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Chapter 7 Notes Book chapter 5 Video #18
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7-1 Chemical Bonding -Atom: basic building block of matter -114 elements (video #19, 20) *Chem bonding: combining of atoms of elements to form new substances
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-Electrons and nrg Levels -2,8,8 *Valence e-: -Stable vs Nonstable
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Ex’s
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-Electrons and Bonding -e- in the outermost nrg level determines whether or not the atom will form chem bonds.
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7-2 Ionic Bonding *Ionic bonding: transfer of e- *Ion: charged particle - Gaining or losing of e- - + or - atoms - Electromagnetic force hold opp charges together
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-Ionization nrg and Electron Affinity *Ionization: 1. Nrg needed to remove e- 2. Ionization nrg for atoms with many e-, is high 3. Atoms with few e-, is low
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Ion ex:
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NaCl--everyone is happy
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*Electron Affinity: tend to attract e-
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-Arrangement of Ions in Ionic Compounds *Crystal lattice: regular repeating arrangement -gives great stability -accounts for certain physical properties ex: ionic cmpnd high MP
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-Each ionic cmpnd has a characteristic crystal lattice
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-Ionic Properties -rigid crystal -conduct elect when melted or dissolved in H2O -probably a metal and nonmetal (from groups 16 or 17) -high melting points
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http://www.nd.edu/~aseriann/CHAP9.html/ sld022.htmhttp://www.nd.edu/~aseriann/CHAP9.html/ sld022.htm
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7-3 Covalent Bonds *Cov Bon: sharing of e- -between atoms that have high ionization nrg and high electron affinities(Neither atom loses e- easily)
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Ex
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Covalent bonds form between: 2 nonmetals or a nonmetal and hydrogen
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Covalent or ionic? Na and Cl ionic C and H covalent C and S covalent Ca and S ionic
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-Nature of the Covalent Bond -Simplest is between H atoms *Electron-Dot Diagram: show only valence e- Ex’s: *Diatomic elements: always exist as 2 atoms cov. bonded
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-Formation of Molecules *Molecule: combination of atoms formed by a cov. Bond. -smallest part. Of a cov bonded substance that has all the prop. of that substance
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-Cov bonded solids tend to have low mp. *network solids: -high mp -large molecules -atoms continue to bond to one
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http://www.nd.edu/~aseriann/CHAP9.html/ sld038.htmhttp://www.nd.edu/~aseriann/CHAP9.html/ sld038.htm
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-Polyatomic ion *group of covalently bonded atoms that act like a single atom when combining with other atoms ex: NH 4
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Compounds containing polyatomic ions are named by using your polyatomic ion chart.
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7-4 Metallic Bonds *outer e- of the atoms form a common e- cloud -sea of mobile e- accounts for many of the properties of metals ex: malleable, ductile
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http://www.nd.edu/~aseriann/CHAP9.html/ sld007.htmhttp://www.nd.edu/~aseriann/CHAP9.html/ sld007.htm
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-metal ions can slide by each other and the e- are free to flow -also accounts for the high electric conductivity and high MP
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7-5 Predicting Types of Bonds -Compounds formed between elements that lose e- easily and those that gain e- easily will have ionic bonds. ex: metal and a nonmetal
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-Compounds formed between elements that tend to gain e-’s will have covalent bonds. ex: between nonmetals ?MgF; OCl; KCl; SBr; CaS
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-Combining Capacity of Atoms *Oxidation #: -some elements have more than one oxidation #; it depends on the other atoms with which it bonds
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-Using Oxidation # -Use to predict how atoms will combine and what the formula for the resulting cmpnds will be. ~the sum of the ox must = 0 EX’s:
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