1. INTRODUCTORY CHEMISTRY INTRODUCTORY CHEMISTRY Concepts & Connections Sixth Edition by Charles H. Corwin Chapter 5 1 © 2011 Pearson Education, Inc. Chapter 5 Models of the Atom by Christopher Hamaker

2. Matter and Structure Understanding the structure of the atom will help to understand the properties of the elements. Keep in mind that these, as all theories, are subject to constant refinement. The picture of the atom isn’t final.

3. 3 Chap ter 4 © 2011 Pearson Education, Inc. Example Video Introduction to the atom (21:05 min) https://www.khanacademy.org/science/chemistry/int roduction-to-the-atom/v/introduction-to-the-atom

4. 2.2 Composition of the Atom Atom - the basic structural unit of an element. –The smallest unit of an element that retains the chemical properties of that element. Radioactive decay - certain kinds of atoms can “split” into smaller particles and release large amounts of energy.

5. Atoms consist of three primary particles. electrons protons neutrons Nucleus - small, dense, positively charged region in the center of the atom. Contains: -protons - positively charged particles -neutrons - uncharged particles

6. Surrounding the nucleus is a diffuse region of negative charge populated by: -electrons - negatively charged particles Selected Properties of the Subatomic Particles NameChargeMass(amu)Mass (grams) Electrons (e) -15.4 x 10 -4 9.1095 x 10 -28 Protons (p)+11.001.6725 X 10 -24 Neutrons (n) 01.001.6750 x 10 -24

7. Chapter 5 7 © 2011 Pearson Education, Inc. Dalton Model of the Atom John Dalton proposed that all matter is made up of tiny particles. These particles are molecules or atoms. Molecules can be broken down into atoms by chemical processes. Atoms cannot be broken down by chemical or physical processes.

8. Chapter 5 8 © 2011 Pearson Education, Inc. Dalton Model According to the law of definite composition, the mass ratio of carbon to oxygen in carbon dioxide is always the same. Carbon dioxide is composed of one carbon atom and two oxygen atoms. Similarly, two atoms of hydrogen and one atom of oxygen combine to give water. Dalton proposed that two hydrogen atoms could substitute for each oxygen atom in carbon dioxide to make methane with one carbon atom and four hydrogen atoms. Indeed, methane is CH 4 !

9. 2 Dalton’s Atomic Theory

10. Chapter 5 10 © 2011 Pearson Education, Inc. Dalton Atomic Theory A Summary of Dalton Atomic Theory: An element is composed of tiny, indivisible, indestructible particles called atoms. 1.All atoms of an element are identical and have the same properties. 2.Atoms of different elements combine to form compounds. 3.Compounds contain atoms in small whole number ratios. 4.Atoms can combine in more than one ratio to form different compounds. 5.Atoms can combine in more that one ratio to form different compounds.

11. Chapter 5 11 © 2011 Pearson Education, Inc. Dalton Atomic Theory, Continued The first two parts of atomic theory were later proven incorrect. We will see this later. Proposals 3, 4, and 5 are still accepted today. The Dalton theory was an important step in the further development of atomic theory.

12. 12 Chap ter 4 © 2011 Pearson Education, Inc. Example Video John Dalton's Atomic Theory (2:57 min) http://www.youtube.com/watch?v=wsYDL6EjV4 k

13. Chapter 5 13 © 2011 Pearson Education, Inc. Subatomic Particles About 50 years after Dalton’s proposal, evidence was seen that atoms were divisible. Two subatomic particles were discovered. 1.Negatively charged electrons, e –. 2.Positively charged protons, p +. An electron has a relative charge of -1, and a proton has a relative charge of +1.

14. Chapter 5 14 © 2011 Pearson Education, Inc. Thomson Model of the Atom J. J. Thomson proposed a subatomic model of the atom in 1903. Thomson proposed that the electrons were distributed evenly throughout a homogeneous sphere of positive charge. This was called the plum pudding model of the atom.

15. Joseph John Thomson (1856-1940). Photo courtesy of The Cavendish Laboratory.

16. Subatomic Particles: Thompson Experiment Electrons, Protons and Neutrons Electrons were the first subatomic particles to be discovered using the cathode ray tube. Indicated that the particles were negatively charged.

