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Structure, Mechanical properties and its applications.
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Ceramic bonds are mixed, ionic and covalent, with a proportion that depends on the particular ceramics The ionic character is given by the difference of electronegativity between the cations (+) and anions (- ). Covalent bonds involve sharing of valence electrons.
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AX-type crystal structure Rock salt structure Sodium chloride (NaCl) is the most common Rc/Ra =0.414-0.732 CN=6 for both cations and anions Unit cell: FCC arrangement of anions with one cation at center of each of 12 cube edges Two interpenetrating FCC lattices
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Cesium chloride structure CN=8, 8 anions at cube corners and 1 cation at center of cube, simple cubic (not BCC) Zinc Blende structure CN=4, FCC structure of S with Zn at interior tetrahedral positions
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Rc/Ra=0.8, CNCa=8, CNF=4 Ca atoms at center of cubes with F atoms at cube corners, similar to CsCl, but only 1/2 of sites are filled with Ca atoms Unit cell consists of 8 cubes A unit cell of CaF2 (AX2) The AmBnXp type crystal structures Ba at cubic corner, O at center of 6 faces, Ti at body center CNO=12, CNBa=6, and CN Ti=6 Large A cation and oxygen form an FCC lattice Cubic--tetragonal at 1300C (Curie points) Cubic -- orthrhombic and rhombohedral at low T
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Ceramics are brittle. For brittle fracture stress concentrators are very important. Fracture strength of ceramic may be greatly enhanced by creating compressive stresses at Surface. The compressive strength is typically ten times the tensile strength. This makes ceramics good structural materials under compression.
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Alumina99 Excellent mechanical strength, thermal conductivity, electrical insulation, high- frequency loss, abrasion resistance, good chemical resistance and other properties. Used for piston pump, electromagnetic pump, thin film circuit substrates and other special purpose
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Alumina95 Can be used in thick film circuit substrates,and applications where the mechanical strength is required.
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Steatite Good electrical and mechanical properties. Widely used in lamps and various electrical appliances
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Cordierite Resistance to thermal shock, high temperature, Widely used in water heater, hairdryer and other electric heater.
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