1. AIR POLLUTION PART I

2. Bellwork: April 21, 2016 1.) Which of the following techniques is not an example of bioremediation? A. Land farming B. Composting C. Rhizofiltration D. Phytoremediation E. All are examples of bioremediation 2.) The eggs and small fry of some aquatic organisms are damaged when a rapidly melting snow pack contains acidic particles, resulting in acidic concentrations of 5 to 10 times higher than acidic rainfall. This condition is known as A. Acid shock B. Eutrophication C. Leaching D. Ozone depletion E. Synergistic effects

3. Core Case Study: When Is a Lichen Like a Canary?  Lichens can warn us of bad air because they absorb it as a source of nourishment. Figure 19-1

4. Core Case Study: When Is a Lichen Like a Canary?  Some lichen species are sensitive to specific air-polluting chemicals.  After Chernobyl, more than 70,000 reindeer had to be killed because they ate highly radioactive lichens.  Because lichens are widespread, long-lived, and anchored in place, they can help track pollution to its source.

5. STRUCTURE AND SCIENCE OF THE ATMOSPHERE  The atmosphere consists of several layers with different temperatures, pressures, and compositions. Figure 19-2

6. Fig. 19-2, p. 440 Atmospheric pressure (millibars) Temperature Thermosphere Pressure Mesopause Heating via ozone Mesosphere Stratopause Altitude (kilometers) Stratosphere Altitude (miles) Tropopause Ozone “layer” Heating from the earth Troposphere Temperature (˚C) Pressure = 1,000 millibars at ground level (Sea level)

7. STRUCTURE AND SCIENCE OF THE ATMOSPHERE  The atmosphere’s innermost layer (troposphere) is made up mostly of nitrogen (78%) and oxygen (21%), with smaller amounts of water vapor and CO 2.  Ozone in the atmosphere’s second layer (stratosphere) filters out most of the sun’s UV radiation that is harmful to us and most other species. In the troposphere, ozone is a pollutant.

8. Primary vs Secondary Primary pollutants: enter atmosphere directly Secondary pollutants: form due to chemical rxns occurring in air.

9. Primary & Secondary Pollutants

10. Primary Pollutants –CO 2 –NO x - from fossil fuels anc volcanoes –SO x - from fossil fuels –PM10 – particulates with a diameter of 1/7 the size of human hair (<10 micrometers) –volatile organic compounds (VOCs)- compounds with a high vapor pressure ex. Toluene, xylene, formaldehyde, benzene, and acetone

11. Secondary Pollutants Examples: –Tropospheric Ozone – from sunlight, NOx and VOCs –acid rain- from sulfur dioxide and nitrogen dioxide –Peroxyacyl Nitrates (PANs)- from sunlight, NOx, and hydrocarbons

12. Case Study: Acid Rain Secondary Pollutant: Sulfuric Acid, H 2 SO 4 SO 2 + H 2 O  H 2 SO 4 Burning coal Reduces crop yields, irritates lungs

13. Effects of Air Pollution Damages lungs and reduces visibility Corrodes materials Contributes to global warming, acid rain, and ozone depletion Bangkok

14. Burning Fossil Fuels Causes most air pollution

15. …By using alternative energy sources

16. Wet Scrubber - -mix liquid w/ air pollutant  pollutant sinks w/ liquid.

17. Catalytic Converter Reduces emissions from combustion engines 3 tasks: A) take CO  CO 2 B) Take NOx  O 2 and N C) Take HCs  CO 2 and H 2 O

18. 18 Smog  Smog –A mixture between smoke and fog that produces unhealthy urban air  Two Types –Photochemical Smog: NOx + Sunlight  Ozone & NO –Sulfurous Smog: SO 2 + Fog

19. Photochemical Smog (Brown Smog) Photochemical smog is a mixture of primary and secondary pollutants formed under the influence of sunlight. Primary Pollutants involved are mostly NOx and VOCs+ sunlight Secondary Pollutants: ozone (O 3 ), aldehydes (CH 2 O), PANS (peroxyacyl nitrates), and nitric acid (HNO 3 ).

21. 21 Sunlight plus Cars Equals Photochemical Smog

22. Industrial Smog (gray smog) Industrial smog consists mostly of sulfur dioxide, suspended droplets of sulfuric acid, and a variety of suspended solid particles and droplets that emanate from coal and heavy oil burning power plants and factories.