17. Cathode Ray Tube

18. 18 Chap ter 4 © 2011 Pearson Education, Inc. Example Video J. J. Thomson (2:00 min) http://www.youtube.com/watch?v=JwdGFZA3W Os

19. Chapter 5 19 © 2011 Pearson Education, Inc. Mass of Subatomic Particles Originally, Thomson could only calculate the mass-to-charge ratio of a proton and an electron. Robert Millikan determined the charge of an electron in 1911. Thomson calculated the masses of a proton and electron: –An electron has a mass of 9.11 × 10 -28 g. –A proton has a mass of 1.67 × 10 -24 g.

20. e - charge = -1.60 x 10 -19 C Thomson’s charge/mass of e - = -1.76 x 10 8 C/g e - mass = 9.10 x 10 -28 g Measured mass of e - (1923 Nobel Prize in Physics)

21. 21 Chap ter 4 © 2011 Pearson Education, Inc. Example Video Millikan Oil Drop Experiment (1:14 min) http://www.youtube.com/watch?v=XMfYHag7Li w

22. Chapter 5 22 © 2011 Pearson Education, Inc. Types of Radiation There are three types of radiation: 1.Alpha (  ) 2.Beta (  ) 3.Gamma (  ) Alpha rays are composed of helium atoms stripped of their electrons (helium nuclei). Beta rays are composed of electrons. Gamma rays are high-energy electromagnetic radiation.

23. (Uranium compound)

24. Chapter 5 24 © 2011 Pearson Education, Inc. Rutherford Gold Foil Experiment Rutherford’s student fired alpha particles at thin gold foils. If the plum pudding model of the atom was correct, α particles should pass through undeflected. However, some of the alpha particles were deflected backward.

25. Chapter 5 25 © 2011 Pearson Education, Inc. Explanation of Scattering Most of the alpha particles passed through the foil because an atom is largely empty space. At the center of an atom is the atomic nucleus, which contains the atom’s protons. The alpha particles that bounced backward did did so after striking the dense nucleus.

26. 26 Chap ter 4 © 2011 Pearson Education, Inc. Example Video Nucleus of an atom (0:48 min) http://www.youtube.com/watch?v=Q8RuO2ekNG w

27. Chapter 5 27 © 2011 Pearson Education, Inc. Rutherford Model of the Atom Rutherford proposed a new model of the atom: The negatively charged electrons are distributed around a positively charged nucleus. An atom has a diameter of about 1 × 10 -8 cm and the nucleus has a diameter of about 1 × 10 -13 cm. If an atom were the size of the Astrodome, the nucleus would be the size of a marble.

28. Chapter 5 28 © 2011 Pearson Education, Inc. Subatomic Particles Revisited Based on the heaviness of the nucleus, Rutherford predicted that it must contain neutral particles in addition to protons. Neutrons, n 0, were discovered about 30 years later. A neutron is about the size of a proton without any charge.

29. Chapter 5 29 © 2011 Pearson Education, Inc. Atomic Notation Each element has a characteristic number of protons in the nucleus. This is the atomic number, Z. The total number of protons and neutrons in the nucleus of an atom is the mass number, A. We use atomic notation to display the number of protons and neutrons in the nucleus of an atom: Sy symbol of the element mass number (p + and n 0 ) atomic number (p + ) A Z

30. Mass Number mass number (A) - sum of the number of protons and neutrons Atomic Number Charge of particle Symbol of the atom atomic number (Z) - the number of protons in the atom

31. Chapter 5 31 © 2011 Pearson Education, Inc. Using Atomic Notation An example: Si The element is silicon (symbol Si). The atomic number is 14; silicon has 14 protons. The mass number is 29; the atom of silicon has 29 protons + neutrons. The number of neutrons is A – Z = 29 – 14 = 15 neutrons. 29 14

32. Calculate the number of protons, neutrons and electrons in each of the following:

33. Chapter 5 33 © 2011 Pearson Education, Inc. Isotopes All atoms of the same element have the same number of protons. Most elements occur naturally with varying numbers of neutrons. Atoms of the same element that have a different number of neutrons in the nucleus are called isotopes. Isotopes have the same atomic number, but different mass numbers.

