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Chemistry Revision  Structure and bonding  Structure and properties  How much?  Rates and energy  Salts and electrolysis.

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Presentation on theme: "Chemistry Revision  Structure and bonding  Structure and properties  How much?  Rates and energy  Salts and electrolysis."— Presentation transcript:

1 Chemistry Revision  Structure and bonding  Structure and properties  How much?  Rates and energy  Salts and electrolysis

2 Columns = groups Group number = number of electrons in outer shell Rows = periods Row number = number of shells Periodic table

3 Type of sub-atomic particleRelative chargeMass Proton+11 Neutron01 ElectronNegligible Atomic structure

4 Each shell = different energy level Shell nearest nucleus = lowest energy level Energy needed to overcome attractive forces between protons and electrons Atomic structure

5 Very strong forces of attraction between positive and negative ions = ionic bond Look! Group 1 element Look! Group 7 element Ionic Bonding

6 Ionic bonds form a giant lattice structure Ionic Bonding

7  Metals lose electrons  Non metals receive electrons  Elements become ions with a charge  Metals = + ion Non metal = - ion  High melting and boiling points – strong bonds  Solid at room temperature  Conduct electricity when melted or dissolved

8 Covalent Bonding (non metals) Simple molecules Giant structures

9 Covalent Bonding  Share electrons  Between non metals  No charge – don’t conduct electricity  Simple molecules have low melting and boiling points  Giant molecules have high melting and boiling points  Graphite and Diamond are examples

10 IonicSimple (covalent) Giant (covalent) Metallic Melting point  Boiling point  Electrical/ heat conductor Yes, when molten or in solution (aq) as allows ions to move No, due to no overall charge No – diamond Yes – graphite due to delocalised electrons Yes, due to delocalised electrons Strong electrostatic forces Strong covalent bonds, weak intermolecular forces Strong covalent bonds Structure and properties

11 Nanoscience  Small particles  Between 1 and 100 nanometres  Titanium oxides used in sunscreen  Can affect health  A spark can cause violent explosion

12 Polymers Thermo softening polymers  Melt easily when heated  Polymer chains easy to separate Thermosetting polymers  Strong covalent bonds  cross linking polymers  Don’t melt when heated

13 How much? Relative Atomic Mass (RAM)  Found on the periodic table  Tells you the number of protons and neutrons in an element  Always the bigger number of the 2

14 How much? Relative Formula Mass (RFM) or Relative Molecular Mass  Works out the mass of a compound  Find the RAM for each element  Add all the RAM numbers together  If there is a number (H 2 SO 4 ) multiply the RAM by that number  (Hx2) + S + (Ox4)

15 How much? Percentage Mass of an element  Calculate the RAM and RFM of the compound % mass = RAM (x number of atoms) x 100 RFM  If the number is larger than 100 check it

16 How much? Percentage Yield  Yield is how much is made  Percentage yield calculates how much is made compared to maximum amount  Rarely 100% because not all reactants react and some product gets left behind % Yield = amount of product produced x 100 Maximum amount of product possible

17 How much?

18 Gas Chromatography  Separates compounds  Used to identify unknown substances  Sample mixture is vaporised  Compounds with weaker attractions leave the column quicker  Times are recorded are compared to known substances

19 How much? Mass Spectrometer  Uses the separated compounds from Gas chromatography  Can identify elements  Identifies very small amounts of substances

20 Rates and energy Collision theory Chemical reactions only occur when reacting particles collide with each other with sufficient energy. The minimum amount of energy is called the activation energy Measure the rate of reaction by:  Gas produced  Mass decrease

21 Rates and energy Surface area  Larger surface area  Increases the number of collisions  More particles can react  Powder has large surface compared to lumps

22 Temperature  Higher temperature – more collisions  Heat gives particles kinetic energy  Particles move more quickly  Therefore collide more often in less time Rates and energy

23 Concentration/Pressure  Higher concentration/pressure – more particles  Less space so number of collisions increases Rates and energy

24 Catalyst  Speeds up the rate of chemical reaction  Not used up in the reaction  Reusable  Don’t need to have high temperatures which are expensive  Transition metals typically used Rates and energy

25 Exothermic  Give energy out to surroundings  Measure by increase of temperature Examples  Hand warmers  Self heating can (calcium oxide + water  Calcium hydroxide) Endothermic  Take in energy from surroundings  Measure by decrease of temperature Examples  Cold packs (ammonium nitrate + water)

26 Hydrated Anhydrous copper sulphate copper sulphate + water Exothermic reaction Endothermic reaction Rates and energy

27 Salts and electrolysis Acids  H+ ions  pH 0-6  HCl, H 2 SO 4, HNO 3 Alkalis  OH- ions  pH 8-14  NaOH  Alkalis = soluble bases

28 AcidFormulaSaltExample HydrochloricHClChlorideSodium chloride SulphuricH 2 SO 4 SulphateCopper sulphate NitricHNO 3 NitratePotassium nitrate Salts and electrolysis

29 1.acid + alkalisalt + water 2.acid + metalsalt + hydrogen 3.acid + metal oxide salt + water 4.acid + carbonate salt + carbon dioxide + water    

30 Salts and electrolysis Insoluble salt – from precipitation reaction (2 liquids react and make a solid) Method: 1.Mix the 2 chemicals (potassium Iodide and Lead Iodide) 2.Filter the precipitate 3.Wash the precipitate and leave to dry

31 Salts and electrolysis Neutralisation (pH 7) = acid and alkali Method: 1.Add universal indicator to your acid 2.Slowly add the alkali until the colour turns green (neutral) 3.Record the amount used and repeat without indicator 4.Pour the solution into evaporating basin 5.Heat using the Bunsen burner

32 Electrolysis  splitting up using electricity  Ionic compounds  Molten/liquid  Opposites attract  Metal  negative electrode  Non metal  positive electrode  OIL RIG – oxidation in loss, reduction is gain Non-metal ion Metal ion Salts and electrolysis

33 Extract aluminium from bauxite ore Use cryolite to lower melting point from 2050 to 850 0 C

34 At anode2Cl - (aq)  Cl 2 (g) + 2e - At cathode2H + (aq) + 2e -  H 2 (g) In solutionNa + and OH - Salts and electrolysis


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