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Objectives Explain why atoms form bonds Define chemical bond & name three types of chemical bonds Compare and contrast the advantages and disadvantages of varying molecular models
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Lewis Dot Diagrams/Lewis Structures diagrams that show the bonding between atoms of a molecule and the lone pairs of electrons that may exist in the molecule. Comes in handy when dealing with reactions and chemical bonds. Lone electrons are where other elements can bond and create molecules.
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Drawing Lewis Dot Diagrams First you need to identify the number of valence electrons Find the V.E. from writing out the shorthand configuration Or based upon the group that it’s in find the number of V.E. from that. Second, place the elements valence electrons around the chemical symbol
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Quick Check! Draw out the Lewis Dot Diagrams for the following elements Iodine Hydrogen Calcium Indium
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Bonding Atoms Why do atoms bond? - each atom wants a full outermost energy level - gain, lose, and share valence electrons to achieve the duet or octet rule aka: “being happy” - gives each atom an electron configuration similar to that of a noble gas ex. Group 18: He, Ne, Ar
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Chemical Bonds Chemical Bonds - attractive force that holds atoms or ions together - 3 types ionic, covalent, metallic - determines the structure of compound - structure affects properties - melting/boiling pts, conductivity etc.
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Chemical Structure/Models Chemical Structure/Molecular Models - arrangement of bonded atoms or ions - bond length: the average distance between the nuclei of two bonded atoms - bond angles: the angle formed by two bonds to the same atom
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Ionic Bonds / Ionic Compounds Definition - bond formed by the attraction between oppositely charged ions cation: positive: lost e-’s anion: negative: gained e-’s - oppositely charged ions attract each other and form an ionic bond ex. Na + + Cl - = NaCl - electrons are transferred from one atom to another - negative ions attract more positive ions, and soon a network is formed
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Ionic Bonding: The Formation of Sodium Chloride Cl 1s 2 2s 2 2p 6 3s 2 3p 5 Na 1s 2 2s 2 2p 6 3s 1 Cl - 1s 2 2s 2 2p 6 3s 2 3p 6 Na + 1s 2 2s 2 2p 6
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Networks / Crystal Lattices Networks - repeating pattern of multiple ions ex. NaCl - every Na ion is next to 6 Cl ions - strong attraction between ions creates a rigid framework, or lattice structure: aka: crystals ex, cubes, hexagons, tetragons
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Properties of Ionic Compounds Structure affects properties - strong attractions between ions: strong bonds - high melting/boiling pt - shatter when struck (think of it as one unit) - conductivity solid: ions are so close together, fixed positions, (can’t move) NO conductivity liquid: ions are freely moving due to a broken lattice structure Good conductivity
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How many Atoms? AND
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Ca + F_________________H + Br_________________ B + P_________________Al + O_________________ Sr + N_________________K + N_________________ B + I_________________Li + Se_________________ Without drawing a diagram, decide how many atoms of each element there are. Then write the formula.
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Covalent Bonds Definition - chemical bond in which two atoms share a pair of valence electrons - can be a single, double, or triple bond single, 2e-’s (-); double, 4e-’s (=); triple, 6e-’s( ) - always formed between nonmetals - mostly low melting/boiling points 2 types of bonds - polar - non polar
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Covalent Bond Cont. Non Polar - bonded atoms that share e - ’s equally - same atoms bonded ex. Cl – Cl: Cl 2 Polar - bonded atoms that do not share e - ’s equally - different atoms bonded H ex. H – N – H: NH 3
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Covalent Bonds Cont. Special Diatomic Atoms Bonded to each other (there are 7!) H 2 N 2 O 2 F 2 Cl 2 Br 2 I 2
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Metallic Bonds Definition - a bond formed by the attraction between positively charged metal ion (cation) and the shared electrons that surround it (sea of electrons) ex. Cu Properties - Conductivity: Good: electrons can move freely - Malleable: lattice structure is flexible
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Predicting Bond Type
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