atoms are arranged in layers The carbon atoms in the layers are arranged in hexagons The layers are held by intermolecular forces Strong covalent bond Weak forces
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Strong covalent bonds between carbon atoms in the layers Weak intermolecular forces between the layers
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Each carbon atom is covalently bonded to three other carbon atoms Therefore only three of the four electrons in the outer shell of the carbon atom (2,4) are used This leaves one free electron on carbon The layers in graphite contains delocalised electrons The electrons can carry a current
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Graphite is soft and slippery The layers can slide over each other because the weak intermolecular forces are easily broken Graphite conducts electricity It has high melting and boiling points as a lot of energy is needed to break the strong covalent bonds http://www.youtube.com/wat ch?v=1IyTMvH4wJU&feature=f vwrel
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Uses of graphite: Pencils The layers slide off and end up on the paper Lubricant Graphite is slippery and allows objects to move easily
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How do the different properties of diamond and graphite depend on their structures?
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