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The Bohr ModelNiels Bohr
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Violet: 400 - 420 nm Indigo: 420 - 440 nm Blue: 440 - 490 nm Green: 490 - 570 nm Yellow: 570 - 585 nm Orange: 585 - 620 nm Red: 620 - 780 nm
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Electromagnetic Spectrum
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Frequency-the number of wave cycles passing a point in a period of time. (C=3.00 x 10 8 m/s) As frequency increases, wavelength decreases crest trough
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Yellow light given off by a sodium vapor lamp has a wavelength of 589 nm. What is the frequency of this radiation? v = c/λ v = c/λ = 3.0 x 10 8 m/s x 10 9 nm = 5.09x10 14 s -1 = 3.0 x 10 8 m/s x 10 9 nm = 5.09x10 14 s -1 589nm 1 m 589nm 1 m
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Max Planck Planck stated energy can be released and absorbed in discrete packets called “quanta”. The energy of one quanta is E = h·ν Where h = 6.63 x 10 -34 J·s
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Light of a particular wavelength (λ) has a particular frequency (v) and energy. Light of a particular wavelength (λ) has a particular frequency (v) and energy. E = h∙v and c = λ∙v E = h∙v and c = λ∙v c=3.00 x 10 8 m/s speed of light h=6.63 x 10 -34 joule-sec Plank’s constant
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Calculate the energy of one photon of yellow light whose wavelength is 589nm. E = hv = (6.626 x 10 -34 J∙s)(5.09x10 14 s -1 ) = (6.626 x 10 -34 J∙s)(5.09x10 14 s -1 ) = 3.37 x 10 -19 J = 3.37 x 10 -19 J Substitute v= c/λ in E = h∙v and you get E = h∙c λ
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Pop quiz What do the following symbols stand for? 1. 1. 2. 2. 3. h 4. c 5. E Bonus: Write the two formulas using the above symbols frequency wavelength Planck’s constant Speed of light energy Hz, s -1, 1/s m, nm J∙s m/s J =c/v =c/v E=h∙v
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Why each element produces a unique line spectra.
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H Add energy (heat or electricity) Excited state
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Wave-particle duality of light Planck stated that energy is radiated in discrete packets called quanta. Planck stated that energy is radiated in discrete packets called quanta. A photon is a quantum of light having the energy h∙v. A photon is a quantum of light having the energy h∙v. Light’s particle nature is seen in its ability to eject electrons from a surface (photoelectric effect), and by the emission spectra of elements. Light’s particle nature is seen in its ability to eject electrons from a surface (photoelectric effect), and by the emission spectra of elements.
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Young woman or old woman? What do you see?
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Light’s wave nature is seen by its ability to diffract, reflect, and refract. Light’s wave nature is seen by its ability to diffract, reflect, and refract.
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Photoelectric effect A minimum amount of energy is needed to eject an electron from a surface exposed to light. A minimum amount of energy is needed to eject an electron from a surface exposed to light.
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Summary: Bohr Model of the Atom What works? Shows that Electron Energies are Quantized Applications: “Neon” lights fireworks Auroras fluorescence spectroscopy chemiluminescence bioluminescence
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