23. Factors That Influence The Formation of Smog Local climate and topography Amount of industry Fuels used in industry, heating & transportation Amount of precipitation (rain and snow cleanse atmosphere of pollutants) Wind patterns (winds sweep pollutants away) Hills and mountains reduce flow of air in valleys and allow pollutants to accumulate at ground level.

24. Other Highly Polluted Cities in the World Denver, Colorado Mexico City, Mexico Rio de Janeiro and Sao Paulo, Brazil Beijing and Shenyang, China Bangkok, Thailand Mexico City Beijing,China

25. Human Respiratory System Nasal Passage – hairs to filter out pollutants Sneezing and coughing expel contaminated air. Sticky mucus in upper respiratory track capture small particles and filter some gaseous pollutants. Cells of upper respiratory tract are lines with cilia that move back and forth, transporting mucous and the pollutants they trap to your throat where they can be expelled. Alveoli in bronchioles allow for proper gas exchange.

26. Effects of Air Pollution on Human Health Elderly, infants, pregnant woman, and people with heart disease, asthma, or other respiratory diseases are most vulnerable to air pollution (indoor and outdoor). –lung cancerlung cancer –asthma:asthma –chronic bronchitischronic bronchitis –emphysemaemphysema

27. Effects of Air Pollutants on Health –Carbon monoxide (CO) – Binds hemoglobin more tightly than oxygen. From smoking, kerosene heaters, woodstoves, fireplaces, and faulty heating systemsCarbon monoxide (CO) –Suspended Particulate Matter –cancer, asthma, lung disease –Sulfur dioxide – aggravates asthma –Nitrogen Oxides – especially NO 2 can irritate the lungs, asthma, emphysema, malignant melanoma –VOC’s – (benzenes and formaldehyde) and toxic particulates such as lead, cadmium, PCB’s and dioxins (agent orange) can cause mutations, reproductive problems, and cancer. –Ozone – coughing, chest pain, shortness of breath, and eye, nose, and throat irritation.

28. How Many People Die Prematurely? No one really knows. Estimated annual deaths in USA related to outdoor air pollution = 65,000 – 200,000 mostly due to exposure to fine or ultra-fine particulate matter (after 9-11 will now start to see tremendous increases in those numbers in from NYC metropolitan region) According to the American Lung Association air pollution in the USA costs a minimum of 150 billion dollars/year in health care costs and losses in work productivity. WHO and World Bank estimated in 1997 that in China 2.7 million people die prematurely each year from the effects of outdoor air pollution.

29. Chloroflourocarbons (CFCs) React with UV radiation to breakdown ozone in the ozone layer CFCs were used in refrigerants, fire extinguishers, fumigation and agriculture Montreal Protocol (1987) was designed to protect the stratospheric ozone layer. CFCs were to be phased out by 2000.

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31. Solutions: Preventing and Reducing Air Pollutants Clean Air Acts of 1970, 1977, and 1990 – These laws require the EPA to establish national ambient air quality standards (NAAQS) for seven outdoor pollutants: 1.Suspended particulate matter 2.Sulfur oxides (SOx) 3.Carbon monoxide (CO) 4.Nitrogen oxides (NOx) 5.Ozone (O 3 ) 6.Volatile Organic Compounds (VOC’s) 7.Lead (Pb)

32. Prevention of Significant Deterioration National Emission Standards for Toxic Air Pollutants – includes 302 compounds and 20 categories of chemical compounds that are harmful to human health. (Due to lack of money provided to EPA, standards have only been set for a few of these compounds._ Car emissions tests – catalytic converters Corporate Average Fuel Economy (CAFÉ) standards Automotive gasoline must have 10% additive of ethanol in nine cities (Baltimore, Chicago, Hartford, Houston, LA, Milwaukee, NY, Philadelphia, and San Diego) Presently there have been decreases in atmospheric pollutants since the 1970’s for ground ozone, CO, SOx, suspended particulate matter, NO 2 and lead levels have decreased.

33. How Can US Air Pollution Laws Be Improved? 1. Pollution prevention is best! Leaded gasoline outlawed, lead in air was reduced by 98%. 2. Increase fuel efficiency standards for cars and trucks, this will reduce oil imports. 3. Require stricter emission standards. 4. Fund research and development of alternative energy resources. Subsidize businesses and homeowners, vehicle owners for using energy conservation approaches such as hybrid vehicles, solar and wind energy for space heating, green buildings, etc..

34. What Can You Do? Car pool/mass transit. Turn off lights. Buy technology endorsed by EPA’s Energy Stars Program. Conserve water and electricity whenever possible reduce, reuse, recycle Walk, ride bike, roller blade, skateboard, motorcycle.