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Published byRalph Alexander Modified over 8 years ago
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History of the Periodic Table
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“Early chemists describe the first dirt molecule.”
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Antoine Lavoisier Compiled a list of all the known elements of the time (1790’s)
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Text p 174
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John Newlands (1864) Noticed repeating patterns “Law of octaves”
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Stanislao Cannizzaro Developed an accepted method for measuring atomic mass
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Dmitri Mendeleev Noticed repeating properties of elements – “Periodicity” Published his periodic table in 1869 Left gaps in table – Predicted properties of undiscovered elements
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Dmitri Mendeleev Noticed some inconsistencies in properties and atomic mass Left them alone – He believed properties were more important than atomic mass
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Henry Moseley (1913) Developed concept of atomic number Arranged elements by increasing atomic number Explained inconsistencies in Mendeleev’s table
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The Periodic Law The physical and chemical properties of elements are periodic functions of their atomic numbers
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The Modern Periodic Table
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Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr H
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Important Types of Elements
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Metals and Nonmetals Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr H
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Metals Very good conductors of heat and electricity Usually shiny and malleable
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Metals Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr H
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Nonmetals Very poor conductors of heat and electricity – “Nonconductors” Exist in all three phases Usually dull and brittle when solid
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Nonmetals Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr H
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Metalloids Have some properties of both metals and nonmetals – “semi-metals” Slightly conductive Usually dull, brittle solids
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Metalloids Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr H
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Electron “Blocks” s-block p-block d-block f-block
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Ge Sn Pb As Sb Bi Se Te Po Br I At Xe SiPSCl CNOF Li K Cs Fr Be Sr “Representative” or “Main Group” Elements Na Rb Mg Ca Ba Ra Ga In Tl Kr Rn 113 AlAr BNe He H
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Important Families of Elements
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Alkali Metals (“s” block) (Group 1) Very reactive – Not found as free metals in nature – React vigorously with water and with many nonmetals Soft, silvery metals Fairly low melting points
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Group 1: Alkali Metals Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr H
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Alkaline-Earth Metals (“s” block) (Group 2) Reactive, but not as reactive as alkali metals – Not found as free metals in nature Harder, denser, and higher melting points than alkali metals
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Group 2: Alkaline Earth Metals Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr H
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Transition Metals (“d” block) Harder, denser than alkali or alkaline-earth metals Much higher melting points than alkali or alkaline-earth metals (except for Hg) Much less reactive Brightly-colored compounds
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Groups 3-12: The Transition Metals H Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr
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“p-block” Elements Wide variety of properties – All of the nonmetals – All of the metalloids – All of the noble gases – Some metals – All three physical states
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“p-block Elements” H Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr
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Halogens (Group 17) Most reactive nonmetals React vigorously with most metals to form salts All three physical states
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Group 17: The HalogensH Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr
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Noble Gases Group 18 Very unreactive – Used to be called “inert” gases
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Group 18: The Noble Gases H Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr
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Hydrogen and Helium Odorless, colorless gases Hydrogen is placed in Group 1 because of its 1s 1 electron configuration Helium is placed in group 18 – Helium is unreactive – Its 1s 2 configuration completely fills its only main energy level
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H Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr Hydrogen and Helium
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Inner Transition Metals (“f” block) Lanthanide series and Actinide series No groups-they are in between Groups 3 and 4 Lanthanides (Period 6) – “Rare earths” – Shiny, reactive metals Actinides (Period 7) – Unstable, radioacative elements – Most are synthetic
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H Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr Inner Transition Metals
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The Lanthanides (Rare Earths) H Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr
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The ActinidesH Li Na K Rb Cs Fr Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf 104 V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg Ga In Tl Ge Sn Pb As Sb Bi Se Te Po Br I At Kr Xe Rn 105 106 107 108 109 110 111 113 AlSiPSClAr BCNOFNe He CePrNdPmSmEuGdTbDyHoErTmYbLu ThPaUrNpPuAmCmBkCfEsFmMdNoLr
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