34. Isotopes - atoms of the same element having different masses. –contain same number of protons –contain different numbers of neutrons Isotopes of Hydrogen Hydrogen (Hydrogen - 1) Deuterium (Hydrogen - 2) Tritium (Hydrogen - 3)

35. Chapter 5 35 © 2011 Pearson Education, Inc. Isotopes, Continued We often refer to an isotope by stating the name of the element followed by the mass number. –Cobalt-60 is –Carbon-14 is How many protons and neutrons does an atom of lead-206 have? –The atomic number of Pb is 82, so it has 82 protons. –Pb-206 has 206 – 82 = 124 neutrons. Co 60 37 C 14 6

36. 6 protons, 8 (14 - 6) neutrons, 6 electrons 6 protons, 5 (11 - 6) neutrons, 6 electrons Do You Understand Isotopes? How many protons, neutrons, and electrons are in C 14 6 ? How many protons, neutrons, and electrons are in C 11 6 ?

37. Chapter 5 37 © 2011 Pearson Education, Inc. Simple and Weighted Averages A simple average assumes the same number of each object. A weighted average takes into account the fact that we do not have equal numbers of all the objects. A weighted average is calculated by multiplying the percentage of the object (as a decimal number) by its mass for each object and adding the numbers together.

38. Chapter 5 38 © 2011 Pearson Education, Inc. Average Atomic Mass Since not all isotopes of an atom are present in equal proportions, we must use the weighted average. Copper has two isotopes: 1. 63 Cu, with a mass of 62.930 amu and 69.09% abundance. 2. 65 Cu, with a mass of 64.928 amu and 30.91% abundance. The average atomic mass of copper is: (62.930 amu)(0.6909) + (64.928 amu)(0.3091) = 63.55 amu

39. Isotopes of the same element have identical chemical properties. Some isotopes are radioactive. Find chlorine on the periodic table. What is the atomic number? 17 What is the mass given? 35.45 This is not the mass number of an isotope.

40. What is this number? It is called the atomic mass - the weighed average of the masses of the isotopes that make up chlorine. Chlorine consists of chlorine-35 and chlorine-37 in a 3:1 ratio. The weighted average is an average corrected by the relative amounts of each isotope present in nature.

41. Calculate the atomic mass of naturally occurring chlorine if 75.77% of chlorine atoms are chlorine-35 and 24.23% of chlorine atoms are chlorine-37. Step 1: Convert the percentage to a decimal fraction. 0.7577 chlorine-35 0.2423 chlorine-37

42. Step 2: Multiply the decimal fraction by the mass of that isotope to obtain the isotope contribution to the atomic mass. For chlorine-35: 0.7577 x 35.00 amu = 26.52 amu For chlorine-37 0.2423 x 37.00 amu = 8.965 amu Step 3: sum to get the weighted average atomic mass of chlorine = 26.52 amu + 8.965 amu = 35.49 amu

43. Atomic Weights Calculate the atomic weight of boron, B, from the following data: ISOTOPE ISOTOPIC MASS (amu) FRACTIONAL ABUNDANCE B-10 10.013 0.1978 B-11 11.009 0.8022

44. Atomic Weights Calculate the atomic weight of boron, B, from the following data: ISOTOPE ISOTOPIC MASS (amu) FRACTIONAL ABUNDANCE B-10 10.013 0.1978 B-11 11.009 0.8022 B-10: 10.013 x 0.1978 = 1.9805 B-11: 11.009 x 0.8022 = 8.8314 10.8119 = 10.812 amu ( = atomic wt.)

45. Nitrogen consists of two naturally occurring isotopes. 99.63% nitrogen- 14 with a mass of 14.003 amu and 0.37% nitrogen-15 with a mass of 15.000 amu. What is the atomic mass of nitrogen?

