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한국진공학회 제 45 회 하계학술대회 Tutorial 08/21/2013 한국화학연구원 최지나
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Red Ox – Red + Ox Reduction Oxidation CB VB h+h+ Recombination (heat) e–e– Excitation by light (hv) H 2 (H ) H 2 O (H + ) CO 2 − CO 2 H 2 O (OH – ) OH Energy : Hydrogen Production via Water Splitting Carbon Dioxide Reduction into Hydrocarbon Fuel Environmental Application: Water and Air Purification
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S.-Y. Lee, S.-J. Park, J. Ind. Eng. Chem. (2013), http://dx.doi.org/10.1016/j.jiec.2013.07.012
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Band Gap Energies and Positions of Various Semiconductors
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High Photocatalytic Activity Robust Chemical Stability Low Production Cost Non-Toxicity TiO 2 & Light Water Treatment Decomposition of Organic Pollutants Anti-Bacterial Anti-Fogging Air Purification Removal of NO x, SO x, Aldehydes Deordorization 3.2 eV Self-Cleaning
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Modification of TiO2 Morphology: Enhancing Photocatalytic Activity High Surface Area Adsorption Capacity Enhanced Interfacial Charge Transfer A. Fujishima et al., Electro. Soc. Interface (2013), 51
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Water Treatment Decomposition of Persistent Organic Pollutants (POPs) Air Purification Removal of NO x and Aldehydes, Deordorization
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TiO 2 loading pH Temperature Dissolved oxygen Contaminants and their loading Light wavelength Light intensity Response surface analysis
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Ti Photocatalyst: TiO 2 / SrTiO 3 / K 2 La 2 Ti 3 O 10 / Ba-La 2 Ti 2 O 7 Nb Photocatalyst: K 4 Nb 6 O 17 / Sr 2 Nb 2 O 7 / Ba 2 Nb 4 O 15 / Cs 2 Nb 4 O 11 Ta Photocatalyst: Ta 2 O 5 / K 2 PrTa 5 O 15 / K 3 Ta 3 B 2 O 12 / NaTaO 3 / La-NaTaO 3 Other Photocatalysts: PbWO 4 / Sr-CeO 2 / BaCeO 3 Co-catalyst: Pt, NiO x, RuO 2
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A. Kudo et al., Che. Soc. Rev. (2008), 253
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S. N. Habisreutinger et al., Angew. Rev. (2012), 7372
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J. Choi et al., Clean Technol. (2012), 229
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S. N. Habisreutinger et al., Angew. Rev. (2012), 7372
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Sun Wavelength (nm) UV VISIR 3.1eV1.6eV 46 % 38%17%3.5%0.5%0%
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J. Choi et al., JPC C (2010), 783
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Acetaldehyde Decomposition TiO 2-x N x
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J. Choi et al., J. Mater. Chem. (2008), 2371
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