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Chapter 2 Topics: The fundamentals of matter and chemistry Energy, energy flow, energy in Earth’s systems Geology: plate tectonics and the rock cycle Geologic and natural hazards and ways to mitigate them
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Chemistry Chemistry: studies types of matter and their interactions Chemistry is crucial for understanding: How gases contribute to global climate change How pollutants cause acid rain Environmental health impacts to wildlife and people Water pollution and wastewater treatment Atmospheric ozone depletion Energy issues
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Matter is conserved Matter = all material in the universe that has mass and occupies space The law of conservation of matter: matter can be transformed from one type of substance into others But it cannot be destroyed or created Because the amount of matter stays constant It is recycled in nutrient cycles and ecosystems We cannot simply wish pollution and waste away
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Atoms and elements Element = a fundamental type of matter with a specific set of physical and chemical properties Atoms = the smallest components that maintain an element’s chemical properties The atom’s nucleus is composed of protons (positive charge) and neutrons (no charge). Atomic number = the number of protons Electrons = negatively charged particles at different energy levels surrounding the nucleus
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The structure of an atom
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Isotopes – variation on a theme Isotopes = atoms of the same element with different numbers of neutrons Isotopes of an element behave differently Mass number = the combined number of protons and neutrons
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Radioactive decay of isotopes Radioactive isotopes decay becoming stable isotopes Half-life = the time for one-half of the atoms to decay Half-lives range from fractions of a second to billions of years
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Bonds hold atoms together The configuration of electrons controls how atoms become bonded with each other Bonds in elements (same kind of atoms) Metallic – electrons are shared among all atoms Covalent – electrons are shared with one other atom Bonds in compounds (different kinds of atoms) Covalent – electrons are shared with a fixed number of atoms (molecule = smallest piece of covalent material) Ionic – electrons are given/taken, creating electrically charged atoms called “ions”
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Water’s chemistry is unique Water has “polar” molecules that link with hydrogen bonds Water has strong cohesion and adhesion (capillary action and good solvent) Water has a high heat capacity (storing and releasing thermal energy with only small changes in temperature)
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Hydrogen ions determine acidity pH indicates the acidity of solutions Acidic: pH < 7 Basic: pH > 7 The pH scale is logarithmic: a pH of 6 reporesents10 times as many H + as a pH of 7
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Carbon chemistry is diverse Carbon has the ability to form covalent bonds with up to four other atoms Compounds containing covalently bonded carbon are called “organic” compounds Hydrocarbons are composed only of carbon and hydrogen
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The building blocks of life Four types of macro- molecules have key roles in all living things: Proteins Nucleic acids Carbohydrates Lipids
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Proteins Long chains composed of amino acids Produce tissues, provide structural support, store energy, transport material Animals use proteins to generate skin, hair, muscles, and tendons Some are components of the immune system or hormones They can serve as enzymes = molecules that promote chemical reactions
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Nucleic acids Long chains of nucleotides that contain sugar, phosphate, and a nitrogen base Deoxyribonucleic acid (DNA) and ribonucleic acid (RNA) carry hereditary information of organisms
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Carbohydrates Compounds of carbon, hydrogen, and oxygen Sugars are simple carbohydrates of 3–7 carbons Glucose = C 6 H 12 O 6 – provides energy for cells Complex carbohydrates store energy and build structures Starch = stores energy in plants Chitin = forms shells of insects and crustaceans Cellulose = provides structure in cell walls of plants Lignin = provides structure (woody tissue) in vascular plants
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Lipids Complex organic compounds that include fats, waxes, and fatty acids Store energy, provide signaling, form cell membranes Commonly hydrophilic on one end and hydrophobic on the other
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Energy – the ability to do work Kinetic energy – the energy of motion Electromagnetic Light Electrical Electrons Thermal Individual atoms Mechanical Groups of atoms Potential energy – stored energy Nuclear In atomic nuclei Chemical In chemical bonds Elastic In stressed materials Gravitational In position relative to other matter
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Thermodynamics First law of thermodynamics = energy can change forms, but cannot be created or destroyed Energy efficiency = the proportion of useful energy obtained from an energy conversion Second law of thermodynamics = energy changes from a more-ordered to a less-ordered state Entropy = an increasing state of disorder Adding energy from outside a system can increase its order
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Source characteristic Energy density Most natural sources of energy supply vast amounts of energy, but do so in a very diffuse way Fossil fuels have very high energy densities Intermittency Most natural sources of energy are kinetic and can be intermittent Fossil fuels contain potential energy and can be used continually
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Energy in Earth’s systems Energy from the sun drives three of Earth’s four systems Atmosphere Uneven heating of Earth’s surface Hydrosphere Evaporation of water from the ocean Biosphere Photosynthesis Energy from within the Earth drives the other system Geosphere Convection in the mantle as thermal energy moves from the core to the crust
