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PDP Chemistry Chemical reactions
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Topic 1: Chemical reactions Atoms Chemical reactions are atoms rearranging Equations Signs of a chemical reaction Balancing chemical equations Types of chemical reaction Measuring chemical quantities
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How are you going to take notes?
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Atoms What is everything made of?
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In Six Easy Pieces, Richard Feynman said: If, in some cataclysm, all of scientific knowledge were to be destroyed, and only one sentence passed on to the next generation of creatures, what statement would contain the most information in the fewest words? I believe it is the atomic hypothesis that all things are made of atoms.
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(Almost) everything is made of atoms Images:http://en.wikipedia.org/wiki/Rock_(geology), http://en.wikipedia.org/wiki/Tree, http://en.wikipedia.org/wiki/Human, http://en.wikipedia.org/wiki/Star
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How big is an atom? about 10 -10 m if an atom was the size of a grain of sand, humans would be the size of a planet. Image: http://en.wikipedia.org/wiki/Earth, http://en.wikipedia.org/wiki/Sandhttp://en.wikipedia.org/wiki/Earth
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The periodic table lists the elements in order of atomic number Image: http://en.wikipedia.org/wiki/File:Periodic_table.svg
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Chemistry is atoms rearranging
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Describing chemical changes Liquid oxygen and liquid hydrogen fuel Image: http://en.wikipedia.org/wiki/Saturn_Vhttp://en.wikipedia.org/wiki/Saturn_V Launch of Apollo 11 Launch of Apollo 11 (from 6 min)
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Some changes are only changes of phase, not chemical changes Image: https://commons.wikimedia.org/wiki/Categor y:States_of_aggregation
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Atoms are rearranged to make new substances in chemical reactions. Hydrogen + Oxygen Water 2 H2 + O2 2 H2O Image: http://labspace.open.ac.uk/mod/resource/view.php?id=438900
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Equations describe chemical reactions
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reactants products Hydrogen + Oxygen Water 2 H2 + O2 2 H2O
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State symbols (s) (l) (g) (aq)
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Signs of a chemical change How do we know a chemical reaction is occurring?
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Sodium reacts with water
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Dilute sulphuric acid reacts with potassium hydroxide solution
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Lead nitrate solution reacts with potassium iodide solution
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Magnesium and hydrochloric acid
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Signs of a chemical change
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Elements, compounds, atoms, molecules, ions
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Molecules Build a molecule PhET http://phet.colorado.edu/en/simulation/build-a-molecule http://phet.colorado.edu/en/simulation/build-a-molecule States of matter: Basics http://phet.colorado.edu/en/simulation/states-of-matter- basics http://phet.colorado.edu/en/simulation/states-of-matter- basics
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What is an atom?
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Symbols and formulae
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Ethane, C 2 H 6
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Naming compounds
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Ionic compounds (usually metal + non-metal) NaCl KI LiF CaCl2 MgSO4 CaCO3 H2SO4 H2O
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Common Anions Common NameFormulaAlternative name Simple Anions ChlorideCl − FluorideF−F− BromideBr − OxideO 2− Polyatomic anions CarbonateCO 3 2- Hydrogen carbonate HCO 3 − bicarbonate HydroxideOH − NitrateNO 3 2- PhosphatePO 4 3- SulfateSO 4 2- Anions from Organic Acids EthanoateCH 3 COO − acetate MethanoateHCOO − formate EthandioateC 2 O 4 −2 oxalate CyanideCN - Common Cations Common NameFormulaAlternative name Simple Cations AluminiumAl 3+ CalciumCa 2+ Copper(II)Cu 2+ cupric HydrogenH+H+ Iron(II)Fe 2+ ferrous Iron(III)Fe 3+ ferric MagnesiumMg 2+ Mercury(II)Hg 2+ mercuric PotassiumK+K+ kalic SilverAg + SodiumNa + natric Polyatomic Cations AmmoniumNH 4 + HydroniumH3O+H3O+
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Covalent compounds (usually non-metals) CO2 H2O CO NH3 SO2 SO3 CH4
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Equations for lab
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Balancing chemical equations
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Balanced equations show the mole ratio of reactants and products Hydrogen + Oxygen Water 2 H2 + O2 2 H2O Image: http://labspace.open.ac.uk/mod/resource/view.php?id=438900
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2 H2 + O2 2 H2O green numbers = subscripts cannot be changed (a compound has one formula- changing the formula changes the compound) red numbers = coefficients changes to balance the reaction (coefficients valid only for a specific reaction)
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Balancing a chemical equation Propane + oxygen carbon dioxide + water _ C 3 H 8(g) + _ O 2(g) _ CO 2(g) + _ H 2 O (l)
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C 3 H 8(g) + 5 O 2(g) 3 CO 2(g) + 4 H 2 O (l) What does an equation tell us about molecules in the reaction? you need 5 oxygen molecules for 1 molecule of propane 1 propane molecule will produce 3 carbon dioxide molecules and 4 Water molecules 2 molecules of propane produce 6 molecules of carbon dioxide 1 mole of propane produces 3 moles of carbon dioxide
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Measuring chemical quantities
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Measuring chemical quantities: solids in grams using a balance (precision ±0.01g or ±0.001g) Image: http://en.wikipedia.org/wiki/Weighing_scale
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Measuring chemical quantities: liquids in litres (L) or decimetres cubed (dm 3 )1L = 1dm 3 In mL or centimetres cubed (cm 3 ) 1mL = 1cm 3 1000 mL = 1L Images: http://commons.wikimedia.org/wiki/Category:Laboratory_glassware
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Converting mass to volume volume = mass x density volume of pure water is 1.0 gcm -3
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Solutions a solute dissolved in a solvent gives a solution units of concentration grams per litre (gL -1 ) or moles per decimetre cubed (moldm -3, M)
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Types of chemical reaction
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-synthesis -decomposition -displacement -double displacement (special type acid-base) -combustion
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Links Powers of ten http://www.powersof10.com/http://www.powersof10.com/ hydrogen explosion http://www.youtube.com/watch?v=DjcztiNGg_8 http://www.youtube.com/watch?v=DjcztiNGg_8 states of matter phet http://phet.colorado.edu/en/simulation/states-of-matter http://phet.colorado.edu/en/simulation/states-of-matter
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