46. Ions - electrically charged particles that result from a gain or loss of one or more electrons by the parent atom. Cation - positively charged. –result from the loss of electrons – 23 Na  23 Na + + 1e - Anion - negatively charged. –results from the gain of electrons – 19 F + 1 e -  19 F -

47. How many protons, neutrons and electrons are in the following ions?

48. Chapter 5 48 © 2011 Pearson Education, Inc. Periodic Table We can use the periodic table to obtain the atomic number and atomic mass of an element. The periodic table shows the atomic number, symbol, and atomic mass for each element.

49. The Relationship between Light and Atomic Structure Spectroscopy - absorption or emission of light by atoms. –Used to understand the electronic structure. To understand the electronic structure, we must first understand light. Electromagnetic radiation –travels in waves from a source –speed of 3.0 x 10 8 m/s

50. The Wave Nature of Light A wave is a continuously repeating change or oscillation in matter or in a physical field. Light is also a wave. It consists of oscillations in electric and magnetic fields that travel through space. Visible light, X rays, and radio waves are all forms of electromagnetic radiation.

51. Chapter 5 51 © 2011 Pearson Education, Inc. Wave Nature of Light Light travels through space as a wave, similar to an ocean wave. –Wavelength is the distance light travels in one cycle. –Frequency is the number of wave cycles completed each second. Light travels at a constant speed: 3.00 × 10 8 m/s (given the symbol c).

52. The Wave Nature of Light A wave can be characterized by its wavelength and frequency. The wavelength,  lambda), is the distance between any two adjacent identical points of a wave. The frequency,  (nu), of a wave is the number of wavelengths that pass a fixed point in one second.

53. Properties of Waves Wavelength ( ) is the distance between identical points on successive waves. Amplitude is the vertical distance from the midline of a wave to the peak or trough.

54. Properties of Waves Frequency ( ) is the number of waves that pass through a particular point in 1 second (Hz = 1 cycle/s). The speed (u) of the wave = x

55. So, given the frequency of light, its wavelength can be calculated, or vice versa. The Wave Nature of Light The product of the frequency, (waves/sec) and the wavelength, (m/wave) would give the speed of the wave in m/s. In a vacuum, the speed of light, c, is 3.00 x 10 8 m/s. Therefore,

56. Maxwell (1873), proposed that visible light consists of electromagnetic waves. Electromagnetic radiation is the emission and transmission of energy in the form of electromagnetic waves. Speed of light (c) in vacuum = 3.00 x 10 8 m/s All electromagnetic radiation x  c

57. Chapter 5 57 © 2011 Pearson Education, Inc. Wavelength Versus Frequency The longer the wavelength of light, the lower the frequency. The shorter the wavelength of light, the higher the frequency.

58. Chapter 5 58 © 2011 Pearson Education, Inc. Radiant Energy Spectrum The complete radiant energy spectrum is an uninterrupted band, or continuous spectrum. The radiant energy spectrum includes many types of radiation, most of which are invisible to the human eye.

60. Electromagnetic Spectrum high energy short wavelength low energy long wavelength

61. Chapter 5 61 © 2011 Pearson Education, Inc. Visible Spectrum Light usually refers to radiant energy that is visible to the human eye. The visible spectrum is the range of wavelengths between 400 and 700 nm. Radiant energy that has a wavelength lower than 400 nm and greater than 700 nm cannot be seen by the human eye.

62. Chapter 5 62 © 2011 Pearson Education, Inc. The Quantum Concept The quantum concept states that energy is present in small, discrete bundles. For example: –A tennis ball that rolls down a ramp loses potential energy continuously. –A tennis ball that rolls down a staircase loses potential energy in small bundles. The loss is quantized.

63. E = h

64. Orbit - what Bohr called the fixed energy levels. Ground state - the lowest possible energy state.

65. Chapter 5 65 © 2011 Pearson Education, Inc. Bohr Model of the Atom Niels Bohr speculated that electrons orbit about the nucleus in fixed energy levels. Electrons are found only in specific energy levels, and nowhere else. The electron energy levels are quantized.

66. emission spectrum - light emitted when a substance is excited by an energy source. The emission spectrum of hydrogen lead to the modern understanding of the electronic structure of the atom.

