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Published byNigel Phelps Modified over 8 years ago
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The kinetic theory assumes the following concepts about gasses are true: Gas particles do not attract or repel each other Gas particles are much smaller than the distances between them. Gas particles are in constant, random motion. No kinetic energy is lost when gas particles collide with each other or with the walls of their container (elastic collisions). All gasses have the same average kinetic energy at a given temperature.
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The following four variables work together to determine the behavior of gasses: Temperature Pressure Volume Number of particles present
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STP = Standard Temperature and Pressure =0.00 ⁰C and 1.00 atm. Temperature: Kelvin (K) ONLY!!!! ⁰C + 273 = K
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Pressure: Atmospheres (atm) ONLY!!! 1 atm = 101.3 kPa 1 atm = 760 mm Hg 1 atm = 760 torr 1 atm = 14.7 psi Volume: Liters (L) ONLY!!!!! 1000 mL = 1 L
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When pressure increases, volume will decrease (with constant temperature) When pressure decreases, volume will increase (with constant temperature) P 1 V 1 = P 2 V 2 P = Pressure V = Volume
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ITS ALL ABOUT PRESSURE AND VOLUME P 1 V 1 = P 2 V 2
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As temperature increases, so does the volume of a gas sample when the pressure is held constant. This is because at higher temperatures, gas particles move faster and strike each other and the walls of the container more frequently and with greater force. For the pressure to stay constant, the volume must increase so the particles have further to travel before striking the walls.
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Avogadro’s Principle states that equal volumes of gasses at the same temperature and pressure contain equal number of particles. Remember from ch 11: 1 mole contains 6.022 × 10 23 particles The molar volume for a gas is the volume that one mole occupies at 0.00 ⁰C and 1atm pressure. AKA STP. Avogadro showed that one mole of any gas will occupy a volume of 22.4L at STP. Because the volume of one mole of a gas at STP is 22.4L, you can use the following conversion factor to find moles, mass or particles in a gas sample 22.4L = 1 Mole
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