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METALS Introduction to MATERIAL SCIENCE HONORS
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Atomic Structure
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Metallic Bonding “Sea of Electrons”
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Properties of Metals Metals are strong.
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Metals have a lustrous look when polished.
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Metals are flexible.
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Metals are malleable.
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Lab: Metal Malleability
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Properties of Metals Metals expand when heated.
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Thermal Expansion
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Properties of Metals Metals have a very high conductivity rate of heat and electricity.
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Commercial Applications Cookware Copper Cast Iron Aluminum Steel
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Medical Applications Metal nanoparticles, such as gold, can heat an area up to 1,000 times its size.
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A short peptide is attached to the nanospheres of gold that enabled them to bind to tumor cells.
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Using laser light, Ohio University scientists uses gold nanoparticles to kill cancer tumors.
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Electrical Applications
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Properties of Metals Certain metals can be magnetic.
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Non-Magnetic Metals
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Magnetic Metals
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Properties of Metals Metals are crystalline in structure.
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Crystal Structures of Metals AluminumFCC CadmiumHCP ChromiumBCC CobaltHCP CopperFCC GoldFCC IronBCC LeadFCC MagnesiumHCP NickelFCC NiobiumBCC PlatinumFCC PoloniumCubic SilverFCC TitaniumHCP VanadiumBCC ZincHCP ZirconiumHCP
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Disadvantages of Metals Metals corrode!
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Unit #1: History of Metals
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Metallurgy Metallurgy is one of the oldest applied sciences. The history of metals is closely linked to that of coins and gemstones.
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As early as 3400 B.C., at the beginning of the historical period, the Egyptians had an intimate knowledge of gold, copper ores and of processes of extracting metals.
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Metallurgy Metals were also known to the Mesopotamians, Greeks and the Romans.
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Native Metals Copper Gold MercurySilver
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Iron
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Native iron is easily distinguishable because it contains 6-8% nickel. Iron was available to the ancients in small amounts from meteors.
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Copper Age (~4000 B.C.) The first metal to be used was copper.
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The first tools, implements & weapons were made from copper.
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The oldest known casting in existence, a pure copper frog, was cast in Mesopotamia.
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Bronze Age (~3000 B.C.) Bronze was the first alloy used. Bronze = Copper & 5-10% Tin
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New discoveries near Ban Chiang, Thailand, indicate that bronze technology was maybe known there as early as 4500 BC!
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Iron Age (~2000 B.C.) Iron smelting began in Egypt.
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Process of Iron Smelting A mixture of iron and oxide impurities is heated to about 1,500°C. Molten iron is drawn off on one side, and slag (waste) on the other.
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Iron Age (~2000 B.C.) Iron weapons revolutionized warfare and iron implements did the same for farming.
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Iron Pillar ~ 400A.D. This iron pillar dating to 400 A.D., remains standing today in Delhi, India. Corrosion to the pillar has been minimal a skill lost to current ironworkers.
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Cast Iron (~800) Chinese were the first in the production of cast iron.
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Molten iron is "cast" into forms made of sand.
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Steel (~500)
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Steel Production Fe 2 O 3(s) + 3CO (g) = 2Fe( l ) + 3CO 2(g) Step 1:
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Molten iron is mixed with carbon & other elements. Step 2:
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How To Smelt Iron? Wood Wood was needed as timber and it takes too much wood so smelt iron.
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Coal Although cheap and plentiful, coal contained sulphur that made the iron too brittle to be of any use.
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Abraham Darby In 1709, Abraham Darby finally succeeded in smelting iron with coke.
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1750 Steel becomes the world’s most used material.
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1850 Charles Martin Hall Isolated Pure Aluminum
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1900
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Specialty Alloys (1935-1955)
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Human Body Parts (1955-present) High quality alloys of titanium & cobalt.
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Super Alloys (1970-Present) Since they can sustain high temperatures, super alloys were developed for jet engines.
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Transparent Aluminum (2010) Fine grained aluminum is heated to 1200°C! 3X tougher than steel & it’s see-through!
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Unit #2: Metal Processing
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Cold Working Altering the shape or size of a metal by plastic deformation.
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Types of Cold-Working Rolling Drawing Pressing
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Hot Working Hot working refers to plastic deformation carried out above the recrystallization temperature.
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Annealing
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Quenching
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Tempering
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Unit #3: Alloys An alloy is a metal composed of more than one element.
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Examples of Alloys Bronze Brass Steel
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Desirable Properties Corrosion Prevention Mechanical Performance
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Unit #4: Corrosion Process & Prevention
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