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Principles of Quantum Mechanics P1) Energy is quantized The photoelectric effect Energy quanta E = h  where h = 6.635 10 -34 J-s.

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Presentation on theme: "Principles of Quantum Mechanics P1) Energy is quantized The photoelectric effect Energy quanta E = h  where h = 6.635 10 -34 J-s."— Presentation transcript:

1 Principles of Quantum Mechanics P1) Energy is quantized The photoelectric effect Energy quanta E = h  where h = 6.635 10 -34 J-s

2 Principles of Quantum Mechanics P2) Wave particle duality de Broglie relationparticle double slit experimentwave

3 Principles of Quantum Mechanics P3) Uncertainty principle position/momentum energy/time where

4 Principles of Quantum Mechanics Schrodinger’s equation Letting We obtain the time-dependent portion The solution of which is The time-independent portion is

5 Principles of Quantum Mechanics Physical meaning of wave function The probability density function is where is the complex conjugate of  but Since this is a probability density

6 Principles of Quantum Mechanics Application 1Electron in Free Space Assuming V(x) = 0 Solution is Adding in the time dependent portion, and setting B=0 where

7 Principles of Quantum Mechanics Application 2Infinite Potential Well In region II, V = 0, so A solution is where

8 Principles of Quantum Mechanics Application 2Infinite Potential Well (cont.) Applying boundary and normalization conditions where n = 1,2,3…

9 Principles of Quantum Mechanics Application 3Potential Barrier Solutions for three regions where

10 Principles of Quantum Mechanics Application 3Potential Barrier (cont.) Tunneling when E < V 0


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