1. System Solutions Overview

2. SYNGAS-Gas Processing
Production of synthesis gas (H2 and CO)
FEEDSTOCK:
gaseous and liquid hydrocarbons
CUSTOMERS:
Krupp-Uhde
LINDE

3. SYNGAS-Gas Processing
SYNGAS BASED PRODUCTS:
SERVICE OF THE SYSTEM:
Process control of the syngas plant
Quality control

4. SYNGAS-Gas Processing
REQUIREMENTS:
Availability - more than 96% per year
Self diagnostic of all subsystems
Minimized maintenance
Integrated architecture of the analysis system

5. SYNGAS-Gas Processing
ANALYZERS:
MLT2 (Ex-proof)
CAT 100/ CAT 200
GCX (BTU)
OCX
DESIGN OF THE SYSTEM:
IEC 1285
Ex-protection
Flexibility

6. PSA-Gas Processing PROCESS:
Purification of Hydrogen, CO, Methane and Helium
CUSTOMERS:
Krupp-Uhde
LINDE
CALORIC
LICENSORS:
UOP

7. PSA-Gas Processing ANALYZERS: MLT2 (Ex-proof) NGA-FID/Methanizer
CAT 200
GCX
SERVICE:
Quality control
REGULATIONS:
Ex-protection acc. to European and US regulations
VDE, IEC

8. PSA-Gas Processing
Systems supplied
between 1998 and 2000

9. NH3-Petrochemical Process
Production of Ammonia (NH3)
FEEDSTOCK:
natural gas up to heavy naphtha
CUSTOMERS:
Krupp-Uhde
ENPPI
Tecnimont
Syn gas Anlage ist immer einer Ammonia Anlage vorgeschaltet

10. NH3-Petrochemical Process
SERVICE OF THE SYSTEM:
Primary process control
Quality control
AMMONIA BASED PRODUCTS:
Salts of Nitric Acid
UREA

11. NH3-Petrochemical Process
ANALYZERS:
MLT 2 (Ex-proof)
GCX
OCX

12. Gasification - Gas Processing
Multi-purpose gasification by partial oxidation
FEEDSTOCK:
gaseous HC‘s up to heavy liquid HC‘s
CUSTOMERS:
Lurgi
SVZ
University of Dresden
University of Siegen
Aus org. Müll Syn Gas herstellen
Hohe Temp mehr CO/H2
Niedrige Temp. Mehr Methanol
O2 Messung wichtig
Pyrolysis Gas Sample Probe (py gas sample probe)

13. Gasification - Gas Processing
APPLICATION:
Production of synthesis gas (H2 and CO)
for methanol plants
for IGCC plants (integrated gasification combined-cycle unit)

14. Gasification - Gas Processing
SERVICE OF THE SYSTEM:
Explosion protection of the reactor
Quality control of the purified synthesis gas
BTU calculation
ANALYZERS:
MLT2 (Ex-proof)
BINOS 100F
GCX

15. Gasification - Gas Processing
REQUIREMENTS:
Availability – more than 97% per year
Safety specifications acc. to AK6 (nuclear power station is AK7)
low maintenance
t90 < 50 s

16. Gasification - Gas Processing
Technical requirements
- Primary Sample Handling System -

17. Ethylene - Petrochemical Process
Ethylene cracking
CUSTOMER:
Norsk Hydro
APPLICATION:
Production of polymer-grade Ethylene by thermal cracking of hydocarbon fractions
ANALYZER:
GCX for primary process control
SERVICE:
Measurement of H2, C1C3 fractions and Ethylene in furnace effluent gas

18. Ethylene - Petrochemical Process
Analytical system:
GCX allows installation in compact enclosure beside pyrolysis gas sampler:
reduced lag time between pyrolysis gas-sampler and S-SHS
minimized sample flow avoids risk of liquid carry-over
enhanced reliability, improved process control
Further „Artic“ installations GCX‘s:
Norsk Hydro (LPG), Borealis (Control of flare gas)

19. Polyethylene - Petrochemical Process
LICENSORS:
BOREALIS, Exxon Chemical, Union Carbide, Elenac, BASF, Snamprogetti, Linde, BP Chemical
PROCESS:
Production of Polyethylene
HDPE
LDPE
LLDPE
CUSTOMERS:
Salzgitter Anlagenbau
ANALYZER:
GCX

