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Gas Laws Chapter 14
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Factors Effecting Gases 1. Temperature (T) a measure of the average kinetic energy (movement) of particles in a sample of matter If the kinetic energy of particles increases, the temperature of the substance increases.
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Temperature Units of temperature can be measured in: 1.Celsius 2.Fahrenheit 3.Kelvin Who uses these temperature scales? U.S.A. uses Fahrenheit The rest of the world uses Celsius Scientists use Kelvin
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Temperature Important equations needed to do temperature conversions: °F = 1.8 (°C) + 32 K = °C + 273
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http://www.youtube.com/watch?v=TNUDBdv3jWI
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Volume 2. Volume (V) the amount of space an object takes up *Gases have an indefinite shape and size depending on pressure and temperature *Gases are compressible and expandable Units of volume can be measured in: 1.mL or L 2.cm 3
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Amount 3.Amount (n) how much of a substance is present Units of amount can be measured in: 1.***Moles (the unit of measurement we use for ALL gas laws) 2.Grams 3.Number of molecules
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Pressure 4. Pressure (P) the force per unit area P = force/area
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Pressure Units of pressure can be measured in: 1.Pascals (Pa) 2.Millimeters of mercury (mm Hg) 3.Torr 4.Newton per meter squared (N/m 2 ) 5.Atmospheres (atm)
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Pressure At standard temperature and pressure (STP) = O° C and 1 atm, the following pressure conversions hold true: 1 atm = 760 mm Hg = 760 torr = 101.3 kPa
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Boyle’s Law If the temperature is constant, as the pressure of a gas increases, the volume decreases. P 1 V 1 =P 2 V 2
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Example A balloon contains 30.0 L of helium gas at 103 kPa. What is the volume of helium when the balloon rises to an altitude where the pressure is only 25.0 kPa?
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Example The pressure on 2.50 L of N 2 O changes from 105 kPa to 40.5 kPa. If the temperature does not change, what will the new volume be?
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Charles’s Law As the temperature of a gas increases, the volume increases if the pressure is constant.
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Example On hot days, you may have noticed that potato chip bags seem to “inflate”, even though they have not been opened. If you have a 250. mL bag at a temperature of 19°C, and I leave it in my car which has a temperature of 60°C, what will the new volume of the bag be?
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Example A 4.00 L sample of air at 35°C expands to 5.50 L when heated. What is the new temperature of the air?
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Gay-Lussac’s Law As the temperature of an enclosed gas increases, the pressure increases if the volume is held constant.
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Example The gas in a used aerosol can is at a pressure of 103 kPa at 25°C. If the can is thrown onto a fire, what will the pressure be when the temperature reaches 828°C?
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Example The pressure in a car tire is 198 kPa at 27°C. After a long drive, the pressure is 225 kPa. What is the temperature of the air in the tire? Assume that the volume is constant.
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Combined Gas Laws Incorporates all 3 gas laws already learned Only the amount of gas is held constant.
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Example A 350 mL sample of helium gas is collected at 22.0°C and 99.3 kPa. What volume would this gas occupy at STP?
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