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Published byMargery Glenn Modified over 8 years ago
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States that if the volume and temperature of a fixed amount of gas do not change, the pressure also remains constant. The Ideal Gas Law
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Equation: Where P = pressure V= volume n = the number of moles of gas in the sample R = the universal gas constant (8.314 J/mol ·K) T = temperature in degrees Kelvin.
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Work required for a gas piston In this diagram the pressure exerted by gas is upward and in order to push the piston downward work must be done on the piston.
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Solving for Work (where dx is the distance change of the piston) Since Pressure = Force/Area then Force = Pressure * Area Therefore the equation can go to: (where V = volume) So for a gas, work is the product of the pressure P and the volume V during a change of volume.
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Temperature Scales: KelvinCelsiusFahrenheit Absolute Zero0-273-459.67 Freezing Point273032 Boiling Point373100212 Equations to change between different units of temperature: Kelvin ↔ Celsius: T c = T k − 273 Fahrenheit ↔ Celsius: T c = (5/9)*(T f − 32) Celsius ↔ Fahrenheit: T f = (9/5)*(T c + 32)
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Thermal Expansion of Solids & Liquids If thermal expansion is sufficiently small relative to an object’s initial dimensions, the change in any dimension is, to a good approximation, proportional the temperature change. Suppose an object has an initial length Li along some direction at some temperature and the length increases by an amount ∆L for a change in temperature ∆T. Because it is convenient to consider the fractional change in length per degree of temperature change, we define the average coefficient of linear expansion as:
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Thermal Expansion cont. Experiments show that α is constant for small changes in temperature. For purposes of calculation, this equation is usually rewritten as: Average volume expansion is very similar:
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Specific Heat The specific heat c of a substance is the heat capacity per unit mass. From this definition: We can relate the energy Q transferred between a sample of mass m of a material and its surroundings to a temperature change ∆T as
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Energy transferred to a substance during a Phase Change Where L = Latent Heat (varies by substance/ chart on p.573) Latent heat of fusion L f is the term used when the phase change is from solid to liquid and latent heat of vaporization L v is the term used when the phase change is from liquid to gas.
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