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Chapter Seventeen Amines and Amides. Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 2 © Royalty-Free / CORBIS Amines.

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Presentation on theme: "Chapter Seventeen Amines and Amides. Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 2 © Royalty-Free / CORBIS Amines."— Presentation transcript:

1 Chapter Seventeen Amines and Amides

2 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 2 © Royalty-Free / CORBIS Amines and Amides → CO 17.1 Parachutist with a parachute made of the polyamide nylon.

3 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 3 Fig. 17.1 Classification of amines is related to the number of R groups attached to the nitrogen atom. Amines and Amides cont’d

4 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 4 →Fig. 17.2 Aniline, the simplest aromatic amine. Aromatic amines are generally toxic. Amines and Amides cont’d

5 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 5 ←Fig. 17.3 Unbranched primary amines at room temperature and pressure. Amines and Amides cont’d

6 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 6 →Fig. 17.4 Amine-amine hydrogen bonding. Amines and Amides cont’d

7 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 7 ←Fig. 17.5 Comparison of boiling points of unbranched primary amines and unbranched primary alcohols. Amines and Amides cont’d

8 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 8 →Fig. 17.6 Low-molecular amines are soluble in water because of amine- water hydrogen bonding interactions. Amines and Amides cont’d

9 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 9 ←Fig. 17.7 Ammonium ion has a tetrahedral structure, as does the quaternary ammonium ion. Amines and Amides cont’d

10 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 10 Fig. 17.8 Heterocyclic amines serve as “parent” molecules for more complex amine derivatives. Amines and Amides cont’d

11 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 11 Amines and Amides cont’d © Inge Spence / Visuals Unlimited →CAG 17.1

12 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 12 Fig. 17.9 (a) Before the conduction of a nerve impulse. (b) An incoming nerve impulse triggers the release of neurotransmitter molecules. (c) Neurotransmitters bind to receptor sites, activating the receptor nerve cell. Amines and Amides cont’d

13 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 13 Amines and Amides cont’d →CC 17.3

14 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 14 ←Fig. 17.10 The alkaloid atropine is obtained from the belladonna plant. Amines and Amides cont’d Nardin / Jacana / Photo Researchers

15 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 15 →Fig. 17.11 Oriental poppy plants are the source of several narcotic painkillers, including morphine. Amines and Amides cont’d Scott Camazine / Photo Researchers

16 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 16 Amines and Amides cont’d ←CC 17.4

17 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 17 ←Fig. 17.12 Primary, secondary, and tertiary amines and amides and the “H v. R” relationship. Amines and Amides cont’d

18 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 18 →Fig. 17.13 Models of the simplest primary, secondary, and tertiary amides. Amines and Amides cont’d

19 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 19 ←Fig. 17.14 Unbranched primary amines at room temperature and pressure. Amines and Amides cont’d

20 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 20 →Fig. 17.15 The high boiling point of amides are related to the numerous amide- amide hydrogen bonding possibilities that exist. Amines and Amides cont’d

21 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 21 Amines and Amides cont’d ←CC 17. 5

22 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 22 Amines and Amides cont’d ← CAG 17.1

23 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 23 ←Fig. 17.16 A white strand of nylon polymer forms between two layers of a solution containing a diacid and a diamine. Amines and Amides cont’d

24 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 24 →Fig. 17.17 A regular hydrogen- bonding pattern among Kevlar polymer strands contributes to the great strength of this polymer. Amines and Amides cont’d

25 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 25 ←Fig. 17.18 Firefighters with flame- resistant clothing containing Nomex. Amines and Amides cont’d Peter Skinner / Photo Researchers

26 Copyright © Houghton Mifflin Company. All rights reserved.Chapter Seventeen | Slide 26 →Fig. 17.19 Polyurethanes have medical applications. Amines and Amides cont’d © Dan McCoy / Rainbow


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