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Energy in the biosphere Autotrophs (primary producers) = organisms that produce their own food Green plants Algae Cyanobacteria Heterotrophs = organisms that gain energy by feeding on others Animals Fungi Microbes
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Capturing energy - photosynthesis Chloroplasts contain chlorophyll, a light- absorbing pigment Light reactions = split water and make ATP Calvin cycle = links carbon atoms from carbon dioxide into sugar (glucose)
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Capturing energy - chemosynthesis Uses energy in hydrogen sulfide to produce sugar Occurs at the bottom of the ocean along divergent plate boundaries where the lack of sun prevents photosynthesis Hydrothermal vents = host communities that thrive in high temperature and pressure
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Geology Geology = the study of Earth’s physical features, processes, and history Geologic processes at and below the Earth: Shape the landscape Influence processes in the oceans Provide the foundation for environmental systems Determine the distribution of mineral resources Create natural hazards
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Earth’s interior is layered Core = solid iron/nickel (inner core), molten iron/nickel (outer core) Mantle = dense “rocky” material, composed of iron-rich silicate minerals, plastic behavior Crust = thin, low-density rock (continental, oceanic), brittle behavior Lithosphere = the crust and uppermost mantle
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Plate tectonics Earth’s lithosphere consists of discrete pieces (plates) that move with respect to each other and interact along their boundaries The process is driven by the outward movement of thermal energy from the core toward the crust Convection within the mantle causes movement of the plates, creating and recycling Earth’s crust(s) Continents have formed, combined, separated, and recombined over millions of years
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Divergent boundaries Oceanic-Oceanic Mid-ocean ridges New oceanic crust is created Continental-Continental Rift valleys Continents are pulled apart
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Convergent boundaries (subduction) Oceanic crust is subducted back into the mantle The melting slab yields an iron-poor, silica-rich magma Oceanic crust is destroyed Continental crust is created Oceanic-Oceanic Island arcs (volcanic) Oceanic-Continental Volcanic mountain ranges
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Convergent boundaries (collision) Continental-Continental Folded mountain ranges No subduction occurs Continental crust is too light (low-density) Continents collide and merge together Continental crust accumulates
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Transform boundaries Lateral, side-by-side motion Grinding, stick-slip movement stores and releases large amounts of energy
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Plate tectonics affects… Not only The location and severity of earthquakes and volcanoes But also The geography of continents and oceans Which affects the patterns of ocean currents And influences the distribution of rainfall Both of which affect climate Which determines the rates of weathering and erosion And the distribution of biomes and ecosystems
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The rock cycle The processes by which Earth’s mineral matter is recycled among magma igneous rock sediments sedimentary rock metamorphic rock
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Igneous rock Igneous rock forms when magma/lava cools and crystallizes Intrusive igneous rock = magma that cools slowly below Earth’s surface (e.g. granite) Extrusive igneous rock = lava that cools quickly above Earth’s surface (e.g. basalt)
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Sedimentary rock Sedimentary rock forms when sediment (loose mineral grains) is lithified (compacted and cemented) Clastic rock = derived from other rocks Chemical rock = precipitate from solution
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Metamorphic rock Metamorphic rock forms when minerals in a rock change due to heat and/or pressure (no melting!!) Occurs deep within the crust when continents collide Shale-slate-phyllite- schist-gneiss
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Geologic and natural hazards Some consequences of plate tectonics are hazardous “The Ring of Fire” – the circum-Pacific belt of subduction zones and fault systems 90% of earthquakes and 50% of volcanoes
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Earthquakes Earthquakes = sudden movement of the lithosphere, releasing accumulated stress Largest earthquakes occur at convergent and transform boundaries due to compression and shear
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Volcanoes Volcano= molten rock, hot gas, or ash erupt through Earth’s surface Greatest hazards posed by volcanoes at subduction zones due to explosive style Also found above hot spots and at divergent boundaries
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Environmental impacts of volcanoes Ash blocks sunlight Sulfur emissions also scatter sunlight and contribute to acid rain Large eruptions, such as Mount Tambora’s in 1816 can decrease global temperatures “the year without a summer”
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Mass wasting Mass wasting = the downslope movement of soil and rock due to gravity Speeds range from imperceptible “creep” to extremely rapid “lahars” Water often plays a key role in triggering and movement
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Tsunamis Tsunami = waves created by sudden displacement of large volumes of water Generally due to earthquakes Extremely long wavelength produces persistent inland flow
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We often make things worse As populations grow, many people have no choice but to live in susceptible areas But many also choose to live in attractive but vulnerable areas (beaches, mountains) Engineered landscapes increase frequency or severity of hazards (damming rivers, suppressing fire, mining, clearing vegetation, changing slopes) Changing climate alters rainfall patterns, increases drought, fire, flooding, storms
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