20. Polyethylene - Petrochemical Process
Analytical system:
for LLDPE
heated SHS
Ex-proof equipment
for LDPE
hypercritical conditions at take off point (  120°C, p  280 bar)
traces of C15 up to C25
temperature drop under adiabatic conditions (D  = 80°C)
Litvinov – Co-Starter für Polmerization
TEA Triethylamine + O2/H2O = Al203
Diffusion von TEA zurück vom Prozeß zum SHS. Blocken des SHS.
Lösung Silikonfalle nach dem Waste Header so dass Rückdiffusion verhindert wird und das Problem nicht mehr auftritt,
Technical problem:
Blocking by liquefaction and solidification of C15 - C25 traces
Explosive process gas

21. Polyethylene - Petrochemical Process
Technical Solution:
multi-stage pressure reduction with increased heat transfer
Liquefaction and separation of C15 - C25 traces before the final pressure reduction stage
This solution allows a maintenance-free operation of the system

22. VC - Petrochemical Process
Vinyl Chloride Monomer
Feedstock: Chlorine, Oxygen, Ethylene
Sub-Processes:
Production of Ethylene dichloride by DIRECT CHLORINATION
Production of Ethylene dichloride by OXYCHLORINATION
VCM by EHYLENE DICHLORIDE CRACKING
Vinyl chloride monomer

23. VC - Petrochemical Process
CUSTOMER:
Krupp Uhde
Promtex (Russia)
Finolex (India)
ANALYSIS SYSTEM:
Primary SHS
Secondary SHS
Final SHS
Gas/Fluids are toxic and explosive, corrosive and tend to polymerization

24. VC - Petrochemical Process
ANALYZERS:
MLT2, BINOS 100, GCX,
AOTF, Model 2700 for 0- 2 ppm HCl
in VCM/ EDC

25. Phthalic anhydride - Chemical Industry
CUSTOMER:
Wacker Chemie
Phthalic acid --> base product for varnish industry O H
- H 2
PROCESS:
FEEDSTOCK: C 3
o-Xylene
Naphthalene

26. Phthalic anhydride - Chemical Industry
SERVICE - ANALYTICAL SYSTEM-:
Measuring of CO and CO2 in reactor effluent gas for process control
ANALYSIS SYSTEM:
Development of EMERSON PROCESS MANAGEMENT and Wacker (EMERSON PROCESS MANAGEMENT is supplier world-wide based on licensor‘s specification)
Selective rejection of Formaldehyde
ANALYZERS: MLT 2.2 and BINOS 100F

27. Bisphenol-A - Chemical Industry
PROCESS: 3 C O +
Bisphenol-A 2
CUSTOMER:
BAYER AG
Bisphenol-A --> base product for polycarbonate and epoxy resins
ANALYZERS:
BINOS 100F, MLT, TOC

28. Bisphenol-A - Chemical Industry
BAYER AG REQUIREMENTS:
Professionel engineering service
joint solving of application problems
detailed documentation in different languages
technical order tracking system
High engineering competency
technical transfer of application solutions
Maximum flexibility
order processing, production and administration

29. Crude Oil - Refining Process
Analysis of gaseous components in pre-prepared crude-oil
CUSTOMER:
Oil industry - Russia -
ANALYZER:
GCX
SERVICE:
C1 up to C4‘s versus total mass of crude oil

30. Crude Oil - Refining Process
Oil-pipeline
SHS -
EMERSON PROCESS MANAGEMENT

31. Crude Oil - Refining Process

32. Crude Oil - Refining Process

33. Butene-1 Plant CUSTOMER: Lurgi ANALYZER: MLT 2; GCX SERVICE:
Prevention of polymerisation
Special seal materials
Polymerisation durch erhöhten Gasfluss vermeiden.
Wenn Prozessgas ausfällt muß das SHS auf Purge umstellen.

34. Butene-1 Plant

35. Ethylene Plant CUSTOMER: LINDE AG ANALYZER: MLT 2; GCX SERVICE:
Cracking of Natural Gas

36. Ethylene Plant

37. Aromatics Plant ANALYZER: MLT 2; GCX 10 GCX`s 9 of them with VLSIV
Calibration pistons

38. Aromatics Plant

39. CO2-Plant

40. CO2-Plant ANALYTICAL SYSTEM: Two 20 meter containers
Assembly of the two containers on site to one
ANALYZER:
MLT 2
SERVICE:
CO2-production for the food industry