67. Chapter 5 67 © 2011 Pearson Education, Inc. Emission Line Spectra When an electrical voltage is passed across a gas in a sealed tube, a series of narrow lines is seen. These lines are the emission line spectrum. The emission line spectrum for hydrogen gas shows three lines: 434 nm, 486 nm, and 656 nm.

68. The Bohr Atom Electrons exist in fixed energy levels surrounding the nucleus. Quantization of energy Initial understanding of the atom by Niels Bohr Promotion of electron occurs as it absorbs energy Excited State Energy is released as the electron travels back to lower levels. Relaxation

69. Orbit - what Bohr called the fixed energy levels. Ground state - the lowest possible energy state.

70. The orbits are also identified using “quantum numbers” –n = 1, 2, 3, … n=1 n=2 n=3 When the electron relaxes (c) the energy released is observed as a single wavelength of light.

71. Chapter 5 71 © 2011 Pearson Education, Inc. Evidence for Energy Levels Bohr realized that this was the evidence he needed to prove his theory. The electric charge temporarily excites an electron to a higher orbit. When the electron drops back down, a photon is given off. The red line is the least energetic and corresponds to an electron dropping from energy level 3 to energy level 2.

72. Chapter 5 72 © 2011 Pearson Education, Inc. “Atomic Fingerprints” The emission line spectrum of each element is unique. We can use the line spectrum to identify elements using their “atomic fingerprint.”

74. Chapter 5 74 © 2011 Pearson Education, Inc. Critical Thinking: “Neon Lights” Most “neon” signs don’t actually contain neon gas. True neon signs are red in color. Each noble gas has its own emission spectrum, and signs made with each have a different color.

75. Chapter 5 75 © 2011 Pearson Education, Inc. Energy Levels and Sublevels It was later shown that electrons occupy energy sublevels within each level. These sublevels are given the designations s, p, d, and f. –These designations are in reference to the sharp, principal, diffuse, and fine lines in emission spectra. The number of sublevels in each level is the same as the number of the main level.

76. Chapter 5 76 © 2011 Pearson Education, Inc. Energy Levels and Sublevels, Continued The first energy level has one sublevel designated 1s. The second energy level has two sublevels designated 2s and 2p. The third energy level has three sublevels designated 3s, 3p, and 3d.

77. Chapter 5 77 © 2011 Pearson Education, Inc. Electron Occupancy in Sublevels The maximum number of electrons in each of the energy sublevels depends on the sublevel: –The s sublevel holds a maximum of 2 electrons. –The p sublevel holds a maximum of 6 electrons. –The d sublevel holds a maximum of 10 electrons. –The f sublevel holds a maximum of 14 electrons. The maximum electrons per level is obtained by adding the maximum number of electrons in each sublevel.

78. Chapter 5 78 © 2011 Pearson Education, Inc. Electrons per Energy Level

79. SUBSHELLS Subshells increase in energy as follows: s<p<d<f Therefore, electrons in 3d subshell have more energy than electrons in the 3p subshell. Note: when giving a subshell, also give the principle energy level with it.

80. SUBSHELLS (continued)

81. Be able to duplicate this breakdown of the Periodic Table and you can do the configuration of any element.

82. Chapter 5 82 © 2011 Pearson Education, Inc. Electron Configurations Electrons are arranged about the nucleus in a regular manner. The first electrons fill the energy sublevel closest to the nucleus. Electrons continue filling each sublevel until it is full, and then start filling the next closest sublevel. A partial list of sublevels in order of increasing energy is as follows: 1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d …

83. Chapter 5 83 © 2011 Pearson Education, Inc. Filling Diagram for Energy Sublevels The order does not strictly follow 1, 2, 3, etc. For now, use Figure 5.16 to predict the order of sublevel filling.

85. Chapter 5 85 © 2011 Pearson Education, Inc. Electron Configurations The electron configuration of an atom is a shorthand method of writing the location of electrons by sublevel. The sublevel is written followed by a superscript with the number of electrons in the sublevel. For example, if the 2p sublevel contains two electrons, it is written 2p 2. The electron sublevels are arranged according to increasing energy.

