1. Welcome to AP Chemistry

2. What is AP Chemistry? l It is several things l Equivalent of 1 year college inorganic chemistry class l A class that will prepare you for a test –May 5 th l Hard work l A wonderful way to start the day l Now on to the details

3. Rules and Procedures l You know the basic rules but here are a few that are specific for this class l No food drink or gum l LATE WORK l Only accepted with an excused absence for all pop quizzes, tests, and labs l I will not accepted it any later.

4. Rules and Procedures l MAKE-UP WORK l It is your responsibility to make up all the work you missed. You have the same number of days that you were absent to turn in the missing work. l Pick up any missing work, and notes before or after class OR on our website. l If you miss a test or quiz, it must be made up outside class.

5. Rules and Procedures l TARDIES l 1 st period goes to the tardy table l Tardy on lab day (excused or unexcused): –if you are unable to finish the lab then you must come to lab make up after school. l Unexcused tardy on test day : –if you are unable to finish the test then you WILL NOT get extra time

6. Rules and Procedures l PASSES l Since every minute of class time is valuable, hall passes will be given at the teachers discretion.

7. Rules and Procedures l LAB- Because of the importance of safety in the lab, violation of laboratory safety rules and procedures may result in loss of lab privileges.

8. What you need for class l Paper l Pencil or pen, l Calculator- scientific l Book? –Not unless I let you know l Lab Notebook

9. AP ® Chemistry Curriculum Changes in matter involve the rearrangement and/or reorganization of atoms and/or the transfer of electrons. B I G I D E A 3 Rates of chemical reactions are determined by details of the molecular collisions. B I G I D E A 4 Chemical and physical properties of materials can be explained by the structure and the arrangement of atoms, ions, or molecules and the forces between them. B I G I D E A 2 The chemical elements are fundamental building materials of matter, and all matter can be understood in terms of arrangements of atoms. These atoms retain their identity in chemical reactions. B I G I D E A 1 The laws of thermodynamics describe the essential role of energy and explain and predict the direction of changes in matter. B I G I D E A 5 Any bond or intermolecular attraction that can be formed can be broken. These two processes are in a dynamic competition, sensitive to initial conditions and external perturbations. B I G I D E A 6

10. Significant figures l Meaningful digits in a MEASUREMENT l Exact numbers are counted, have unlimited significant figures l If it is measured or estimated, it has sig figs. l If not it is exact. l All numbers except zero are significant. l Some zeros are, some aren’t

11. Which zeroes count? l In between other sig figs does l Before the first number doesn’t l After the last number counts iff l it is after the decimal point l the decimal point is written in l 3200 2 sig figs l 3200. 4 sig figs

12. Doing the math l Multiplication and division, same number of sig figs in answer as the least in the problem l Addition and subtraction, same number of decimal places in answer as least in problem.

13. More Preliminaries Scientific Method Metric System Uncertainty

14. Scientific method. l A way of solving problems l Observation- what is seen or measured l Hypothesis- educated guess of why things behave the way they do. (possible explanation) l Experiment- designed to test hypothesis l leads to new observations, l and the cycle goes on

15. Scientific method. l After many cycles, a broad, generalizable explanation is developed for why things behave the way they do l Theory l Also regular patterns of how things behave the same in different systems emerges l Law l Laws are summaries of observations

16. Scientific method. l Theories have predictive value. l The true test of a theory is if it can predict new behaviors. l If the prediction is wrong, the theory must be changed. l Theory- why l Law - how

17. Observations Hypothesis Experiment Law Theory (Model) Prediction Experiment Modify

18. Metric System l Every measurement has two parts l Number l Scale (unit) l SI system (le Systeme International) based on the metric system l Prefix + base unit l Prefix tells you the power of 10 to multiply by - decimal system -easy conversions

19. Metric System l Base Units l Mass - kilogram (kg) l Length- meter (m) l Time - second (s) l Temperature- Kelvin (K) l Electric current- ampere (amp, A) l Amount of substance- mole (mol)

