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Exam techniques by Dr Mike Thompson Head of Science (Rugby School)
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Exam boards OCR CIE Edexcel AQA WJEC CIE (Pre-U)
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Most common mistake Not reading the Question (RTQ) Answer the Question asked, and answer all parts!
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Amount of substance Amount In moles Volume concentration Most common error in calculations is…..?
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Amount of substance Amount In moles Volume in cm 3 concentration not dividing by 1000 to convert cm3 into dm3
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Electronic configuration Most common error in calculations is…..?
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Electronic configuration Selecting the wrong number and not using superscripts 1s2 2s2 2p6 3s2 3p6 4s2 3d4
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Electronic configuration Selecting the wrong number and not using superscripts 1s2 2s2 2p6 3s2
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Structure and bonding Ionic Covalent Metallic Most common errors involve using the wrong words
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Ionic Compounds common error is writing the wrong formula…..? LiO MgCl CaOH
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Ionic compounds common error is writing the wrong formula…..? LiO MgCl CaOH
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Ionic compounds common error is writing the wrong formula…..?
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Ion Formulae Group12345670 Charge on Ion 1+2+3+4+3-2-1-None formed Group NumberGroup NameExamples of Ions 1Alkali MetalsLi +, Na +, K +, Rb +, Cs + 2Alkaline Earth metalsBe 2+, Mg 2+, Ca 2+, Sr 2+ 7Halogens F -, Cl -, Br -, I - 0Noble GasesNo examples (full outer shell) Name of ion Oxides Hydroxide s SulfatesCarbonateNitrates Formula of ion O2-O2- OH - SO 4 2- CO 3 2- NO 3 -
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Bonding and structure of sodium chloride (6) How many marks would this answer get? Ionic bonding with attraction between oppositely charged molecules Ionic lattice
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Bonding and structure of sodium chloride (6) Any errors ? Ionic bonding with attraction between oppositely charged molecules Ionic lattice 2 marks
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Bonding and structure of sodium chloride (6) Model answer Ionic bonding with electrostatic attraction between oppositely charged ions Giant Ionic lattice 3D arrangement of ions Na + ions surrounded by Cl - ions and vice versa
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Describe the structure and bonding for H 2 and explain why it has a low b.p. -253 ⁰C (7) Break the Question into the different parts Structure: Bonding: Boiling point:
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Describe the structure and bonding for H 2 and explain why it has a low b.p. -253 ⁰C (7) How many marks would this answer get? Structure: covalent molecule Bonding: between non-metals Boiling point: Low as little energy needed to break its covalent bonds
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Describe the structure and bonding for H 2 and explain why it has a low b.p. -253 ⁰C (7) 1 mark Structure: covalent molecule Bonding: between non-metals Boiling point: Low as little energy needed to break its covalent bonds
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Describe the structure and bonding for H 2 and explain why it has a low b.p. -253 ⁰C (7) Any errors ? Structure: covalent molecule Bonding: between non-metals Boiling point: Low as little energy needed to break its covalent bonds
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Describe the structure and bonding for H 2 and explain why it has a low b.p. -253 ⁰C (7) Model answer Structure: simple covalent molecule Bonding: covalent bonding, shared pair of (negative) electrons, which are attracted to the positive nuclei of both atoms Boiling point: Low as little energy needed to break weak intermolecular forces
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Covalent bonding Most common errors are… Thinking they involve metals (Na-Cl) Forgetting bonding electrons are in pairs Forgetting to add all the outer electrons for Halogens
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Covalent bonding Most common errors are… Thinking they involve metals (Na-Cl) Forgetting to add all the outer electrons for Halogens
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Covalent bonding How to get better Play with molymods
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Covalent bonding How to get better Play with molymods
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Covalent bonding How to get better Practise drawing dot-and-cross diagrams
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Describe the structure & bonding in magnesium (5) Metallic Model answer
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Describe the structure & bonding in magnesium (5) Metallic Model answer The diagram gets 2 marks Giant 3D lattice Metallic bonding Electrostatic attraction between positive metal ions and free delocalised electrons
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Drawing Hydrogen bonds not showing all relevant dipoles not showing the lone pair not showing a bond angle of 180o Most common errors are
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Drawing Hydrogen bonds not showing all relevant dipoles not showing the lone pair not showing a bond angle of 180o Most common errors are
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Drawing Hydrogen bonds not showing all relevant dipoles not showing the lone pair not showing a bond angle of 180o Most common errors are
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Drawing Hydrogen bonds Most common errors are
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Empirical molecular structural displayed Types of formulae (ethanol)
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Molecular formula of ethanol? Ratio of elements in a compound C 2 H 5 OH
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Molecular formula of ethanol? Ratio of elements in a compound C 2 H 5 OH
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Molecular formula of ethanol? Ratio of elements in a compound C 2 H 6 O
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Ethanol – give its Functional Group? Alcohol 1 mark
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Ethanol – give its Functional Group? 1 0 Alcohol 2 marks
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Empirical formula of ethane? C2H6C2H6
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Simplest whole number ratio of elements in a compound C 2 H 6
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Empirical formula of ethane? Simplest whole number ratio of elements in a compound CH 3
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Structural formula of ethanol?