86. Chapter 5 86 © 2011 Pearson Education, Inc. Writing Electron Configurations First, determine how many electrons are in the atom. Bromine has 35 electrons. Arrange the energy sublevels according to increasing energy: –1s 2s 2p 3s 3p 4s 3d … Fill each sublevel with electrons until you have used all the electrons in the atom: –Fe: 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 5 The sum of the superscripts equals the atomic number of bromine (35).

87. H He Li Be N Na Cl Ag

88. Abbreviated Electron Configurations Uses noble gas symbols to represent the inner shell and the outer shell or valance shell is written after. For example: Let’s look at Aluminum The full electron configuration is: 1s 2 2s 2 2p 6 3s 2 3p 1. What noble gas is this the configuration of? Neon. Therefore, the configuration can be written: [Ne]3s 2 3p 1

89. N S Ti Sn

90. ORBITALS Orbital - a specific region of a subshell containing a maximum of two electrons. The two electrons in the orbital spin in opposite directions. When the orbital contains two electrons, the electrons are said to be paired. Let’s look at these orbital closely

91. Chapter 5 91 © 2011 Pearson Education, Inc. Quantum Mechanical Model An orbital is the region of space where there is a high probability of finding an atom. In the quantum mechanical atom, orbitals are arranged according to their size and shape. The higher the energy of an orbital, the larger its size. All s orbitals have spherical shapes.

92. Chapter 5 92 © 2011 Pearson Education, Inc. Shapes of p Orbitals Recall that there are three different p sublevels. All p orbitals have dumbbell shapes. Each of the p orbitals has the same shape, but each is oriented along a different axis in space.

93. Chapter 5 93 © 2011 Pearson Education, Inc. Shapes of d Orbitals Recall that there are five different d sublevels. Four of the d orbitals have a clover-leaf shape and one has a dumbbell and doughnut shape.

94. Chapter 5 94 © 2011 Pearson Education, Inc. Location of Electrons in an Orbital The orbitals are the region of space in which the electrons are most likely to be found. An analogy for an electron in a p orbital is a fly trapped in two bottles held end to end.

96. How many electrons can be in the 4d subshell? 10

97. Be able to duplicate this breakdown of the Periodic Table and you can do the configuration of any element.

98. 98 Chap ter 4 © 2011 Pearson Education, Inc. Example Video Orbitals (13:38 min) https://www.khanacademy.org/science/chemistry/or bitals-and-electrons/v/orbitals More on orbitals and electron configuration (14:13) https://www.khanacademy.org/science/chemistry/or bitals-and-electrons/v/more-on-orbitals-and- electron-configuration

99. 1) Electron Configurations: Introduction to using the periodic table to determine electron configurations (10:04 min) http://www.khanacademy.org/science/chemistry /v/electron-configurations 2) Electron Configurations 2: Figuring out configurations for the d-block elements (10:18 min) http://www.khanacademy.org/science/chemis try/v/electron-configurations-2 Using the periodic table to determine electron Configurations - Videos

100. Chapter 5 100 © 2011 Pearson Education, Inc. Chapter Summary Atoms are composed of protons, neutrons, and electrons. The protons and neutrons are located in the nucleus, and the electrons are outside the nucleus. Atoms are mostly empty space. The number of protons is referred to as the atomic number for the atom.

101. Chapter 5 101 © 2011 Pearson Education, Inc. Chapter Summary, Continued All atoms of the same element have the same number of protons. Isotopes are atoms with the same number of protons, but differing numbers of neutrons. The mass number for an isotope is the total number of protons plus neutrons. The atomic mass of an element is the weighted average of the masses of all the naturally occurring isotopes.

102. Chapter 5 102 © 2011 Pearson Education, Inc. Chapter Summary, Continued Light has properties of both waves and particles. The particles of light are referred to as photons. The energy of photons is quantized. Electrons exist around the nucleus of atoms in discrete, quantized energy levels. Electrons fill energy sublevels, starting with the lowest energy sublevel and filling each successive level of higher energy.