20. Prefixes l giga- G 1,000,000,00010 9 l mega - M 1,000,00010 6 l kilo - k 1,00010 3 l deci-d0.1 10 -1 l centi-c0.01 10 -2 l milli-m0.001 10 -3 l micro-m0.000001 10 -6 l nano-n0.000000001 10 -9

21. Deriving the Liter l Liter is defined as the volume of 1 dm 3 l gram is the mass of 1 cm 3

22. Mass and Weight l Mass is measure of resistance to change in motion l Weight is force of gravity. l Sometimes used interchangeably l Mass can’t change, weight can

23. Uncertainty l Basis for significant figures l All measurements are uncertain to some degree l Precision- how repeatable l Accuracy- how correct - closeness to true value. l Random error - equal chance of being high or low- addressed by averaging measurements - expected

24. Uncertainty l Systematic error- same direction each time l Want to avoid this l Better precision implies better accuracy l you can have precision without accuracy l You can’t have accuracy without precision

25. Dimensional Analysis Using the units to solve problems

26. Dimensional Analysis l Use conversion factors to change the units l Conversion factors = 1 l 1 foot = 12 inches (equivalence statement) l 12 in = 1 = 1 ft. 1 ft. 12 in l 2 conversion factors l multiply by the one that will give you the correct units in your answer.

27. Examples l 11 yards = 2 rod l 40 rods = 1 furlong l 8 furlongs = 1 mile l The Kentucky Derby race is 1.25 miles. How long is the race in rods, furlongs, meters, and kilometers? l A marathon race is 26 miles, 385 yards. What is this distance in rods, furlongs, meters, and kilometers?

28. Examples l Science fiction often uses nautical analogies to describe space travel. If the starship U.S.S. Enterprise is traveling at warp factor 1.71, what is its speed in knots? l Warp 1.71 = 5.00 times the speed of light l speed of light = 3.00 x 10 8 m/s l 1 knot = 2000 yd/h exactly

29. l Apothecaries (druggists) use the following set of measures in the English system: l 20 grains ap = 1 scruple (exact) l 3 scruples = 1 dram ap (exact) l 8 dram ap = 1 oz. ap (exact) l 1 dram ap = 3.888 g l 1 oz. ap = ? oz. troy l What is the mass of 1 scruple in grams? Examples

30. l The speed of light is 3.00 x 10 8 m/s. How far will a beam of light travel in 1.00 ns?

31. Temperature and Density

32. Temperature l A measure of the average kinetic energy l Different temperature scales, all are talking about the same height of mercury. l Derive a equation for converting ºF toºC

33. 0ºC 32ºF 0ºC = 32ºF

34. 100ºC212ºF 100ºC = 212ºF 0ºC 32ºF 0ºC = 32ºF

35. 100ºC212ºF 0ºC 32ºF 100ºC = 212ºF 0ºC = 32ºF 100ºC = 180ºF

36. 100ºC212ºF 0ºC 32ºF 100ºC = 212ºF 0ºC = 32ºF 100ºC = 180ºF 1ºC = (180/100)ºF 1ºC = 9/5ºF

37. ºC ºF

38. ºC ºF (0,32)= (C 1,F 1 )

39. ºC ºF (0,32) = (C 1,F 1 ) (120,212) = (C 2,F 2 )

40. Density l Ratio of mass to volume l D = m/V l Useful for identifying a compound l Useful for predicting weight l An intrinsic property- does not depend on what the material is

41. Density Problem l An empty container weighs 121.3 g. Filled with carbon tetrachloride (density 1.53 g/cm 3 ) the container weighs 283.2 g. What is the volume of the container?

42. Density Problem lAlA 55.0 gal drum weighs 75.0 lbs. when empty. What will the total mass be when filled with ethanol? density 0.789 g/cm 3 1 gal = 3.78 L 1 lb = 454 g