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CH 3 CH 2 HO
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Structural formula of ethanol? CH 3 CH 2 OH
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Displayed formula of ethanol
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Displayed formula of ethanol show all the bonds including O-H
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Displayed formula of ethanol
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Displayed formula of ethanol?
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Decimal places (2)
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Decimal places (2)
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Decimal places (2)
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Use unambiguous language
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Count bonds to carbon in organic compounds it always forms four bonds = tetravalent
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1 2 3 4 5
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1 2 3 4
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Drawing a chiral carbon Most common errors…..? Not drawing in 3D Connecting the wrong atoms Not making the carbon look tetrahedral
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Drawing a chiral carbon Most common errors…..? Not drawing in 3D Connecting the wrong atoms Not making the carbon look tetrahedral
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Drawing a chiral carbon Most common errors…..? Not drawing in 3D Connecting the wrong atoms Not making the carbon look tetrahedral
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Ionisation energy Definition (words) 1 st I.E. Energy needed to remove one mole of electrons from one mole of gaseous atoms to produce one mole of gaseous 1+ ions
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Ionisation energy Definition (words) 1 st I.E. Energy needed to remove one mole of electrons from one mole of gaseous atoms to produce one mole of gaseous 1+ ions
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Ionisation energy Definition (equation) 1 st I.E. M (g) M + (g) + e - 1 mole 1 mole 1 mole
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Mass spectrum Identify the molecular ion
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Mass spectrum Identify the molecular ion M ?
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Mass spectrum Identify the molecular ion M
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Mass spectrum Identify the molecular ion M +
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Mass spectrum Identify the molecular ion M + [M+1] + Due to carbon-13
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Van der Waals’ forces Can you explain how these weakest of intermolecular forces are formed? (uneven distribution of electron clouds)
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Van der Waals’ forces How are these weakest of intermolecular forces formed?
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Van der Waals’ forces How are these weakest of intermolecular forces formed?
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Van der Waals’ forces When revising don’t climb the walls like Helium! (take regular breaks)
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Silly marks to lose Remember to add state symbols...when writing an equation for the standard enthalpy of formation of a compound, e.g. CO 2 C + O 2 CO 2 State symbols are often missed out and are essential to get the mark!
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Silly marks to lose Remember to add state symbols...when writing an equation for the standard enthalpy of formation of a compound, e.g. CO 2 C (s) + O 2 (g) CO 2 (g)
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Practical / ISA / PSA Tips Titrations Results table FIT for purpose Rough1 st 2 nd Final / cm 3 Initial / cm 3 Titre / cm 3 Average / cm 3
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Practical / ISA / PSA Tips Titrations Results table with (quantities & units) All values recorded to 2 decimal places Rough1 st 2 nd Final / cm 3 Initial / cm 3 Titre / cm 3 Average / cm 3
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Practical / ISA / PSA Tips Titrations Results need to be concordant (within 0.10 cm 3 ) Rough1 st 2 nd Final / cm 3 Initial / cm 3 Titre / cm 3 Average / cm 3
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Practical / ISA / PSA Tips Titrations Results table FIT for purpose (quantities &units) Rough1 st 2 nd Final / cm 3 24.30 48.3024.20 Initial / cm 3 0.0024.30 0.20 Titre / cm 3 24.3024.00 Average / cm 3 24.00
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The End Thankyou for listening And good luck with your A-levels mat@rugbyschool.net
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Useful websites http://www.chemguide.co.uk/ http://www.knockhardy.org.uk/sci.htm http://a-levelchemistry.co.uk/ http://www.chm.bris.ac.uk/motm/motm.htm http://chemnet.rsc.org/ http://www.rsc.org/learn-chemistry
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