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Organic Chemistry
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Prefixes 1.Meth- 2.Eth- 3.Prop- 4.But- 5.Pent- 6.Hex- 7.Hept- 8.Oct- 9.Non- 10.Dec- Count number of carbons in longest chain
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Alkanes Only single bonds between C’s Root -ane Formula is C n H 2n+2
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Alkenes One double bonds between C’s Root #-ene (# = location of dbl bond always lowest number) Formula is C n H 2n for single alkene Can have more than one double bond simply indicated by #,#-di-ene, etc. Subtract 2 H for each extra double bond
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Alkynes One triple bonds between C’s Root #-yne (# = location of tpl bond always lowest number) Formula is C n H 2n-2 for single alkyne Can have more than one triple bond simply indicated by #,#-di-yne, etc. Subtract 4 H for each extra triple bond
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Cyclic Hydrocarbons Cyclo-carbons in a ring (C n H 2n for alkane) Cyclopropane Cyclobutane Cyclopentane Cyclohexane
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Practice CH 4 CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 3 CHCH CH 3 CH 2 CH 2 CCCH 3 CH 2 CHCH 3
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Practice Propane 2-Hexene Ethyne Cyclohexane Cyclopentyne
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Branches Branch – chain of C(s) off main chain Double or triple bonds have to be in main chain Named by counting number of carbons and adding –yl to prefix and indicating what C it is on ex. 3-methylhexane If two of the same branch write as #,#-di__ ex. 3,4-dimethylhexane
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Practice Exercise 24.1 through 24.4 & 24.6
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Cis-Trans A double bond does not allow rotation therefore there are two isomers for a basic alkene if there are two different groups on each side of the double bond. If the priority groups are both pointing the same way-cis If the priority groups are opposite-trans
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Cis-Trans Rules for priority: –Check first element of each group: higher atomic mass has priority –If the first element is the same move to the next one and repeat until they differ
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Practice Exercise 24.5
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Aromatic Only one aromatic you need to know Benzene C 6 H 6 Same rules apply If benzene is an attached group it is named phenyl-
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Ortho, meta, para If two groups on ring then name ortho (o), meta (m), or para (p). CH 3 Ortho (o-di-methylbenzene) Meta (m-di-methylbenzene) Para (p-di-methylbenzene)
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Practice Exercise 24.7
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Homework 27-39 odd
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